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Exchange bias effect in the phase separated Nd_{1-x}Sr_{x}CoO_3 at the spontaneous ferromagnetic/ferrimagnetic interface
We report the new results of exchange bias effect in Nd_{1-x}Sr_{x}CoO_3 for
x = 0.20 and 0.40, where the exchange bias phenomenon is involved with the
ferrimagnetic (FI) state in a spontaneously phase separated system. The
zero-field cooled magnetization exhibits the FI (T_{FI}) and ferromagnetic
(T_C) transitions at ~ 23 and \sim 70 K, respectively for x = 0.20. The
negative horizontal and positive vertical shifts of the magnetic hysteresis
loops are observed when the system is cooled through T_{FI} in presence of a
positive static magnetic field. Training effect is observed for x = 0.20, which
could be interpreted by a spin configurational relaxation model. The
unidirectional shifts of the hysteresis loops as a function of temperature
exhibit the absence of exchange bias above T_{FI} for x = 0.20. The analysis of
the cooling field dependence of exchange bias field and magnetization indicates
that the ferromagnetic (FM) clusters consist of single magnetic domain with
average size around \sim 20 and ~ 40 \AA ~ for x = 0.20 and 0.40, respectively.
The sizes of the FM clusters are close to the percolation threshold for x =
0.20, which grow and coalesce to form the bigger size for x = 0.40 resulting in
a weak exchange bias effect.Comment: 9 pages, 9 figure
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Electrospun Piezoelectric Polymer Nanofiber Layers for Enabling in Situ Measurement in High-Performance Composite Laminates
This article highlights the effects from composite manufacturing parameters on fiber-reinforced composite laminates modified with layers of piezoelectric thermoplastic nanofibers and a conductive electrode layer. Such modifications have been used for enabling in situ deformation measurement in high-performance aerospace and renewable energy composites. Procedures for manufacturing high-performance composites are well-known and standardized. However, this does not imply that modifications via addition of functional layers (e.g., piezoelectric nanofibers) while following the same manufacturing procedures can lead to a successful multifunctional composite structure (e.g., for enabling in situ measurement). This article challenges success of internal embedment of piezoelectric nanofibers in standard manufacturing of high-performance composites via relying on composite process specifications and parameters only. It highlights that the process parameters must be revised for manufacturing of multifunctional composites. Several methods have been used to lay up and manufacture composites such as electrospinning the thermoplastic nanofibers, processing an inter digital electrode (IDE) made by conductive epoxy-graphene resin, and prepreg autoclave manufacturing aerospace grade laminates. The purpose of fabrication of IDE was to use a resin type (HexFlow RTM6) for the conductive layer similar to that used for the composite. Thereby, material mismatch is avoided and the structural integrity is sustained via mitigation of downgrading effects on the interlaminar properties. X-ray diffraction, Fourier transform infrared spectroscopy, energy dispersive X-ray spectroscopy, and scanning electron microscopy analyses have been carried out in the material characterization phase. Pulsed thermography and ultrasonic C-scanning were used for the localization of conductive resin embedded within the composite laminates. This study also provides recommendations for enabling internally embedded piezoelectricity (and thus health-monitoring capabilities) in high-performance composite laminates
On the optical properties of Ag^{+15} ion-beam irradiated TiO_{2} and SnO_{2} thin films
The effects of 200-MeV Ag^{+15} ion irradiation on the optical properties of
TiO_{2} and SnO_{2} thin films prepared by using the RF magnetron sputtering
technique were investigated. These films were characterized by using UV-vis
spectroscopy, and with increasing irradiation fluence, the transmittance for
the TiO_{2} films was observed to increase systematically while that for
SnO_{2} was observed to decrease. Absorption spectra of the irradiated samples
showed minor changes in the indirect bandgap from 3.44 to 3.59 eV with
increasing irradiation fluence for TiO_{2} while significant changes in the
direct bandgap from 3.92 to 3.6 eV were observed for SnO_{2}. The observed
modifications in the optical properties of both the TiO_{2} and the SnO_{2}
systems with irradiation can be attributed to controlled structural
disorder/defects in the system.Comment: 6 pages, ICAMD-201
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