Mode-Coupling Theory of Colloids with Short-range Attractions

Within the framework of the mode-coupling theory of super-cooled liquids, we investigate new phenomena in colloidal systems on approach to their glass transitions. When the inter-particle potential contains an attractive part, besides the usual repulsive hard core, two intersecting liquid-glass transition lines appear, one of which extends to low densities, while the other one, at high densities, shows a re-entrant behaviour. In the glassy region a new type of transition appears between two different types of glasses. The complex phenomenology can be described in terms of higher order glass transition singularities. The various glass phases are characterised by means of their viscoelastic properties. The glass driven by attractions has been associated to particle gels, and the other glass is the well known repulsive colloidal glass. These correspondences, in associations with the new predictions of glassy behaviour mean that such phenomena may be expected in colloidal systems with, for example, strong depletion or other short-ranged attractive potentials.Comment: 17 pages, 8 figure

Scaling of dynamics with the range of interaction in short-range attractive colloids

We numerically study the dependence of the dynamics on the range of interaction $\Delta$ for the short-range square well potential. We find that, for small $\Delta$, dynamics scale exactly in the same way as thermodynamics, both for Newtonian and Brownian microscopic dynamics. For interaction ranges from a few percent down to the Baxter limit, the relative location of the attractive glass line and the liquid-gas line does not depend on $\Delta$. This proves that in this class of potentials, disordered arrested states (gels) can be generated only as a result of a kinetically arrested phase separation.Comment: 4 pages, 4 figure

Numerical study of the glass-glass transition in short-ranged attractive colloids

We report extensive numerical simulations in the {\it glass} region for a simple model of short-ranged attractive colloids, the square well model. We investigate the behavior of the density autocorrelation function and of the static structure factor in the region of temperatures and packing fractions where a glass-glass transition is expected according to theoretical predictions. We strengthen our observations by studying both waiting time and history dependence of the numerical results. We provide evidence supporting the possibility that activated bond-breaking processes destabilize the attractive glass, preventing the full observation of a sharp glass-glass kinetic transition.Comment: 15 pages, 9 figures; Proceedings of "Structural Arrest Transitions in Colloidal Systems with Short-Range Attractions", Messina, Italy, December 2003 (submitted to J. Phys.: Condens. Matt.

Gravitational time advancement and its possible detection

The gravitational time advancement is a natural but a consequence of curve space-time geometry. In the present work the expressions of gravitational time advancement have been obtained for geodesic motions. The situation when the distance of signal travel is small in comparison to the distance of closest approach has also been considered. The possibility of experimental detection of time advancement effect has been explored.Comment: 5 pages, 4 figures, a part of the work has been changed in the revised versio

On the time delay in binary systems

The aim of this paper is to study the time delay on electromagnetic signals propagating across a binary stellar system. We focus on the antisymmetric gravitomagnetic contribution due to the angular momentum of one of the stars of the pair. Considering a pulsar as the source of the signals, the effect would be manifest both in the arrival times of the pulses and in the frequency shift of their Fourier spectra. We derive the appropriate formulas and we discuss the influence of different configurations on the observability of gravitomagnetic effects. We argue that the recently discovered PSR J0737-3039 binary system does not permit the detection of the effects because of the large size of the eclipsed region.Comment: 7 pages, 2 eps figures, RevTex, to appear in Physical Review

In silico, in vitro, and in vivo approaches to identify molecular players in fragile X tremor and Ataxia syndrome

Fragile X-associated tremor/ataxia syndrome (FXTAS) is a late-onset neurodegenerative monogenetic disorder affecting carriers of premutation (PM) forms of the FMR1 gene, resulting in a progressive development of tremors, ataxia, and neuropsychological problems. This highly disabling disease is quite common in the general population with an estimation of about 20 million PM carriers worldwide. The chances of developing FXTAS increase dramatically with age, with about 45% of male carriers over the age of 50 being affected. Both the gene and pathogenic trigger, a mutant expansion of CGG RNA, causing FXTAS are known. This makes it an interesting disease to develop targeted therapeutic interventions for. Yet, no such interventions are available at this moment. Here we discuss in silico, in vitro, and in vivo approaches and how they have been used to identify the molecular determinants of FXTAS pathology. These approaches have yielded substantial information about FXTAS pathology and, consequently, many markers have emerged to play a key role in understanding the disease mechanism. Integration of the different approaches is expected to provide crucial information about the value of these markers as either therapeutic target or biomarker, essential to monitor therapeutic interventions in the future

Anisotropic lattice compression and pressure-induced electronic phase transitions in Sr2IrO4

FUNDAÇÃO DE AMPARO À PESQUISA DO ESTADO DE SÃO PAULO - FAPESPCONSELHO NACIONAL DE DESENVOLVIMENTO CIENTÍFICO E TECNOLÓGICO - CNPQThe crystal lattice of Sr2IrO4 is investigated with synchrotron x-ray powder diffraction under hydrostatic pressures up to P = 43 GPa and temperatures down to 20 K. The tetragonal unit cell is maintained over the whole investigated pressure range, within101716FUNDAÇÃO DE AMPARO À PESQUISA DO ESTADO DE SÃO PAULO - FAPESPCONSELHO NACIONAL DE DESENVOLVIMENTO CIENTÍFICO E TECNOLÓGICO - CNPQFUNDAÇÃO DE AMPARO À PESQUISA DO ESTADO DE SÃO PAULO - FAPESPCONSELHO NACIONAL DE DESENVOLVIMENTO CIENTÍFICO E TECNOLÓGICO - CNPQ2016/00756-62017/10581-12018/20142-8308607/2018-0409504/2018-1We thank D. Haskel and G. Fabbris for illuminating discussions and for sharing unpublished data, and M. Eleotério, J. Fonseca Júnior, and R. D. Reis for technical assistance. LNLS is acknowledged for concession of beamtime. This work was supported by Fap

Gaussian density fluctuations and Mode Coupling Theory for supercooled liquids

The equations of motion for the density modes of a fluid, derived from Newton's equations, are written as a linear generalized Langevin equation. The constraint imposed by the fluctuation-dissipation theorem is used to derive an exact form for the memory function. The resulting equations, solved under the assumption that the noise, and consequently density fluctuations, of the liquid are gaussian distributed, are equivalent to the random-phase-approximation for the static structure factor and to the well known ideal mode coupling theory (MCT) equations for the dynamics. This finding suggests that MCT is the canonical mean-field theory of the fluid dynamics.Comment: 4 pages, REVTE