659 research outputs found
Development of high-temperature ferromagnetism in SnO2 and paramagnetism in SnO by Fe doping
We report the development of room-temperature ferromagnetism in chemically synthesized powder samples of Sn1−xFexO2 (0.005≤ x ≤0.05) and paramagnetic behavior in an identically synthesized set of Sn1−xFexO. The ferromagnetic Sn0.99Fe0.01O2 showed a Curie temperature TC=850 K, which is among the highest reported for transition-metal-doped semiconductor oxides. With increasing Fe doping, the lattice parameters of SnO2 decreased and the saturation magnetization increased, suggesting a strong structure-magnetic property relationship. When the Sn0.95Fe0.05O2 was prepared at different temperatures between 200 and 900 °C, systematic changes in the magnetic properties were observed. Combined Mössbauer spectroscopy and magnetometry measurements showed a ferromagnetic behavior in Sn0.95Fe0.05O2 samples prepared at and above 350°C, but the ferromagnetic component decreased gradually as preparation temperature approached 600 °C. All Sn0.95Fe0.05O2 samples prepared above 600 °C were paramagnetic. X-ray photoelectron spectroscopy, magnetometry, and particle induced x-ray emission studies showed that the Fe dopants diffuse towards the surface of the particles in samples prepared at higher temperatures, gradually destroying the ferromagnetism. Mössbauer studies showed that the magnetically ordered Fe3+ spins observed in the Sn0.95Fe0.05O2 sample prepared at 350 °C is only ~24% of the uniformly incorporated Fe3+. No evidence of any iron oxide impurity phases were detected in Sn1−xFexO2 or Sn1−xFexO, suggesting that the emerging magnetic interactions in these systems are most likely related to the properties of the host systems SnO2 and SnO, and their oxygen stoichiometry
63Cu NQR evidence of dimensional crossover to anisotropic 2d regime in S= 1/2 three-leg ladder Sr2Cu3O5
We probed spin-spin correlations up to 725 K with 63Cu NQR in the S= 1/2
three-leg ladder Sr2Cu3O5. We present experimental evidence that below 300 K,
weak inter-ladder coupling causes dimensional crossover of the spin-spin
correlation length \xi from quasi-1d (\xi ~ 1/T) to anisotropic 2d regime (\xi
\~ exp[2\pi\rho_{s}/T], where 2\pi\rho_{s} = 290 +/- 30 K is the effective spin
stiffness). This is the first experimental verification of the renormalized
classical behavior of the anisotropic non-linear sigma model in 2d, which has
been recently proposed for the striped phase in high T_{c} cuprates.Comment: 4 pages, 3 figure
Evidence for Ballistic Thermal Conduction in the One-Dimensional S=1/2 Heisenberg Antiferromagnetic Spin System Sr2CuO3
We have measured the thermal conductivity of the one-dimensional (1D) S=1/2
Heisenberg antiferromagnetic spin system of Sr2Cu1-xPdxO3 single crystals
including nonmagnetic impurities of Pd2+. It has been found that the mean free
path of spinons along the 1D spin chain at low temperatures is very close to
the average length of finite spin chains between spin defects estimated from
the magnetic susceptibility measurements. This proves that the thermal
conduction due to spinons at low temperatures in Sr2CuO3 is ballistic as
theoretically expected [Zotos et al.: Phys. Rev. Lett. 55 (1997) 11029]
How linear features alter predator movement and the functional response
In areas of oil and gas exploration, seismic lines have been reported to alter the movement patterns of wolves (Canis lupus). We developed a mechanistic first passage time model, based on an anisotropic elliptic partial differential equation, and used this to explore how wolf movement responses to seismic lines influence the encounter rate of the wolves with their prey. The model was parametrized using 5 min GPS location data. These data showed that wolves travelled faster on seismic lines and had a higher probability of staying on a seismic line once they were on it. We simulated wolf movement on a range of seismic line densities and drew implications for the rate of predator–prey interactions as described by the functional response. The functional response exhibited a more than linear increase with respect to prey density (type III) as well as interactions with seismic line density. Encounter rates were significantly higher in landscapes with high seismic line density and were most pronounced at low prey densities. This suggests that prey at low population densities are at higher risk in environments with a high seismic line density unless they learn to avoid them
Critical dynamics of a spin-5/2 2D isotropic antiferromagnet
We report a neutron scattering study of the dynamic spin correlations in
RbMnF, a two-dimensional spin-5/2 antiferromagnet. By tuning an
external magnetic field to the value for the spin-flop line, we reduce the
effective spin anisotropy to essentially zero, thereby obtaining a nearly ideal
two-dimensional isotropic antiferromagnet. From the shape of the quasielastic
peak as a function of temperature, we demonstrate dynamic scaling for this
system and find a value for the dynamical exponent . We compare these
results to theoretical predictions for the dynamic behavior of the
two-dimensional Heisenberg model, in which deviations from provide a
measure of the corrections to scaling.Comment: 5 pages, 4 figures. Submitted to Physical Review B, Rapid
Communication
Conductivity of quantum-spin chains: A Quantum Monte Carlo approach
We discuss zero-frequency transport properties of various spin-1/2 chains. We
show, that a careful analysis of Quantum Monte-Carlo (QMC) data on the
imaginary axis allows to distinguish between intrinsic ballistic and diffusive
transport. We determine the Drude weight, current-relaxation life-time and the
mean-free path for integrable and a non-integrable quantum-spin chain. We
discuss, in addition, some phenomenological relations between various
transport-coefficients and thermal response functions
A Systems Approach for Tumor Pharmacokinetics
Recent advances in genome inspired target discovery, small molecule screens, development of biological and nanotechnology have led to the introduction of a myriad of new differently sized agents into the clinic. The differences in small and large molecule delivery are becoming increasingly important in combination therapies as well as the use of drugs that modify the physiology of tumors such as anti-angiogenic treatment. The complexity of targeting has led to the development of mathematical models to facilitate understanding, but unfortunately, these studies are often only applicable to a particular molecule, making pharmacokinetic comparisons difficult. Here we develop and describe a framework for categorizing primary pharmacokinetics of drugs in tumors. For modeling purposes, we define drugs not by their mechanism of action but rather their rate-limiting step of delivery. Our simulations account for variations in perfusion, vascularization, interstitial transport, and non-linear local binding and metabolism. Based on a comparison of the fundamental rates determining uptake, drugs were classified into four categories depending on whether uptake is limited by blood flow, extravasation, interstitial diffusion, or local binding and metabolism. Simulations comparing small molecule versus macromolecular drugs show a sharp difference in distribution, which has implications for multi-drug therapies. The tissue-level distribution differs widely in tumors for small molecules versus macromolecular biologic drugs, and this should be considered in the design of agents and treatments. An example using antibodies in mouse xenografts illustrates the different in vivo behavior. This type of transport analysis can be used to aid in model development, experimental data analysis, and imaging and therapeutic agent design.National Institutes of Health (U.S.) (grant T32 CA079443
Thermal conductivity via magnetic excitations in spin-chain materials
We discuss the recent progress and the current status of experimental
investigations of spin-mediated energy transport in spin-chain and spin-ladder
materials with antiferromagnetic coupling. We briefly outline the central
results of theoretical studies on the subject but focus mainly on recent
experimental results that were obtained on materials which may be regarded as
adequate physical realizations of the idealized theoretical model systems. Some
open questions and unsettled issues are also addressed.Comment: 17 pages, 4 figure
Diffusive energy transport in the S=1 Haldane chain compound AgVP2S6
We present the results of measurements of the thermal conductivity
of the spin S=1 chain compound AgVP_2S_6 in the temperature range between 2 and
300 K and with the heat flow directed either along or perpendicular to the
chain direction. The analysis of the anisotropy of the heat transport allowed
for the identification of a small but non-negligible magnon contribution
along the chains, superimposed on the dominant phonon contribution
. At temperatures above about 100 K the energy diffusion constant
D_E(T), calculated from the data, exhibits similar features as
the spin diffusion constant D_S(T), previously measured by NMR. In this regime,
the behaviour of both transport parameters is consistent with a diffusion
process that is caused by interactions inherent to one-dimensional S=1 spin
systems.Comment: 6 pages, 4 figure
- …