FeEDDHA-facilitated Fe uptake in relation to the behaviour of FeEDDHA components in the soil-plant system as a function of time and dosage.

FeEDDHA products are widely used to prevent and remedy Fe chlorosis in crops grown on calcareous soils. These products consist of a mixture of FeEDDHA components: racemic o,o-FeEDDHA, meso o,o-FeEDDHA, o,p-FeEDDHA and rest-FeEDDHA. The FeEDDHA components differ in physical and chemical properties, and as a consequence also in effectiveness as Fe fertilizer. In order to efficiently match dose, frequency and moment of FeEDDHA application with the Fe requirements of plants, it is important to understand the behaviour of the FeEDDHA components in the soil-plant system as a function of time and dosage, and to relate this behaviour to Fe uptake by plants. These issues have been examined in a pot trial study with soybean plants (Glycine max (L.) Merr. cv Mycogen 5072) grown on calcareous soil from Santomera, Spain. Four FeEDDHA treatments (two compositions, two dosages) were applied prior to the set in of chlorosis. Leaching of FeEDDHA components was prevented. Plant and soil were sampled every week, for six weeks. From one week onward the Fe concentration in the pore water was largely gouverned by racemic and meso o,o-FeEDDHA. The concentration behaviour of the o,o-FeEDDHA isomers underwent two stages: a strong decline within the first week resulting from linear adsorption, and a gradual decline from one week onward. For meso o,o-FeEDDHA, unlike racemic o,o-FeDDHA, the gradual decline could be mathematically well described with an exponential decay function. Soybean plants mainly took up Fe in the progressed vegetative stage (3rd and 4th week) and in the reproductive stage, when the pods were being filled with seeds (6th week). Fe uptake and removal of racemic o,o-FeEDDHA from the soil system display a similar time-trend, whereas the removal of meso o,o-FeEDDHA had a plant-independent character. This indicates the removal of racemic o,o-FeEDDHA is to a larger extent plant-relate

Chemical speciation of heavy metals in sandy soils in relation to availability and mobility

The environmental risk of heavy metals which are present in soil at a certain total content is highly dependent on soil properties. Chemical speciation is a comprehensive term for the distribution of heavy metals over all possible chemical forms (species) in soil solution and in the solid phase. The chemical behaviour of heavy metals depends among others on the quantity and type of sorption sites at the solid surface (e.g. organic matter) and environmental conditions (e.g. pH, competitors, complexes).In this thesis, emphasis is given to the effects of pH, solid and dissolved organic matter, inorganic complexation, and calcium competition on the speciation of the heavy metals cadmium and copper in sandy soils. For cadmium, inorganic complexation (e.g. by chloride) is of great importance whereas for copper organic complexation (dissolved organic matter) (DOC) is more important with respect to availability and mobility. Copper binding by dissolved organic matter (DOC) and by (soil) solid organic matter could be described well with the Non-Ideal Competitive Adsorption (NICA) model and with the Two Species Freundlich (TSF) model using parameters derived from purified humic acid.Both models accurately predicted the copper concentration at different depths in a field. Leaching experiments revealed that copper mobility depends on DOC concentration. DOC coagulation was described as a function of complexed cations such as aluminium, calcium, copper and protons. The long term effect of changes in soil pH, and solid and dissolved organic matter on copper mobility are illustrated using a dynamic soil (solution) composition balance approach. Understanding of the chemical behaviour of cadmium and copper makes it possible to estimate the availabile and mobile contaminant fraction from routine accessible parameters such as total content, pH and organic matter.</p

FeEDDHA-facilitated Fe uptake in relation to the behaviour of FeEDDHA components in the soil-plant system as a function of time and dosage.

FeEDDHA products are widely used to prevent and remedy Fe chlorosis in crops grown on calcareous soils. These products consist of a mixture of FeEDDHA components: racemic o,o-FeEDDHA, meso o,o-FeEDDHA, o,p-FeEDDHA and rest-FeEDDHA. The FeEDDHA components differ in physical and chemical properties, and as a consequence also in effectiveness as Fe fertilizer. In order to efficiently match dose, frequency and moment of FeEDDHA application with the Fe requirements of plants, it is important to understand the behaviour of the FeEDDHA components in the soil-plant system as a function of time and dosage, and to relate this behaviour to Fe uptake by plants. These issues have been examined in a pot trial study with soybean plants (Glycine max (L.) Merr. cv Mycogen 5072) grown on calcareous soil from Santomera, Spain. Four FeEDDHA treatments (two compositions, two dosages) were applied prior to the set in of chlorosis. Leaching of FeEDDHA components was prevented. Plant and soil were sampled every week, for six weeks. From one week onward the Fe concentration in the pore water was largely gouverned by racemic and meso o,o-FeEDDHA. The concentration behaviour of the o,o-FeEDDHA isomers underwent two stages: a strong decline within the first week resulting from linear adsorption, and a gradual decline from one week onward. For meso o,o-FeEDDHA, unlike racemic o,o-FeDDHA, the gradual decline could be mathematically well described with an exponential decay function. Soybean plants mainly took up Fe in the progressed vegetative stage (3rd and 4th week) and in the reproductive stage, when the pods were being filled with seeds (6th week). Fe uptake and removal of racemic o,o-FeEDDHA from the soil system display a similar time-trend, whereas the removal of meso o,o-FeEDDHA had a plant-independent character. This indicates the removal of racemic o,o-FeEDDHA is to a larger extent plant-relate

Naar een advies voor fosfaatbemesting op nieuwe leest. Dl. 1: Snijmaïs

De Commissie Bemesting Grasland en Voedergewassen heeft in 2006 geconcludeerd dat het advies voor snijmaïs niet langer voldoet, omdat het is gebaseerd op aardappelproeven en het advies vaak hoger is dan toegestaan is op basis van het P-gebruiksnormenstelsel. Vandaar dit het onderzoek, dat tot doel heeft een nieuwe adviessystematiek voor maïsland te ontwikkelen, die gebaseerd is op de directe P-beschikbaarheid en het P-naleverend vermogen van de bodem

Mobilization of heavy metals from contaminated paddy soil by EDDS, EDTA, and elemental sulfur

For enhanced phytoextraction, mobilization of heavy metals (HMs) from the soil solid phase to soil pore water is an important process. A pot incubation experiment mimicking field conditions was conducted to investigate the performance of three soil additives in mobilizing HMs from contaminated paddy soil (Gleyi-Stagnic Anthrosol): the [S, S]-isomer of ethylenediamine disuccinate (EDDS) with application rates of 2.3, 4.3, and 11.8 mmol kg¿1 of soil, ethylenediamine tetraacetate (EDTA; 1.4, 3.8, and 7.5 mmol kg¿1), and elemental sulfur (100, 200, and 400 mmol kg¿1). Temporal changes in soil pore water HM and dissolved organic carbon concentrations and pH were monitored for a period of 119 days. EDDS was the most effective additive in mobilizing soil Cu. However, EDDS was only effective during the first 24 to 52 days, and was readily biodegraded with a half-life of 4.1 to 8.7 days. The effectiveness of EDDS decreased at the highest application rate, most probably as a result of depletion of the readily desorbable Cu pool in soil. EDTA increased the concentrations of Cu, Pb, Zn, and Cd in the soil pore water, and remained effective during the whole incubation period due to its persistence. The highest rate of sulfur application led to a decrease in pH to around 4. This increased the pore water HM concentrations, especially those of Zn and Cd. Concentrations of HMs in the soil pore water can be regulated to a large extent by choosing the proper application rate of EDDS, EDTA, or sulfur. Hence, a preliminary work such as our pot experiment in combination with further plant experiments (not included in this study) will provide a good tool to evaluate the applicability of different soil additives for enhanced phytoextraction of a specific soil