143,343 research outputs found
Issues Relevant to C-H Activation at Platinum(II): Comparative Studies between Cationic, Zwitterionic, and Neutral Platinum(II) Compounds in Benzene Solution
Cationic late metal systems are being highly scrutinized due to
their propensity to mediate so-called electrophilic C-H
activation reactions. This contribution compares the reactivity
of highly reactive cationic platinum(II) systems with
structurally related but neutral species. Our experimental
design exploits isostructural neutral and cationic complexes
supported by bis(phosphine) ligands amenable to mechanistic
examination in benzene solution. The data presented herein
collectively suggests that neutral platinum complexes can be
equally if not more reactive towards benzene than their
cationic counter-parts. Moreover, a number of unexpected
mechanistic distinctions between the two systems arise that
help to explain their respective reactivity
Wide-angle perfect absorber/thermal emitter in the THz regime
We show that a perfect absorber/thermal emitter exhibiting an absorption peak
of 99.9% can be achieved in metallic nanostructures that can be easily
fabricated. The very high absorption is maintained for large angles with a
minimal shift in the center frequency and can be tuned throughout the visible
and near-infrared regime by scaling the nanostructure dimensions. The stability
of the spectral features at high temperatures is tested by simulations using a
range of material parameters.Comment: Submitted to Phys. Rev. Let
Energy-level pinning and the 0.7 spin state in one dimension: GaAs quantum wires studied using finite-bias spectroscopy
We study the effects of electron-electron interactions on the energy levels
of GaAs quantum wires (QWs) using finite-bias spectroscopy. We probe the energy
spectrum at zero magnetic field, and at crossings of opposite-spin-levels in
high in-plane magnetic field B. Our results constitute direct evidence that
spin-up (higher energy) levels pin to the chemical potential as they populate.
We also show that spin-up and spin-down levels abruptly rearrange at the
crossing in a manner resembling the magnetic phase transitions predicted to
occur at crossings of Landau levels. This rearranging and pinning of subbands
provides a phenomenological explanation for the 0.7 structure, a
one-dimensional (1D) nanomagnetic state, and its high-B variants.Comment: 6 pages, 4 figure
Reliable and robust molecular sexing of the hen harrier (Circus cyaneus) using PCR-RFLP of the CHD1 gene
The hen harrier (Circus cyaneus) is a bird of prey that is persecuted in the United Kingdom, and there is a need for a DNA-based individual identification and sexing system for the use in forensic investigations. This study reports a new set of PCR primers for the chromo-helicase-DNA-binding protein 1 gene, which allows sexing using PCR-RFLP. Instead of exonic primers that amplify across a large intron, this set consists of a primer within the intron, enabling reduction in amplicon sizes from 356 to 212 bp and 565 to 219 bp in W and Z chromosomes. DNA degradation and dilution experiments demonstrate that this set is significantly more robust than one that amplifies across the intron, and sequencing of the intronic primer-binding region across several individuals shows that it is highly conserved. While our objective is to incorporate this primer set into an STR-based individualization kit, it may in the meantime prove useful in forensic or conservation studies
Doubly Heavy Baryons and Quark-Diquark Symmetry in Quenched and Partially Quenched Chiral Perturbation Theory
We extend the chiral Lagrangian with heavy quark-diquark symmetry to quenched
and partially quenched theories. These theories are used to derive formulae for
the chiral extrapolation of masses and hyperfine splittings of doubly heavy
baryons in lattice QCD simulations. A quark-diquark symmetry prediction for the
hyperfine splittings of heavy mesons and doubly heavy baryons is rather
insensitive to chiral corrections in both quenched and partially quenched QCD.
Extrapolation formulae for the doubly heavy baryon electromagnetic transition
moments are also determined for the partially quenched theory.Comment: 19pp, Ref. adde
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