A new XRD method to quantify plate and lath martensites of hardened medium-carbon steel

This paper introduces a new technique to separately measure the volume fraction and tetragonal ratio of co-existing lath and plate martensites in ultrahigh strength steel, and to calculate their different carbon contents. First of all, the two martensites are assumed to have body centre tetragonal lattice structures of different tetragonal ratios. X-ray diffraction is then applied to obtain the overlapping (200) diffraction peak, which is subsequently separated as four sub-peaks using a self-made multiple Gaussian peak-fitting method to allow the measurement of the individual lattice parameters c and a. Finally a modified equation is applied to calculate the carbon contents from the obtained tetragonal ratios. The new technique is then applied to investigate the effect of subsequent tempering on the decarbonisation of the as-quenched martensites. Keywords: Gaussian peak-fitting, martensite carbon content, martensite tetragonal ratio, medium-carbon steels, Xray diffractio

The correlation between stacking fault energy and the work hardening behaviour of high-mn twinning induced plasticity steel tested at various temperatures

High-Mn Twinning Induced Plasticity (TWIP) steels have superior mechanical properties, which make them promising materials in automotive industry to improve the passenger safety and the fuel consumption. The TWIP steels are characterized by high work hardening rates due to continuous mechanical twin formation during the deformation. Mechanical twinning is a unique deformation mode, which is highly governed by the stacking fault energy (SFE). The composition of steel alloy was Fe-18Mn-0.6C-1Al (wt.%) with SFE of about 25-30 mJ/m2 at room temperature. The SFE ensures the mechanical twinning to be the main deformation mechanism at room temperature. The microstructure, mechanical properties, work hardening behaviour and SFE of the steel was studied at the temperature range of ambient ≤T[°C]≤ 400°C. The mechanical properties were determined using Instron tensile testing machine with 30kN load cell and strain rate of 10-3s-1 and the work hardening behaviour curves were generated using true stress and true strain data. The microstructure after deformation at different temperatures was examined using Zeiss Supra 55VP SEM. It was found that an increase in the deformation temperature raised the SFE resulting in the deterioration of the mechanical twinning that led to decrease not only in the strength but also in the total strain of the steel. A correlation between the temperature, the SFE, the mechanical twinning, the mechanical properties and the work hardening rate was also found. © (2014) Trans Tech Publications, Switzerland

Growth of bainitic ferrite and carbon partitioning during the early stages of bainite transformation in a 2 mass% silicon steel studied by in situ neutron diffraction, TEM and APT

In situ neutron diffraction, transmission electron microscopy (TEM) and atom probe tomography (APT) have been used to study the early stages of bainite transformation in a 2 mass% Si nano-bainitic steel. It was observed that carbon redistribution between the bainitic ferrite and retained austenite at the early stages of the bainite transformation at low isothermal holding occurred in the following sequence: (i) formation of bainitic ferrite nuclei within carbondepleted regions immediately after the beginning of isothermal treatment; (ii) carbon partitioning immediately after the formation of bainitic ferrite nuclei but substantial carbon diffusion only after 33 min of bainite isothermal holding; (iii) formation of the carbon-enriched remaining austenite in the vicinity of bainitic laths at the beginning of the transformation; (iv) segregation of carbon to the dislocations near the austenite/ferrite interface; and (v) homogeneous redistribution of carbon within the remaining austenite with the progress of the transformation and with the formation of bainitic ferrite colonies. Bainitic ferrite nucleated at internal defects or bainite/austenite interfaces as well as at the prior austenite grain boundary. Bainitic ferrite has been observed in the form of an individual layer, a colony of layers and a layer with sideplates at the early stages of transformation. © 2016, International Union of Crystallograph