PEMBUATAN KARBON AKTIF DARI TEMPURUNG KELAPA DENGAN AKTIVATOR NAOH SERTA APLIKASI ADSORPSI MERKURI MENGGUNAKAN KOLOM UNGGUN TETAP

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Propionic Anhydride Modification of Cellulosic Kenaf Fibre Enhancement with Bionanocarbon in Nanobiocomposites

The use of chemical modification of cellulosic fibre is applied in order to increase the hydrophobicity, hence improving the compatibility between the fibre and matrix bonding. In this study, the effect of propionic anhydride modification of kenaf fibre was investigated to determine the role of bionanocarbon from oil palm shell agricultural wastes in the improvement of the functional properties of bionanocomposites. The vinyl esters reinforced with unmodified and propionic anhydride modified kenaf fibres bio nanocomposites were prepared using 0, 1, 3, 5 wt% of bio-nanocarbon. Characterisation of the fabricated bionanocomposite was carried out using FESEM, TEM, FT-IR and TGA to investigate the morphological analysis, surface properties, functional and thermal analyses, respectively. Mechanical performance of bionanocomposites was evaluated according to standard methods. The chemical modification of cellulosic fibre with the incorporation of bionanocarbon in the matrix exhibited high enhancement of the tensile, flexural, and impact strengths, for approximately 63.91%, 49.61% and 54.82%, respectively. The morphological, structural and functional analyses revealed that better compatibility of the modified fibre–matrix interaction was achieved at 3% bionanocarbon loading, which indicated improved properties of the bionanocomposite. The nanocomposites exhibited high degradation temperature which signified good thermal stability properties. The improved properties of the bionanocomposite were attributed to the effect of the surface modification and bionanocarbon enhancement of the fibre–matrix networks

Improved Hydrophobicity of Macroalgae Biopolymer Film Incorporated with Kenaf Derived CNF Using Silane Coupling Agent

Hydrophilic behaviour of carrageenan macroalgae biopolymer, due to hydroxyl groups, has limited its applications, especially for packaging. In this study, macroalgae were reinforced with cellulose nanofibrils (CNFs) isolated from kenaf bast fibres. The macroalgae CNF film was after that treated with silane for hydrophobicity enhancement. The wettability and functional properties of unmodified macroalgae CNF films were compared with silane-modified macroalgae CNF films. Characterisation of the unmodified and modified biopolymers films was investigated. The atomic force microscope (AFM), SEM morphology, tensile properties, water contact angle, and thermal behaviour of the biofilms showed that the incorporation of Kenaf bast CNF remarkably increased the strength, moisture resistance, and thermal stability of the macroalgae biopolymer films. Moreover, the films’ modification using a silane coupling agent further enhanced the strength and thermal stability of the films apart from improved water-resistance of the biopolymer films compared to unmodified films. The morphology and AFM showed good interfacial interaction of the components of the biopolymer films. The modified biopolymer films exhibited significantly improved hydrophobic properties compared to the unmodified films due to the enhanced dispersion resulting from the silane treatment. The improved biopolymer films can potentially be utilised as packaging materials

Coffee Waste Macro-Particle Enhancement in Biopolymer Materials for Edible Packaging

Plastic pollution has raised interest in biodegradable and sustainable plastic alternatives. For edible food packaging, seaweed biopolymers have been studied for their film-forming properties. In this study, packaging films were developed using the solvent casting technique from natural red seaweed (Kappaphycus alvarezii) and coffee waste product. The physico-chemical and thermal properties of seaweed/coffee biopolymer films was obtained using dynamic light scattering (DLS), scanning electron microscopy (SEM), Fourier transmission irradiation (FT-IR), water contact angle measurement (WCA) and thermogravimetric analysis (TGA). The characterization study was carried out to improve the film’s morphological, thermal, and mechanical properties. The average particle size of coffee waste was found to be between 1.106 and 1.281 µm, with a zeta potential value of −27.0 mV indicating the compound’s strong negative charge. The SEM analysis revealed that the coffee filler was evenly dispersed in the polymer matrix, improving the film’s structural properties. The FT-IR result shows that coffee waste was successfully incorporated over the film matrix with the presence of a N-H bond. The hydrophobic property of the film was enhanced with the incorporation of coffee filler, indicating increased water contact angle compared to the neat film. The tensile properties of the biopolymer film were significantly improved at 4 wt% coffee powder with optimum tensile strength (35.47 MPa) with the addition of coffee waste powder. The incorporation of coffee waste into the seaweed matrix increased the functional properties of the fabricated biopolymer film. Thus, seaweed/coffee biopolymer film has the potential to be used in food packaging and other applications

Bionanocarbon Functional Material Characterisation and Enhancement Properties in Nonwoven Kenaf Fibre Nanocomposites

Bionanocarbon as a properties enhancement material in fibre reinforced nanobiocomposite was investigated for sustainable material applications. Currently, an extensive study using the micro size of biocarbon as filler or reinforcement materials has been done. However, poor fibre-matrix interface results in poor mechanical, physical, and thermal properties of the composite. Hence in this study, the nanoparticle of biocarbon was synthesised and applied as a functional material and properties enhancement in composite material. The bionanocarbon was prepared from an oil palm shell, an agriculture waste precursor, via a single-step activation technique. The nanocarbon filler loading was varied from 0, 1, 3, and 5% as nanoparticle properties enhancement in nonwoven kenaf fibre reinforcement in vinyl ester composite using resin transfer moulding technique. The functional properties were evaluated using TEM, particle size, zeta potential, and energy dispersion X-ray (EDX) elemental analysis. While the composite properties enhancement was evaluated using physical, mechanical, morphological, thermal, and wettability properties. The result indicated excellent nanofiller enhancement of fibre-matrix bonding that significantly improved the physical, mechanical, and thermal properties of the bionanocomposite. The SEM morphology study confirmed the uniform dispersion of the nanoparticle enhanced the fibre-matrix interaction. In this present work, the functional properties of bionanocarbon from oil palm shells (oil palm industrial waste) was incorporated in nanaobiocomposite, which significantly enhance its properties. The optimum enhancement of the bionanocomposite functional properties was obtained at 3% bionanocarbon loading. The improvement can be attributed to homogeneity and improved interfacial interaction between nanoparticles, kenaf fibre, and matrix

Functional Properties of Kenaf Bast Fibre Anhydride Modification Enhancement with Bionanocarbon in Polymer Nanobiocomposites

The miscibility between hydrophilic biofibre and hydrophobic matrix has been a challenge in developing polymer biocomposite. This study investigated the anhydride modification effect of propionic and succinic anhydrides on Kenaf fibre’s functional properties in vinyl ester bionanocomposites. Bionanocarbon from oil palm shell agricultural wastes enhanced nanofiller properties in the fibre-matrix interface via the resin transfer moulding technique. The succinylated fibre with the addition of the nanofiller in vinyl ester provided great improvement of the tensile, flexural, and impact strengths of 92.47 ± 1.19 MPa, 108.34 ± 1.40 MPa, and 8.94 ± 0.12 kJ m−2, respectively than the propionylated fibre. The physical, morphological, chemical structural, and thermal properties of bionanocomposites containing 3% bionanocarbon loading showed better enhancement properties. This enhancement was associated with the effect of the anhydride modification and the nanofiller’s homogeneity in bionanocarbon-Kenaf fibre-vinyl ester bonding. It appears that Kenaf fibre modified with propionic and succinic anhydrides incorporated with bionanocarbon can be successfully utilised as reinforcing materials in vinyl ester matrix

Extraction and Isolation of Cellulose Nanofibers from Carpet Wastes Using Supercritical Carbon Dioxide Approach

Cellulose nanofibers (CNFs) are the most advanced bio-nanomaterial utilized in various applications due to their unique physical and structural properties, renewability, biodegradability, and biocompatibility. It has been isolated from diverse sources including plants as well as textile wastes using different isolation techniques, such as acid hydrolysis, high-intensity ultrasonication, and steam explosion process. Here, we planned to extract and isolate CNFs from carpet wastes using a supercritical carbon dioxide (Sc.CO2) treatment approach. The mechanism of defibrillation and defragmentation caused by Sc.CO2 treatment was also explained. The morphological analysis of bleached fibers showed that Sc.CO2 treatment induced several longitudinal fractions along with each fiber due to the supercritical condition of temperature and pressure. Such conditions removed th fiber’s impurities and produced more fragile fibers compared to untreated samples. The particle size analysis and Transmission Electron Microscopes (TEM) confirm the effect of Sc.CO2 treatment. The average fiber length and diameter of Sc.CO2 treated CNFs were 53.72 and 7.14 nm, respectively. In comparison, untreated samples had longer fiber length and diameter (302.87 and 97.93 nm). The Sc.CO2-treated CNFs also had significantly higher thermal stability by more than 27% and zeta potential value of −38.9± 5.1 mV, compared to untreated CNFs (−33.1 ± 3.0 mV). The vibrational band frequency and chemical composition analysis data confirm the presence of cellulose function groups without any contamination with lignin and hemicellulose. The Sc.CO2 treatment method is a green approach for enhancing the isolation yield of CNFs from carpet wastes and produce better quality nanocellulose for advanced applications

Enhanced Functional Properties of Bioplastic Films Using Lignin Nanoparticles from Oil Palm-Processing Residue

The development of bioplastic materials that are biobased and/or degradable is commonly presented as an alleviating alternative, offering sustainable and eco-friendly properties over conventional petroleum-derived plastics. However, the hydrophobicity, water barrier, and antimicrobial properties of bioplastics have hindered their utilization in packaging applications. In this study, lignin nanoparticles (LNPs) with a purification process were used in different loadings as enhancements in a Kappaphycus alvarezii matrix to reduce the hydrophilic nature and improve antibacterial properties of the matrix and compared with unpurified LNPs. The influence of the incorporation of LNPs on functional properties of bioplastic films, such as morphology, surface roughness, structure, hydrophobicity, water barrier, antimicrobial, and biodegradability, was studied and found to be remarkably enhanced. Bioplastic film containing 5% purified LNPs showed the optimum enhancement in almost all of the ultimate performances. The enhancement is related to strong interfacial interaction between the LNPs and matrix, resulting in high compatibility of films. Bioplastic films could have additional advantages and provide breakthroughs in packaging materials for a wide range of applications

The role of cellulose nanofibrillated fibers produced with combined supercritical carbon dioxide and high-pressure homogenization process as reinforcement material in biodegradable polymer

The production of kenaf bast cellulose nanofibrillated fiber (CNF) using a combined method of supercritical carbon dioxide (SC-CO2) and high-pressure homogenization as the reinforcement with biopolymer were studied. The obtained CNF was used as reinforcement in polylactic acid using the solvent casting method. The obtained CNF were verified using TEM and FTIR analysis to approve the effectiveness of the technique. The dispersion of kenaf bast cellulose nanofibrillated fiber in modified PLA was studied with scanning electron microscopy and atomic force microscopy. Further characterization, such as, mechanical, thermal, and wettability properties of the composite was also analyzed. The TEM and FTIR confirmed the formation of nanofiber, and the FTIR result showed a typical bond present in cellulose nanofibrillated fiber. The SEM and AFM showed good dispersion of the kenaf bast cellulose nanofibrilated fiber in PLA. The mechanical and thermal properties of the composite were significantly improved compared with the neat PLA. The wettability showed that the addition of CNF increased the hydrophilicity of the sample. The production of CNF through combine methods displayed comparable properties to those produced from conventional methods and the CNF preparation method in this study is simplified and adaptable for potential industrial application.This work was supported by the Ministry of Culture and Education of the Republic of Indonesia by World Class Professor (WCP), Program 2020 Contract number: 101.26/E4.3/KU/2020. The authors would like to thank the collaboration between the Department of Mechanical Engineering, Universitas Syiah Kuala, Banda Aceh, Indonesia, Center for Advanced Materials, Qatar University, Qatar, Department of Chemical Engineering, Universitas Syiah Kuala, Banda, Indonesia, and School of Industrial Technology, Universiti Sains Malaysia, Penang, Malaysia that has made this work possible.Scopu