File forensics for RAW camera image formats

Recent research in multimedia forensics has developed a variety of methods to detect image tampering and to identify the origin of image files. Many of these techniques are based on characteristics in the JPEG format, as it is the most used file format for digital images. In recent years RAW image formats have gained popularity among amateur and professional photographers. This increase in their use and possible misuse makes these file formats an important subject to file forensic examinations. The aim of this paper is to explore to which extend methods previously developed for images in JPEG format can be applied to RAW image formats

Forensic analysis of video file formats

AbstractVideo file format standards define only a limited number of mandatory features and leave room for interpretation. Design decisions of device manufacturers and software vendors are thus a fruitful resource for forensic video authentication. This paper explores AVI and MP4-like video streams of mobile phones and digital cameras in detail. We use customized parsers to extract all file format structures of videos from overall 19 digital camera models, 14 mobile phone models, and 6 video editing toolboxes. We report considerable differences in the choice of container formats, audio and video compression algorithms, acquisition parameters, and internal file structure. In combination, such characteristics can help to authenticate digital video files in forensic settings by distinguishing between original and post-processed videos, verifying the purported source of a file, or identifying the true acquisition device model or the processing software used for video processing

Crucial role of local peroxynitrite formation in neutrophil-induced endothelial cell activation

Introduction and methods: The reaction of superoxide anions and NO not only results in a decreased availability of NO, but also leads to the formation of peroxynitrite, the role of which in the cardiovascular system is still discussed controversially. In cultured human endothelial cells, we studied whether there is a significant interaction between endothelial NO and neutrophil-derived superoxide anions in terms of endothelial peroxynitrite formation. We particularly studied whether a significantly higher redox-stress can be found in those endothelial cells directly adjacent to an activated neutrophil. Results: A considerable part of the 2,7-dihydrodichlorofluoresceine signal in endothelial cells was due to oxidation by peroxynitrite. Providing superoxide radicals by enzymatic source or by the neutrophil respiratory burst increased the fluorescence, which was attenuated by blockade of endothelial NO-synthase, suggesting that peroxynitrite was formed from neutrophil- or extracellular enzyme-derived superoxide and endothelial NO. Considerably higher fluorescence intensity was observed in endothelial cells in direct neighborhood to a neutrophil. This was particularly pronounced in the presence of a NO-donor and was accompanied by a strong activation of NF-κB and increased expression of E-selectin in these cells. Conclusion: Endothelial cells adjacent to neutrophils may have elevated levels of peroxynitrite that result in an increased expression of adhesion molecules. Such cells might represent a preferential site for adhesion and migration of additional neutrophils when simultaneously high concentrations of NO and neutrophil-derived superoxide are present

New composite separator pellet to increase power density and reduce size of thermal batteries.

We show that it is possible to manufacture strong macroporous ceramic films that can be backfilled with electrolyte to form rigid separator pellets suitable for use in thermal batteries. Several new ceramic manufacturing processes are developed to produce sintered magnesium oxide foams with connected porosities of over 80% by volume and with sufficient strength to withstand the battery manufacturing steps. The effects of processing parameters are quantified, and methods to imbibe electrolyte into the ceramic scaffold demonstrated. Preliminary single cell battery testing show that some of our first generation pellets exhibit longer voltage life with comparable resistance at the critical early times to that exhibited by a traditional pressed pellets. Although more development work is needed to optimize the processes to create these rigid separator pellets, the results indicate the potential of such ceramic separator pellets to be equal, if not superior to, current pressed pellets. Furthermore, they could be a replacement for critical material that is no longer available, as well as improving battery separator strength, decreasing production costs, and leading to shorter battery stacks for long-life batteries

On resampling detection in re-compressed images

Resampling detection has become a standard tool in digital image forensics. This paper investigates the important case of resampling detection in re-compressed JPEG images. We show how blocking artifacts of the previous compression step can help to increase the otherwise drastically reduced detection performance in JPEG compressed images. We give a formulation on how affine transformations of JPEG compressed images affect state-of-the-art resampling detectors and derive a new efficient detection variant, which better suits this relevant detection scenario. The principal appropriateness of using JPEG pre-compression artifacts for the detection of resampling in re-compressed images is backed with experimental evidence on a large image set and for a variety of different JPEG qualities. Index Terms — digital image forensics, tamper detection, resampling detection, re-compression artifacts 1

Spacer-Controlled Supramolecular Assemblies of Cu(II) with Bis(2-Hydroxyphenylimine) Ligands. from Monoligand Complexes to Double-Stranded Helicates and Metallomacrocycles

Reaction of Cu(NO3)2·3H2O or Cu(CH3COO)2·H2O with the bis(2-hydroxyphenylimine) ligands H2L1-H2L4 gave four Cu(II) complexes of composition [Cu2(L1)(NO3)2(H2O)]·MeOH, [Cu2(L2)2], [Cu2(L3)2] and [Cu2(L4)2]·2MeOH. Depending on the spacer unit, the structures are characterized by a dinuclear arrangement of Cu(II) within one ligand (H2L1), by a double-stranded [2+2] helical binding mode (H2L2 and H2L3) and a [2 + 2] metallomacrocycle formation (H2L4). In these complexes, the Cu(II) coordination geometries are quite different, varying between common square planar or square pyramidal arrangements, and rather rare pentagonal bipyramidal and tetrahedral geometries. In addition, solution studies of the complex formation using UV/Vis and ESI-MS as well as solvent extraction are reported