Crossover from commensurate to incommensurate antiferromagnetism in stoichiometric NaFeAs revealed by single-crystal 23Na,75As-NMR experiments

We report results of 23Na and 75As nuclear magnetic resonance (NMR) experiments on a self-flux grown high-quality single crystal of stoichiometric NaFeAs. The NMR spectra revealed a tetragonal to twinned-orthorhombic structural phase transition at T_O = 57 K and an antiferromagnetic (AF) transition at T_AF = 45 K. The divergent behavior of nuclear relaxation rate near T_AF shows significant anisotropy, indicating that the critical slowing down of stripe-type AF fluctuations are strongly anisotropic in spin space. The NMR spectra at low enough temperatures consist of sharp peaks showing a commensurate stripe AF order with a small moment \sim 0.3 muB. However, the spectra just below T_AF exhibits highly asymmetric broadening pointing to an incommensurate modulation. The commensurate-incommensurate crossover in NaFeAs shows a certain similarity to the behavior of SrFe2As2 under high pressure.Comment: 5 pages, 5 figures, revised version to appear in J. Phys. Soc. Jp

Pressure shift of the superconducting T_c of LiFeAs

The effect of hydrostatic pressure on the superconductivity in LiFeAs is investigated up to 1.8 GPa. The superconducting transition temperature, T_c, decreases linearly with pressure at a rate of 1.5 K/GPa. The negative pressure coefficient of T_c and the high ambient pressure T_c indicate that LiFeAs is the high-pressure analogue of the isoelectronic SrFe_2As_2 and BaFe_2As_2.Comment: 3 pages, 2 figure

First-Principles Study for the Anisotropy of Iron-based Superconductors toward Power and Device Applications

Performing the first-principles calculations, we investigate the anisotropy in the superconducting state of iron-based superconductors to gain an insight into their potential applications. The anisotropy ratio $\gamma_\lambda$ of the c-axis penetration depth to the ab-plane one is relatively small in BaFe2As2 and LiFeAs, i.e., $\gamma_\lambda \sim 3$, indicating that the transport applications are promising in these superconductors. On the other hand, in those having perovskite type blocking layers such as Sr2ScFePO3 we find a very large value, $\gamma_\lambda \sim 200$, comparable to that in strongly anisotropic high-Tc cuprate Bi2Sr2CaCu2O{8-\delta}. Thus, the intrinsic Josephson junction stacks are expected to be formed along the c-axis, and novel Josephson effects due to the multi-gap nature are also suggested in these superconductors.Comment: 5 pages, 4 figure

Nutritional factors and gender influence age-related DNA methylation in the human rectal mucosa

Aberrant methylation of CpG islands (CGI) occurs in many genes expressed in colonic epithelial cells, and may contribute to the dysregulation of signalling pathways associated with carcinogenesis. This cross-sectional study assessed the relative importance of age, nutritional exposures and other environmental factors in the development of CGI methylation. Rectal biopsies were obtained from 185 individuals (84 male, 101 female) shown to be free of colorectal disease, and for whom measurements of age, body size, nutritional status and blood cell counts were available. We used quantitative DNA methylation analysis combined with multivariate modelling to investigate the relationships between nutritional, anthropometric and metabolic factors and the CGI methylation of 11 genes, together with LINE-1 as an index of global DNA methylation. Age was a consistent predictor of CGI methylation for 9/11 genes but significant positive associations with folate status and negative associations with vitamin D and selenium status were also identified for several genes. There was evidence for positive associations with blood monocyte levels and anthropometric factors for some genes. In general, CGI methylation was higher in males than in females and differential effects of age and other factors on methylation in males and females were identified. In conclusion, levels of age-related CGI methylation in the healthy human rectal mucosa are influenced by gender, the availability of folate, vitamin D and selenium, and perhaps by factors related to systemic inflammatio

Private quantum decoupling and secure disposal of information

Given a bipartite system, correlations between its subsystems can be understood as information that each one carries about the other. In order to give a model-independent description of secure information disposal, we propose the paradigm of private quantum decoupling, corresponding to locally reducing correlations in a given bipartite quantum state without transferring them to the environment. In this framework, the concept of private local randomness naturally arises as a resource, and total correlations get divided into eliminable and ineliminable ones. We prove upper and lower bounds on the amount of ineliminable correlations present in an arbitrary bipartite state, and show that, in tripartite pure states, ineliminable correlations satisfy a monogamy constraint, making apparent their quantum nature. A relation with entanglement theory is provided by showing that ineliminable correlations constitute an entanglement parameter. In the limit of infinitely many copies of the initial state provided, we compute the regularized ineliminable correlations to be measured by the coherent information, which is thus equipped with a new operational interpretation. In particular, our results imply that two subsystems can be privately decoupled if their joint state is separable.Comment: Child of 0807.3594 v2: minor changes v3: presentation improved, one figure added v4: extended version with a lot of discussions and examples v5: published versio

Contrast of LiFeAs with isostructural, isoelectronic, and non-superconducting MgFeGe

Stoichiometric LiFeAs at ambient pressure is an 18 K superconductor while isoelectronic MgFeGe is not, despite their extremely similar electronic structures. To investigate possible sources of this distinctively different superconducting behavior, we quantify the differences using first principles density functional theory, establishing first that the Fe total 3d occupations are identical in the two compounds. Individual 3d orbital occupations also differ very little ($\sim 0.01$). The differences in Fermi surfaces (FSs) do not seem significant; however a redistribution of bands just above the Fermi level does represent a possibly significant distinction. Because the bands and FSs of LiFeAs are less in agreement with experiment than for other iron-pnictides, we study the effects of additional exchange-correlations effects beyond GGA (the generalized gradient approximation) by applying the modified Becke-Johnson potential (mBJ) exchange potential, which gives much improved bandgaps in insulators compared to GGA and might be useful for semimetals such as the Fe-based superconductors. Overall, we conclude that the mBJ corrections do not improve the description of LiFeAs as compared to experiment

The Role of Disgust in Male Sexual Decision-Making

Sexual arousal is known to increase risky behaviors, such as having unprotected sex. This may in part relate to the emotion of disgust, which normally serves a disease avoidant function, and is suppressed by sexual arousal. In this report we examine disgust's role in sexual decision-making. Male participants received two study packets that were to be completed at home across two different time-points. Participants were asked to complete one packet in a sexually aroused state and the other in a non-aroused state. Participants were asked to rate: (1) arousal, (2) disgust, (3) willingness for sex, and (4) disease risk toward a range of female targets, which varied in level of potential disease risk (sex-worker vs. non sex-worker) and attractiveness. A measure of trait disgust was also included along with other related scales. Sexual arousal was associated with reduced disgust and reduced judgments of disease risk for all targets—these latter two variables being correlated—and with enhanced willingness to have sex with all of the depicted persons. Willingness to have sex when aroused (in contrast to non-aroused) was predicted by disease risk judgments and trait disgust, suggesting both direct (state) and indirect (trait) effects of disgust on sexual decision-making

Perturbation Theory of High-Tc Superconductivity in Iron Pnictides

The high-transition-temperature (high-Tc) superconductivity discovered recently in iron pnictides is analyzed within a perturbation theory. Specifically, the probable pairing symmetry, the doping dependence of the transition temperature and the pairing mechanism are studied by solving the Eliashberg equation for multi-band (2- and 5-band) Hubbard models with realistic electronic structures. The effective pairing interaction is expanded perturbatively in the on-site Coulomb integrals up to third order. Our perturbative weak-coupling approach shows that sufficiently large eigenvalues of the Eliashberg equation are obtained to explain the actual high transition temperatures by taking realistic on-site Coulomb integrals in the 5-band model. Thus, unconventional (non-phonon-mediated) superconductivity is highly likely to be realized. The superconducting order parameter does not change its sign on the Fermi surfaces, but it does change between the electron and hole Fermi surfaces. Consequently, the probable pairing symmetry is always "a nodeless extended s-wave symmetry (more specifically, an s_{+-}-wave symmetry)" over the whole parameter region that we investigated. It is suggested that the 2-band model is insufficient to explain the high values of Tc.Comment: 24 pages, 9 figure

Heavy anion solvation of polarity fluctuations in Pnictides

Once again the condensed matter world has been surprised by the discovery of yet another class of high temperature superconductors. The discovery of iron-pnictide (FeAs) and chalcogenide (FeSe) based superconductors with a $T_c$ of up to 55 K is again evidence of how complex the many body problem really is, or in another view how resourceful nature is. The first reactions would of course be that these new materials must in some way be related to the copper-oxide based superconductors for which a large number of theories exist although a general consensus regarding the correct theory has not yet been reached. Here we point out that the basic physical paradigm of the new iron based superconductors is entirely different from the cuprates. Their fundamental properties, structural and electronic, are dominated by the exceptionally large pnictide polarizabilities

Pair-Hopping Mechanism for Layered Superconductors

We propose a possible charge fluctuation effect expected in layered superconducting materials. In the multireference density functional theory, relevant fluctuation channels for the Josephson coupling between superconducting layers include the interlayer pair hopping derived from the Coulomb repulsion. When interlayer single-electron tunneling processes are irrelevant in the Kohn-Sham electronic band structure calculation, the two-body effective interactions stabilize a superconducting phase. This state is also regarded as a valence-bond solid in a bulk electronic state. The hidden order parameters coexist with the superconducting order parameter when the charging effect of a layer is comparable to the pair hopping. Relevant materials structures favorable for the pair-hopping mechanism are discussed.Comment: 24 pages, 2 figures, to be published in J. Phys. Soc. Jpn. (2009