Structure, Morphology and Color Tone Properties of theNeodymium Substituted Hematite

Co-precipitation method has been employed to fabricate neodymium substituted hematite with different compositions from the aqueous solution of their corresponding metal salts. Thermal analysis and X-ray diffraction studies revealed the coexistence of Fe(2)O(3) and Nd(2)O(3) phases up to 1050℃ and formation of solid solution phase among them at 1100℃ and above temperatures, which was evidenced by shifting of the XRD peaks. Unit cell parameters and the cell volumes of the samples were found to increase by adding Nd(3+) ions in the reaction process. FESEM studies showed the suppression of particle growth due to the presence of Nd(3+) ions. Spectroscopic measurement evidenced that neodymium substituted hematite exhibited brighter yellowish red color tone than that of pure α-Fe(2)O(3)

Synthesis and characterization of cerium substituted hematite by sol-gel method

Fine particles of cerium substituted hematite with different compositions were prepared by the sol-gel method from the aqueous solution of their corresponding metal salts. Mixed hydroxides of Fe3+ and Ce4+ were obtained by reacting aqueous NH3 with the aqueous solution of FeCl3 and Ce(NH3)(2)(NO3)(6) at pH 2.5-3.0) and they were heat treated at different temperatures between 400 and 1200 degrees C in air for 2 h to get the mixed oxide product. Thermal analysis and X-ray diffraction studies revealed the coexistence of Fe2O3 and CeO2 phase separately up to 900 degrees C, and covalent interaction between them above 1000 degrees C, which was evidenced by the shifting of the XRD peaks. Unit cell parameters and the cell volumes (V) of the samples derived between 1000 and 1200 degrees C were found to be in the range a=5.045-5.048 +/- 0.007 angstrom, c=13.774-13.815 +/- 0.041 angstrom and V=303.608-304.874 angstrom(3) respectively. It was observed that both the lattice parameters and the cell volumes were higher than that of the pure alpha-Fe2O3 (a =5.036 angstrom, c = 13.749 angstrom, V=301.976 angstrom(3)) system. The expansion of lattice parameters further supported the incorporation of the large Ce4+ ion into the alpha-Fe2O3 matrix. The lattice parameter increased with increasing Ce4+ ion loading. FESEM studies showed the growth of the particles with increasing temperature though it was suppressed due to the presence of Ce4+ ions as compared to the pure system. (C) 2005 Elsevier B.V. All rights reservedclose