Simulating Dispersion in the Evening-Transition Boundary Layer

This is the author accepted manuscript. The final version is available from Springer Verlag via the DOI in this recordWe investigate dispersion in the evening-transition boundary layer using large-eddy simulation (LES). In the LES, a particle model traces pollutant paths using a combination of the resolved flow velocities and a random displacement model to represent subgrid-scale motions. The LES is forced with both a sudden switch-off of the surface heat flux and also a more gradual observed evolution. The LES shows ‘lofting’ of plumes from near-surface releases in the pre-transition convective boundary layer; it also shows the subsequent ‘trapping’ of releases in the post-transition near-surface stable boundary layer and residual layer above. Given the paucity of observations for pollution dispersion in evening transitions, the LES proves a useful reference. We then use the LES to test and improve a one-dimensional Lagrangian Stochastic Model (LSM) such as is often used in practical dispersion studies. The LSM used here includes both time-varying and skewed turbulence statistics. It is forced with the vertical velocity variance, skewness and dissipation from the LES for particle releases at various heights and times in the evening transition. The LSM plume spreads are significantly larger than those from the LES in the post-transition stable boundary-layer trapping regime. The forcing from the LES was thus insufficient to constrain the plume evolution, and inclusion of the significant stratification effects was required. In the so-called modified LSM, a correction to the vertical velocity variance was included to represent the effect of stable stratification and the consequent presence of wave-like motions. The modified LSM shows improved trapping of particles in the post-transition stable boundary layer

In-situ thermally-reduced graphene oxide/epoxy composites: thermal and mechanical properties

Graphene has excellent mechanical, thermal, optical and electrical properties and this has made it a prime target for use as a filler material in the development of multifunctional polymeric composites. However, several challenges need to be overcome in order to take full advantage of the aforementioned properties of graphene. These include achieving good dispersion and interfacial properties between the graphene filler and the polymeric matrix. In the present work we report the thermal and mechanical properties of reduced graphene oxide/epoxy composites prepared via a facile, scalable and commercially-viable method. Electron micrographs of the composites demonstrate that the reduced graphene oxide (rGO) is well-dispersed throughout the composite. Although no improvements in glass transition temperature, tensile strength, and thermal stability in air of the composites were observed, good improvements in thermal conductivity (about 36%), tensile and storage moduli (more than 13%) were recorded with the addition of 2 wt% of rGO

The tensile fatigue behavior of a glass-fiber reinforced plastic composite using a hybrid-toughened epoxy matrix

ABSTRACT A thermosetting epoxy-polymer was modified by incorporating 9 wt.% of carboxyl-terminated butadiene-acrylonitrile (CTBN) rubber microparticles and 10 wt.% of silica nanoparticles. The tensile fatigue behaviour at a stress ratio, R = 0.1 for both the neat (i.e. unmodified) epoxy-polymer and the hybridepoxy polymer was first investigated. The fatigue life of the hybrid-epoxy * Corresponding author: Tel. +91-80-2508 6310 ; Fax: +91-80-2508 6301 E-mail address: [email protected] (CM Manjunatha) 2 polymer was about six to ten times higher than that the neat-epoxy polymer. Secondly, the neat and the hybrid-epoxy resins were infused into a quasiisotropic lay-up, E-glass fiber fabric via a 'Resin Infusion under Flexible Tooling' (RIFT) set-up to fabricate glass-fiber reinforced-plastic (GFRP) composite panels. The tensile fatigue tests at a stress ratio, R = 0.1 were performed on both of these GFRP composites during which the matrix cracking and stiffness degradation were routinely monitored. The fatigue life of the GFRP composite increased by about six to ten times due to employing the hybrid-epoxy matrix, compared to the neat-epoxy matrix. Suppressed matrix cracking and a reduced crack propagation rate were observed in the hybrid-epoxy matrix, which resulted from the various toughening micromechanisms induced by the presence of both the rubber microparticles and silica nanoparticles. These factors were considered to contribute towards the enhanced fatigue life which was observed for the GFRP composite employing the hybrid-epoxy matrix

The tensile fatigue behaviour of a silica nanoparticle-modified glass fibre reinforced epoxy composite

Abstract An anhydride-cured thermosetting epoxy polymer was modified by incorporating 10 wt.% of welldispersed 20 nm diameter silica nanoparticles. The stress-controlled tensile fatigue behaviour at a stress ratio of R = 0.1 was investigated for bulk specimens of the neat and the silica-modified epoxy. The addition of the silica nanoparticles increased the fatigue life by about three to four times. The neat and the nanoparticle-modified epoxy resins were used to fabricate glass fibre reinforced plastic (GFRP) composite laminates by resin infusion under flexible tooling (RIFT). Tensile fatigue tests were performed on these composites, during which the matrix cracking and stiffness degradation was monitored. The fatigue life of the GFRP composite was increased by about three to four times due to the silica nanoparticles. Suppressed matrix cracking and a reduced crack propagation rate in the nanoparticle-modified matrix were observed to contribute towards the enhanced fatigue life of the composite containing the silica nanoparticles

Surface functionalisation of nanodiamonds for human neural stem cell adhesion and proliferation.

Biological systems interact with nanostructured materials on a sub-cellular level. These interactions may govern cell behaviour and the precise control of a nanomaterial's structure and surface chemistry allow for a high degree of tunability to be achieved. Cells are surrounded by an extra-cellular matrix with nano-topographical properties. Diamond based materials, and specifically nanostructured diamond has attracted much attention due to its extreme electrical and mechanical properties, chemical inertness and biocompatibility. Here the interaction of nanodiamond monolayers with human Neural Stem Cells (hNSCs) has been investigated. The effect of altering surface functionalisation of nanodiamonds on hNSC adhesion and proliferation has shown that confluent cellular attachment occurs on oxygen terminated nanodiamonds (O-NDs), but not on hydrogen terminated nanodiamonds (H-NDs). Analysis of H and O-NDs by Atomic Force Microscopy, contact angle measurements and protein adsorption suggests that differences in topography, wettability, surface charge and protein adsorption of these surfaces may underlie the difference in cellular adhesion of hNSCs reported here

Tough nanoparticle-modified polymers

A crosslinked epoxy polymer has been modified by the addition of nano-silica particles. The particles were introduced via a sol-gel technique which gave a very well dispersed phase of nano-silica particles which were about 20 nm in diameter. The glass transition temperature was unchanged by the addition of the nanoparticles, but both the modulus and toughness were increased. The fracture energy, GIc, increased from 100 J/m 2 for the unmodified epoxy to 460 J/m2 for the epoxy with 20 wt. % of nano-silica. The microscopy studies showed evidence of debonding of the nanoparticles and subsequent plastic void growth of the epoxy polymer. A theoretical model of plastic void growth was used to confirm this mechanism. The cyclic-fatigue behaviour of the epoxy polymers has also been studied and the fatigue properties were clearly enhanced by the presence of the nano-silica particles. Indeed, it was found that the values of the strain-energy release rate at threshold, Gth, from the cyclic-fatigue tests increased steadily as the toughness, GIc, also increased, i.e. as the concentration of nano-silica particles was increased