1 research outputs found
Silica-Silver Nanocomposites as Regenerable Sorbents for Hg<sup>0</sup> Removal from Flue Gases
Silica-silver
nanocomposites (Ag-SBA-15) are a novel class of multifunctional
materials with potential applications as sorbents, catalysts, sensors,
and disinfectants. In this work, an innovative yet simple and robust
method of depositing silver nanoparticles on a mesoporous silica (SBA-15)
was developed. The synthesized Ag-SBA-15 was found to achieve a complete
capture of Hg<sup>0</sup> at temperatures up to 200 °C. Silver
nanoparticles on the SBA-15 were shown to be the critical active sites
for the capture of Hg<sup>0</sup> by the Ag–Hg<sup>0</sup> amalgamation
mechanism. An Hg<sup>0</sup> capture capacity as high as 13.2 mg·g<sup>–1</sup> was achieved by Ag(10)-SBA-15, which is much higher
than that achievable by existing Ag-based sorbents and comparable
with that achieved by commercial activated carbon. Even after exposure
to more complex simulated flue gas flow for 1 h, the Ag(10)-SBA-15
could still achieve an Hg<sup>0</sup> removal efficiency as high as
91.6% with a Hg<sup>0</sup> capture capacity of 457.3 μg·g<sup>–1</sup>. More importantly, the spent sorbent could be effectively
regenerated and reused without noticeable performance degradation
over five cycles. The excellent Hg<sup>0</sup> removal efficiency
combined with a simple synthesis procedure, strong tolerance to complex
flue gas environment, great thermal stability, and outstanding regeneration
capability make the Ag-SBA-15 a promising sorbent for practical applications
to Hg<sup>0</sup> capture from coal-fired flue gases