Die Struktur von DL-μ-hydroxo-di-μ-nitro-bis(triamminkobalt)(3+)-trichlorid-hydrat

DL-μ-Hydroxo-di-μ-nitro-bis(triamminecobalt)(3 + )-trichloride hydrate, [(NH_3)_3Co(OH)(N0_2hCo(NH_3)_3]Cl_3. H_20, crystallizes in the monoclinic space group P2_1/c with ɑ = 9·70, b = 6-73, c = 24·57 Å and β = 104·3°; there are four formula units in the cell. The structure was determined by the heavy-atom method and refined by three-dimensional least-squares calculations. The final R index for 1397 observed reflections of non-zero weight is 0·067

Hyperfine structure and nuclear hyperpolarization observed in the bound exciton luminescence of Bi donors in natural Si

As the deepest group V donor in Si, Bi has by far the largest hyperfine interaction, and also a large I=9/2 nuclear spin. At zero field this splits the donor ground state into states having total spin 5 and 4, which are fully resolved in the photoluminescence spectrum of Bi donor bound excitons. Under a magnetic field, the 60 expected allowed transitions cannot be individually resolved, but the effects of the nuclear spin distribution, -9/2 <= I_z <= 9/2, are clearly observed. A strong hyperpolarization of the nuclear spin, with sign opposite to the expected equilibrium polarization, is observed to result from the nonresonant optical excitation. This is very similar to the recently reported optical hyperpolarization of P donors observed by EPR at higher magnetic fields. We introduce a new model to explain this effect, and predict that it may be very fast.Comment: 4 pages, 3 figures, 1 tabl

The Crystal Structure of Guanosine Dihydrate and Inosine Dihydrate

Crystals of the dihydrates of guanosine (C_(10)H_(13)N_5O_5) and inosine (C_(10)H_(12)N_4O_5) are nearly isostructural. They are monoclinic, space group P2_1, with cell dimensions ɑ = 17·518, b = 11 ·502, c = 6·658 Å, β = 98·17° (guanosine) and ɑ = 17·573, b =11·278, c=6-654 Å, β = 98·23° (inosine). There are two nucleoside molecules and four water molecules per asymmetric unit. Data were collected on an automated diffractometer; the structures were solved by Patterson and trial-and-error methods and refined to R indices of about 0·035. The structure features hydrogen bonding between purine bases to form ribbons parallel to b and parallel stacking of purine bases along c; the separation between adjacent rings within a stack is 3·3 Å. The conformations about the glycosidic C-N bond and the puckerings of the sugar rings arc quite different for the two molecules in the asymmetric unit

Further investigations of the deep double donor magnesium in silicon

The deep double donor levels of substitutional chalcogen impurities in silicon have unique optical properties which may enable a spin/photonic quantum technology. The interstitial magnesium impurity (Mg$_i$) in silicon is also a deep double donor but has not yet been studied in the same detail as have the chalcogens. In this study we look at the neutral and singly ionized Mg$_i$ absorption spectra in natural silicon and isotopically enriched 28-silicon in more detail. The 1s(A$_1$) to 1s(T$_2$) transitions, which are very strong for the chalcogens and are central to the proposed spin/photonic quantum technology, could not be detected. We observe the presence of another double donor (Mg$_{i*}$) that may result from Mg$_i$ in a reduced symmetry configuration, most likely due to complexing with another impurity. The neutral species of Mg$_{i*}$ reveal unusual low lying ground state levels detected through temperature dependence studies. We also observe a shallow donor which we identify as a magnesium-boron pair

Imaging anomalous nematic order and strain in optimally doped BaFe2_2(As,P)2_2

We present the strain and temperature dependence of an anomalous nematic phase in optimally doped BaFe$_2$(As,P)$_2$. Polarized ultrafast optical measurements reveal broken 4-fold rotational symmetry in a temperature range above $T_c$ in which bulk probes do not detect a phase transition. Using ultrafast microscopy, we find that the magnitude and sign of this nematicity vary on a ${50{-}100}~\mu$m length scale, and the temperature at which it onsets ranges from 40 K near a domain boundary to 60 K deep within a domain. Scanning Laue microdiffraction maps of local strain at room temperature indicate that the nematic order appears most strongly in regions of weak, isotropic strain. These results indicate that nematic order arises in a genuine phase transition rather than by enhancement of local anisotropy by a strong nematic susceptibility. We interpret our results in the context of a proposed surface nematic phase