2,219 research outputs found

    Distributed Channel Assignment in Cognitive Radio Networks: Stable Matching and Walrasian Equilibrium

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    We consider a set of secondary transmitter-receiver pairs in a cognitive radio setting. Based on channel sensing and access performances, we consider the problem of assigning channels orthogonally to secondary users through distributed coordination and cooperation algorithms. Two economic models are applied for this purpose: matching markets and competitive markets. In the matching market model, secondary users and channels build two agent sets. We implement a stable matching algorithm in which each secondary user, based on his achievable rate, proposes to the coordinator to be matched with desirable channels. The coordinator accepts or rejects the proposals based on the channel preferences which depend on interference from the secondary user. The coordination algorithm is of low complexity and can adapt to network dynamics. In the competitive market model, channels are associated with prices and secondary users are endowed with monetary budget. Each secondary user, based on his utility function and current channel prices, demands a set of channels. A Walrasian equilibrium maximizes the sum utility and equates the channel demand to their supply. We prove the existence of Walrasian equilibrium and propose a cooperative mechanism to reach it. The performance and complexity of the proposed solutions are illustrated by numerical simulations.Comment: submitted to IEEE Transactions on Wireless Communicaitons, 13 pages, 10 figures, 4 table

    Novel organic synthesis through ultrafast chemistry

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    How fast are flashes? The field of flow chemistry has recently received increasing attention owing to the availability of commercial flow equipment. New syntheses with very short-lived intermediates have been enabled by sub-millisecond mixing and reaction regimes in tailor-made flow devices

    Neue organische synthesen durch ultraschnelle chemie

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    Schnell wie der Blitz: Neue Synthesen gelingen dank sehr kurzlebiger Intermediate, die durch Submillisekundenmischen und -reaktionen in speziellen Fluss-Systemen erzeugt werden

    330ā€” Public Opinion and Policy Regarding Welfare in the United States

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    Government spending on social programs is perhaps the most widely debated platform topic in American politics. The American two party system has produced two distinctive camps, defined most obviously by liberal Democrats and Democratic Socialists on one side, and conservative Republicans on the other. The former argues that government should play a stronger role in securing wealth for the lower class than it currently does via social safety nets provided by taxes on richer individuals. The latter claims that the current American welfare state is either doing enough or too much in its legal role to redistribute funds to lower class individuals/households. While these assertions may be accurate, they are extremely broad and do not properly explain the status of our welfare state or how it has attained its current form. In this analysis, I will look at data and historical trends regarding the US budget, public opinion on its own welfare/ social spending, specific programs, and any legislation, movements, or events that are relevant to the current status of our welfare state. I predict that public opinion regarding the social spending programs of the US government have had an effect on actual legislation and budgets passed by congress

    Broad levels in 17^{17}O and their relevance for the astrophysical s-process

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    Levels in 17^{17}O affect the astrophysical s-process in two opposite ways. The neutron production is enhanced by resonances in the 13^{13}C(Ī±\alpha,nn)16^{16}O reaction at excitation energies around 7 MeV in 17^{17}O, and the number of available neutrons is reduced by low-lying resonances in the 16^{16}O(nn,Ī³\gamma)17^{17}O reaction corresponding to levels in 17^{17}O with excitation energies of 4āˆ’54-5 MeV. The present work uses the 19^{19}F(dd,Ī±\alpha)17^{17}O reaction to determine absolute widths of the relevant levels in 17^{17}O. The results improve the uncertainties of the previously adopted values and resolve a discrepancy between recent studies for the 1/2+1/2^+ level close to the threshold of the 13^{13}C(Ī±\alpha,nn)16^{16}O reaction. In addition, improved excitation energies and widths are provided for several states in 17^{17}O up to excitation energies close to 8 MeV.Comment: 5 pages, 2 figures, Phys. Rev. C (in press

    In vivo manipulation of interleukin-2 expression by a retroviral tetracycline (tet)-regulated system

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    We have used the tetracycline (tet)-regulated system as described previously to evaluate the applicability of controlled gene expression in cancer gene therapy. As a model gene, we used the human interleukin-2 (IL-2) gene, which has been placed under the transcriptional control of the tetO/promoter. Human melanoma cells were transduced by two modified retroviral tet vectors containing the transactivator regulatory unit and the IL-2 gene driven by the tetO/promoter, respectively. In the absence of tet, IL-2 expression in the target cells was stable over several months. IL-2 production was in the range of 40 U/106 cells/24 hours. A fine tuning of IL-2 expression could be achieved by culturing the transduced cells with increasing doses of tet, whereby a concentration of 500 ng/mL tet in the culture medium abrogated IL-2 expression. Most importantly for clinical application, IL-2 expression by the transduced melanoma cells could also be regulated in vivo. When nu/nu mice were inoculated with the transduced tumor cells, they failed to develop tumors. Instead, the inhibition of IL-2 expression in the transduced tumor cells by oral administration of tet led to subcutaneous tumor growth; this growth rate was comparable with the growth rate of subcutaneously inoculated untransduced parental cells. The finding demonstrates the applicability of the tet-regulated system in cancer gene therapy

    Safe use of nitromethane for aldol reactions in flow

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    Using a simple flow reactor, the safe use of nitromethane at elevated reaction temperatures was demonstrated in a nitroaldol reaction of different aldehydes. The reaction products were isolated in good yields after a short reaction tim

    Frontispiece: stereoselective ketone rearrangements with hypervalent iodine reagents

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    Stereoselective Rearrangements The first stereoselective version of an iodine(III)-mediated rearrangement of arylketones in the presence of orthoesters is described T. Wirth and F. Malmedy on pageā€…16072ā€…ff. The reaction products, Ī±-arylated esters, are very useful intermediates in the synthesis of bioactive compounds, such as ibuprofen. With chiral lactic acid-based iodine(III) reagents, enantioselectivities of up to 73ā€‰%ā€‰ee have been achieved

    Structurally defined Ī±-Tetralol-Based chiral hypervalent iodine reagents

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    A novel class of chiral hypervalent iodine reagents containing an Ī±-tetralol-scaffold is being introduced. Iodine triacetate is employed in a key-step as highly selective and efficient iodinating reagent for a short and convenient synthesis of iodine(III) derivatives. Solid state X-ray analyses offer valuable structural information while reactivities and stereoselectivities are investigated in three model reactions
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