Modification, Ablation and Hardening of Metallic Surfaces by a Cryogenic Nitrogen Jet

AbstractThis contribution gives the first results of an ongoing research aiming at developing a new surface treatment technique usinga supercritical nitrogen jet, named Jazolthop, for surface modification. As nitrogen is naturally recycled within air, this new process has a high potential for surface treatment without any chemical, physical or sewage effluents. This contribution shows that, pending on the operating condition, the technique can be used (i) under a stripping or ablation mode as well as, in a “less conventional” approach, (ii) for surface hardening.Illustration of the ablation mode is given for a Ti-6Al-4V alloy treated under static conditions using an intrusive jet. After 2min of treatment, a thickness of 200μm was removed from the surface by successive stripping out of micro-chips.Illustration of the hardening mode is given through the analysis of stainless steels treated under the cryogenic jet at a moving torch velocity of 5mm/min. The jet conditions were selected to be less intrusive and trigger the martensitic transformation without creating surface flaws of micro-cavities. In this case, the hardness of the steels was more than doubled after the passage of the cryogenic jet

Surface oxidation and phase transformation of the stainless steel by hybrid laser-waterjet impact

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Surface modification of polymer textile biomaterials by N2 supercritical jet: Preliminary mechanical and biological performance assessment

International audienceForeign Body Reaction (FBR) is a critical issue to be addressed when polyethylene terephthalate (PET) textile implants are considered in the medical field to treat pathologies involving hernia repair, revascularization strategies in arterial disease, and aneurysm or heart valve replacement. The natural porosity of textile materials tends to induce exaggerated tissue ingrowth which may prevent the implants from remaining flexible. One hypothesized way to limit the FBR process is to increase the material surface roughness at the yarn level. Supercritical N 2 (ScN 2) jet particle projection is a technique that provides enough velocity to particles in order to induce plastic deformation on the impacted surface. This work investigates the influence of ScN 2 jet projection parameters like standoff distance or particle size on the roughness that can be obtained on medical polymer yarns of various diameters (100 and 400 μm) and woven textile surfaces obtained from a 100 μm yarn. Moreover, the mechanical and biological performances of the obtained modified textile material are assessed. Results bring out that with appropriate testing conditions (500 bars jet/500 mm distance between nozzle and PET textile) and particle size around 50 μm, it is possible to generate 20 μm large and 4 μm deep craters on a 100 μm monofilament PET yarn and fabric. Regarding the strength of the textile material, it is only slightly modified with the treatment process, as the tenacity of the yarns decreases by only 10%. Moreover, It is shown that the obtained structures tend to limit the adhesion and slow down the proliferation of human fibroblasts

Effects of the impact of a low temperature nitrogen jet on metallic surfaces

International audienceThe technology of nitrogen jets impacting surfaces at low temperature has recently been introduced for surface cleaning/stripping. Under the impact of the jet, the material surface undergoes a thermomechanical shock inducing complex transformation mechanisms. Depending on the material and test parameters such as standoff distance, dwell time, upstream pressure, the latter include cleavage, cracking, spalling, blistering, grain fragmentation, phase transformation and ductile deformation. Quite often, these modes are superimposed in the same test, or even in the same material area. In this study, an overview of these mechanisms is proposed for metallic materials. Measurements of thermomechanical variables in the impacted area are presented and the influence of the test parameters on surface transformation is investigated. Grain fragmentation and ultrafast transport of nitrogen in a deep layer below the surface are explored

Cold Spray of Metallic Coatings on Polymer Based Composites for the Lightning Strike Protection of Airplane Structures

International audienceUnlike their metal counterparts, composite structures do not readily conduct away the electrical currents generated by lightning strikes. Cost reduction and expected production growth of the next middle range airplanes require automated manufacturing process of polymer components. The development of an automated technology to metallize polymer based composite for lightning strike protection is the aim of the CO3 project (EU Grant agreement: ID831979). In this study, thermal and electrical conductivities of composites were achieved by cold spray deposition of Cu or Al coatings. Critical points to be addressed were substrate erosion during cold spray, lack of polymer-metal adhesion and poor deposition efficiency. Several strategies were tested: i) a thin polymer film was cocured at the substrate surface before cold spraying, to enable implantation of metallic particles in the film, helping coating build-up and protecting the fibers of the composite. ii) Cold spraying a mix of metal and polymer powders to improve coating adhesion and prevent fiber damage. iii) Supercritical Nitrogen Deposition technology, prior to cold spray, to mechanically anchor metallic particles into the polymer. Subsequent cold spraying of purely metallic coatings was more efficient and showed better adhesion. All coatings were tested in terms of adhesion strength and electrical conductivity