6 research outputs found

    Radiation Shielding And Optical Properties Of Added Bao And Wo3 To Bi2o3-Zno-B2o3-Sls Glass Network At Selective Photon Energy

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    In the current study, WO3 and BaO were added to Bi2O3-ZnO-B2O3-SLS glass to develop leadbrown. Furthermore, the Soda-Lime-Silica (SLS) glass waste used to limit the accumulation glass waste, which requires extensive time to decompose. This also saves on the consumption of pure SiO2, which is a finite resource. The meltquenching method was utilized to fabricate eleven glass samples. The structural, physical, optical, and attenuation characteristics were studied for current glass samples. The XRF results showed that SLS waste glass contained multi-chemical compounds such as 74.1% SiO2 and other minor elements

    Radiation parameterizations and optical characterizations for glass shielding composed of SLS waste glass and lead-free materials

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    The novelty in the present search, the Soda-Lime-Silica (SLS) glass waste to prepare free lead glass shielding was used in order to limit the accumulation of glass waste, which requires extensive time to decompose. This also saves on the consumption of pure SiO2, which is a finite resource. Furthermore, the combining of BaO with Bi2O3 into a glass network leads to increased optical properties and improved attenuation. The UV–Visible Spectrophotometer was used to investigate the optical properties and the radiation shielding properties were reported for current glass samples utilizing the PhysX/PDS online software. The optical property results indicate that when BaO content increases in glass structure, the Urbach energy ΔE, and refractive index n increases while the energy optical band gap Eopt decreases. The result of the metallisation criteria (M) revealed that the present glass samples are nonmetallic (insulators). Furthermore, the radiation shielding parameter findings suggest that when BaO was increased in the glass structure, the linear attenuation coefficient and effective atomic number (Zeff) rose. But the half-value layer HVL declined as the BaO concentration grew. According to the research, the glass samples are non-toxic, transparent to visible light, and efficient radiation shielding materials. The Ba5 sample is considered the best among all the samples due to its higher attenuation value and lower HVL and MFP values, which make it a suitable candidate as transparent glass shield shielding

    Development of Novel Transparent Radiation Shielding Glasses by BaO Doping in Waste Soda Lime Silica (SLS) Glass

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    In the current study, BaO was doped in Bi2O3-ZnO-B2O3-SLS glass to develop lead-free radiation shielding glasses and to solve the dark brown of bismuth glass. The melt-quenching method was utilized to fabricate (x) BaO (1 − x)[0.3 ZnO 0.2 Bi2O3 0.2 B2O3 0.3 SLS] (where x are 0.01, 0.02, 0.03, 0.04, and 0.05 mol) at 1200 °C. Soda lime silica glass waste (SLS), which is mostly composed of 74.1% SiO2, was used to obtain SiO2. The mass attenuation coefficient (μm) was investigated utilizing X-ray fluorescence (XRF) at 16.61, 17.74, 21.17, and 25.27 keV and narrow beam geometry at 59.54, 662, and 1333 keV. Moreover, the other parameters related to gamma ray shielding properties such as half-value layer (HVL), mean free path (MFP), and effective atomic number (Zeff) were computed depending on μm values. The results indicated that HVL and MFP decreased, whereas μm increased with an increase in BaO concentration. According to these results, it can be concluded that BaO doped in Bi2O3-ZnO-B2O3-SLS glass is a nontoxic, transparent to visible light, and a good shielding material against radiation

    Development of novel transparent radiation shielding glasses by BaO doping in waste soda lime silica (SLS) glass

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    In the current study, BaO was doped in Bi2O3-ZnO-B2O3-SLS glass to develop lead-free radiation shielding glasses and to solve the dark brown of bismuth glass. The melt-quenching method was utilized to fabricate (x) BaO (1 − x)[0.3 ZnO 0.2 Bi2O3 0.2 B2O3 0.3 SLS] (where x are 0.01, 0.02, 0.03, 0.04, and 0.05 mol) at 1200 °C. Soda lime silica glass waste (SLS), which is mostly composed of 74.1% SiO2, was used to obtain SiO2. The mass attenuation coefficient (μm) was investigated utilizing X-ray fluorescence (XRF) at 16.61, 17.74, 21.17, and 25.27 keV and narrow beam geometry at 59.54, 662, and 1333 keV. Moreover, the other parameters related to gamma ray shielding properties such as half-value layer (HVL), mean free path (MFP), and effective atomic number (Z e f f) were computed depending on μm values. The results indicated that HVL and MFP decreased, whereas μm increased with an increase in BaO concentration. According to these results, it can be concluded that BaO doped in Bi2O3-ZnO-B2O3-SLS glass is a nontoxic, transparent to visible light, and a good shielding material against radiation

    The Effect of WO<sub>3</sub>-Doped Soda Lime Silica SLS Waste Glass to Develop Lead-Free Glass as a Shielding Material against Radiation

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    The current study aims to enhance the efficiency of lead-free glass as a shielding material against radiation, solve the problem of the dark brown of bismuth glass, and reduce the accumulation of waste glass disposed in landfills by using soda-lime-silica SLS glass waste. The melt-quenching method was utilized to fabricate (WO3)x [(Bi2O3)0.2 (ZnO)0.3 (B2O3)0.2 (SLS)0.3]1−x at 1200 °C, where x = (0, 0.01, 0.02, 0.03, 0.04, and 0.05 mol). Soda lime silica SLS glass waste, which is mostly composed of 74.1 % SiO2, was used to obtain SiO2. Radiation Attenuation parameters were investigated using narrow-beam geometry and X-ray fluorescence (XRF). Furthermore, the parameters related to radiation shielding were calculated. The results showed that when WO3 concentration was increased, the half-value layer was reduced, whereas the μ increased. It could be concluded that WBiBZn-SLS glass is a good shielding material against radiation, nontoxic, and transparent to visible light

    Investigation of optical properties and radioactive attenuation parameters of doped tungsten oxide soda lime silica SLS waste glass

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    The optical properties and radioactive attenuation parameters of doped tungsten oxide soda-lime-silica (SLS) waste glass were investigated in the current work. A novel series of lead-free transparent glass samples were manufactured with the possibility of developing radiation-absorbing glass shielding materials. The glass composition is WO3–Bi2O3–ZnO–B2O3-SLS. A new approach was employed in the utilization of soda-lime-silica (SLS) glass as an alternative for pure silicon dioxide having 74.1% of SiO2 and other elements in it. The optical properties were investigated with the help of a UV–Visible Spectrophotometer. The results for the optical properties showed that when WO3 content is increased in the glass structure, the Urbach energy ΔE and refractive index n, increase from 0.337 to 0.431 and 2.84 to 2.94 respectively, the optical basicity Λ also increase with the increase in WO3 while the energy optical band gap Eopt registered a decrease. The metallization criterion (M) confirmed that the current glass samples are nonmetallic (insulator) because Rm/Vm < 1 which is confirmed in the condensed matter theory in the Lorentz–Lorenz equations. Moreover, the theoretical radiation shielding parameter results indicate that the linear attenuation coefficient μ and Zeff were increased with an increase in WO3. It can be seen also that the relationship between the μ and HVL is an inverse one; larger values of μ result in lesser thickness of the HVL. Whereas, as the WO3 concentration increases, the half-value layer HVL decreases. The results of this study demonstrate that the glass samples are harmless, transparent to visible light, and effective radiation shielding materials
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