788 research outputs found
Experimental study of the Ca2 1S+1S asymptote
The filtered laser excitation technique was applied for measuring transition
frequencies of the Ca B-X system from asymptotic levels of the
X ground state reaching . That level has an
outer classical turning point of about 20~\AA which is only 0.2 \rcm below the
molecular SS asymptote. Extensive analysis of the spectroscopic data,
involving Monte Carlo simulation, allowed for a purely experimental
determination of the long range parameters of the potential energy curve. The
possible values of the s-wave scattering length could be limited to be between
250 and 1000.Comment: 10 pages, 7 figure
Fourier-transform spectroscopy of Sr2 and revised ground state potential
Precise potentials for the ground state X1Sigma+g and the minimum region of
the excited state 2_1Sigma+u of Sr2 are derived by high resolution
Fourier-transform spectroscopy of fluorescence progressions from single
frequency laser excitation of Sr2 produced in a heat pipe at 950 Celsius. A
change of the rotational assignment by four units compared to an earlier work
(G. Gerber, R. M\"oller, and H. Schneider, J. Chem. Phys. 81, 1538 (1984)) is
needed for a consistent description leading to a significant shift of the
potentials towards longer inter atomic distances. The huge amount of ground
state data derived for the three different isotopomers 88Sr2, 86Sr88Sr and
87Sr88Sr (almost 60% of all excisting bound rovibrational ground state levels
for the isotopomer 88Sr2) fixes this assignment undoubtedly. The presented
ground state potential is derived from the observed transitions for the radial
region from 4 to 11 A (9 cm-1 below the asymptote) and is extended to the longe
range region by the use of theoretical dispersion coefficients together with
already available photoassociation data. New estimations of the scattering
lengths for the complete set of isotopic combinations are derived by mass
scaling with the derived potential. The data set for the excited state
2_1Sigma+u was sufficient to derive a potential energy curve around the
minimum.Comment: 10 pages, 7 figures, some small corrections done especially to the
potential description of the excited state (already included in the published
journal version
KRb Feshbach Resonances: Modeling the interatomic potential
We have observed 28 heteronuclear Feshbach resonances in 10 spin combinations
of the hyperfine ground states of a 40K 87Rb mixture. The measurements were
performed by observing the loss rates from an atomic mixture at magnetic fields
between 0 and 700 G. This data was used to significantly refine an interatomic
potential derived from molecular spectroscopy, yielding a highly consistent
model of the KRb interaction. Thus, the measured resonances can be assigned to
the corresponding molecular states. In addition, this potential allows for an
accurate calculation of the energy differences between highly excited levels
and the rovibrational ground level. This information is of particular relevance
for the formation of deeply bound heteronuclear molecules. Finally, the model
is used to predict Feshbach resonances in mixtures of 87Rb combined with 39K or
41K.Comment: 4 pages, 3 figure
Radio frequency association of heteronuclear Feshbach molecules
We present a detailed analysis of the production efficiency of weakly bound
heteronuclear KRb-Feshbach molecules using radio frequency association in a
harmonic trap. The efficiency was measured in a wide range of temperatures,
binding energies and radio frequencies. A comprehensive analytical model is
presented, explaining the observed asymmetric spectra and achieving good
quantitative agreement with the measured production rates. This model provides
a deep understanding of the molecule association process and paves the way for
future experiments which rely on Feshbach molecules e.g. for the production of
deeply bound molecules.Comment: 5 pages, 4 figure
Feshbach spectroscopy and scattering properties of ultracold Li+Na mixtures
We have observed 26 interspecies Feshbach resonances at fields up to 2050 G
in ultracold Li+Na mixtures for different spin-state combinations.
Applying the asymptotic bound-state model to assign the resonances, we have
found that most resonances have d-wave character. This analysis serves as
guidance for a coupled-channel calculation, which uses modified interaction
potentials to describe the positions of the Feshbach resonances well within the
experimental uncertainty and to calculate their widths. The scattering length
derived from the improved interaction potentials is experimentally confirmed
and deviates from previously reported values in sign and magnitude. We give
prospects for Li+Na and predict broad Feshbach resonances suitable
for tuning.Comment: 8 pages, 4 figures, version as published in PR
Effect of the tropical tannin-rich shrub legumes Calliandra calothyrsus and Flemingia macrophylla on methane emission and nitrogen and energy balance in growing lambs
The objective of this study was to test whether the use of tannin-rich shrub legume forage is advantageous for methane mitigation and metabolic protein supply at unchanged energy supply when supplemented in combination with tannin-free legumes to sheep. In a 6 × 6 Latin-square design, foliage of two tannin-rich shrub legume species (Calliandra calothyrsus and Flemingia macrophylla) were used to replace either 1/3 or 2/3, respectively, of a herbaceous high-quality legume (Vigna unguiculata) in a diet composed of the tropical grass Brachiaria brizantha and Vigna in a ratio of 0.55 : 0.45. A Brachiaria-only diet served as the negative control. Each experimental period lasted for 28 days, with week 3 serving for balance measurement and data collection inclusive of a 2-day stay of the sheep in open-circuit respiration chambers for measurement of gaseous exchange. While Vigna supplementation improved protein and energy utilisation, the response to the partial replacement with tannin-rich legumes was less clear. The apparent total tract digestibilities of organic matter, NDF and ADF were reduced when the tannin-rich plants partially replaced Vigna, and the dose-response relationships were mainly linear. The tannin-rich plants caused the expected redistribution of more faecal N in relation to urinary N. While Flemingia addition still led to a net body N retention, even when fed at the higher proportion, adding higher amounts of Calliandra resulted in body protein mobilisation in the growing lambs. With respect to energy, supplementation of Vigna alone improved utilisation, while this effect was absent when a tannin-rich plant was added. The inclusion of the tannin-rich plants reduced methane emission per day and per unit of feed and energy intake by up to 24% relative to the Vigna-only-supplemented diet, but this seems to have been mostly the result of a reduced organic matter and fibre digestion. In conclusion, Calliandra seems less apt as protein supplement for ruminants while Flemingia could partially replace a high-quality legume in tropical livestock systems. However, methane mitigation would be small due to associated reductions in N and energy retentio
The Effects of Cultivation Site on Forage Quality of Calliandra calothyrsus var. Patulul
An in vitro experiment was performed to compare the forage quality of foliage of Calliandra (Calliandra calothyrsus Meissner var. Patulul) cultivated on either low or medium-fertility soils in Colombia and Kenya, respectively. A grass-alone diet, with and without urea supplementation, and five legume-supplemented diets (1/3 of dietary dry matter) were tested with the rumen simulation technique (Rusitec) (n=4). The legume supplements consisted of Cratylia (Cratylia argentea), Calliandra from Colombia or Kenya, or 1:1 mixtures of Cratylia with Calliandra Colombia or Kenya. The tannin content of Calliandra Colombia was almost twice as high as that of Calliandra Kenya. Supplementation with urea or Cratylia alone, but not with Calliandra alone, increased ammonia concentration in the fermenter fluid. Unlike Calliandra Colombia, Calliandra Kenya in mixture with Cratylia increased ammonia concentration. The apparent degradation of organic matter increased with all types of supplementation, except with Calliandra Colombia alone. Although the foliage of Calliandra from the two cultivation sites had similar contents of organic matter, crude protein and neutral detergent fibre, they differed in␣nearly all fermentation properties. The material from Kenya showed a higher apparent nutrient degradability. These results indicate that C. calothyrsus var. Patulul cultivated at the Kenyan site had a clearly higher forage quality than foliage from the same variety cultivated in Colombia. However, both materials had a much lower forage quality than Cratylia. The Cratylia-related effects on ruminal fermentation were mainly the results of an increased supply of fermentable nitrogenous compounds as was obvious from the comparison with the urea-supplemented gras
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