1 research outputs found
Development of Magnetic Nanoparticles as Microwave-Specific Catalysts for the Rapid, Low-Temperature Synthesis of Formalin Solutions
A series of heterogeneous catalyst
materials possessing good microwave
absorption properties were investigated for their activity as oxidation
catalysts under microwave irradiation. These catalysts, a series of
nanoscale magnetic spinel oxides of the composition MCr<sub>2</sub>O<sub>4</sub> (M = Cu, Co, Fe), were irradiated in aqueous methanol
solution (1:1 MeOH:H<sub>2</sub>O v:v). This resulted in rapid conversion
of methanol to formaldehyde, directly generating aqueous formalin
solutions. The catalytic reaction occurred under relatively mild conditions
(1 atm O<sub>2</sub>, 60 °C), with irradiation times of 80 min
converting 24.5%, 17.7%, and 13.2% of the available methanol to formaldehyde
by the Cu, Fe, and Co chromite spinel catalysts, respectively. Importantly,
reactions run under identical conditions of concentration, time, and
temperature using traditional convective heating yielded dramatically
lower amounts of conversions; specifically, 1.0% and 0.21% conversions
were observed with Cu and Co spinels, and no observable thermal products
were obtained from the Fe spinels. This work provides a clear demonstration
that microwave-driven catalysis can yield enhanced reactivity and
can afford new catalytic pathways