Assessment of the environmental toxicity and carcinogenicity of tungsten-based shot.

The toxicity of elemental tungsten released from discharged shot was assessed against previous studies that established a 1% toxic threshold for soil organisms. Extremely heavy theoretical shot loadings of 69,000 shot/ha were used to generate estimated environmental concentrations (EEC) for two brands of tungsten-based shot containing 51% and 95% tungsten. The corresponding tungsten EEC values were 6.5–13.5 mg W/kg soil, far below the 1% toxic threshold. The same shot loading in water produced tungsten EEC values of 2.1–4.4 mg W/L, levels that are not toxic under experimental conditions. Pure tungsten has not been shown to exhibit carcinogenic properties when ingested or embedded in animal tissues, but nickel, with which it is often alloyed, has known carcinogenicity. Given the large number of waterfowl that carry shot embedded in their body, it is advisable to screen lead shot substitutes for their carcinogenic potential through intra-muscular implantation

Coupled thermomechanical dynamics of phase transitions in shape memory alloys and related hysteresis phenomena

In this paper the nonlinear dynamics of shape memory alloy phase transformations is studied with thermomechanical models based on coupled systems of partial differential equations by using computer algebra tools. The reduction procedures of the original model to a system of differential-algebraic equations and its solution are based on the general methodology developed by the authors for the analysis of phase transformations in shape memory materials with low dimensional approximations derived from center manifold theory. Results of computational experiments revealing the martensitic-austenitic phase transition mechanism in a shape-memory-alloy rod are presented. Several groups of computational experiments are reported. They include results on stress- and temperature-induced phase transformations as well as the analysis of the hysteresis phenomenon. All computational experiments are presented for Cu-based structures