Merging Filaments and Hub Formation in the G083.097++03.270 Molecular Complex

We uncover a hub-filament system associated with massive star formation in the G083.097$+$03.270. Diagnosed with simultaneous $^{12}$CO, $^{13}$CO, and C$^{18}$O line observations, the region is found to host two distinct and elongated filaments having separate velocity components, interacting spatially and kinematically, that appear to have seeded the formation of a dense hub at the intersection. A large velocity spread at the hub in addition to clear bridging feature connecting the filaments in velocity are indicating merging of filaments. Along the filaments axis, the velocity gradient reveals a global gas motion with an increasing velocity dispersion inward to the hub signifying turbulence. Altogether, the clustering of Class I sources, a high excitation temperature, a high column density, and presence of a massive outflow at the central hub suggest enhanced star formation. We propose that merging of large-scale filaments and velocity gradients along filaments are the driving factors in the mass accumulation process at the hub that have sequentially led to the massive star formation. With two giant filaments merging to coincide with a hub therein with ongoing star formation, this site serves as a benchmark for the `filaments to clusters' star-forming paradigm.Comment: 12 pages, 7 figures, 1 table, accepted for publication in Ap

Modeling the time-resolved quasi-periodic oscillations in AGNs

Observation of the bright Seyfert 1 galaxy RE J1034+396 is believed to demonstrate a drift of the central period of the Quasi Periodic Oscillation (QPO) linearly correlated with the temporary X-ray luminosity. We show, using a specific scenario of the oscillation mechanism in black hole accretion disc, that modeling such correlated trends puts very strong constraints on the nature of this oscillation and the characteristic features of the hot flow in Active Galactic Nuclei (AGN). In our model, QPO oscillations are due to the oscillations of the shock formed in the low angular momentum hot accretion flow, and the variation of the shock location corresponds to the observed changes in the QPO period and the X-ray flux. In this scenario, change in the shock location caused by perturbation of the flow angular momentum is compatible with the trends observed in RE J1034+396, whereas the perturbation of the specific flow energy results in too strong flux response to the change of the oscillation period. Using a complete general relativistic framework to study the accretion flow in the Kerr metric, we discuss the role of the black hole spin in the period drift. Future missions are expected to bring more active galaxies with time-resolved quasi-periodic oscillations so similar quantitative study for other QPO scenarios will be necessary.Comment: Final version accepted for publication in MNRAS. Several modifications made. Eight pages. Six colour figure

An Expeditious and Safe Synthesis of Some Exocyclic α,β-Unsaturated Ketones by Microwave-Assisted Condensation of Cyclic Ketones with Aromatic Aldehydes over Anhydrous Potassium Carbonate

A rapid, efficient, and solvent-free methodology for synthesis of exocyclic α,β-unsaturated ketones of the categories E-3-arylidene-4-chromanones, E-2-arylidene-1-tetralones, E-2-arylidene-1-indanones, E-3-cinnamylidene-4-chromanones, E-2-cinnamylidene-1-tetralones, E-2-cinnamylidene-1-indanones, α,α′-(E,E)-bis(arylidene)-cycloalkanones, and α,α′-(E,E)-bis(cinnamylidene)-cycloalkanones has been developed through cross-aldol condensation of the constituent cyclic ketones and aldehydes by microwave irradiation over anhydrous potassium carbonate. However, for condensation of 1-thio-4-chromanones with aromatic aldehydes by this method, the initially formed exocyclic α,β-unsaturated ketone has been found to undergo isomerization yielding 3-(arylmethyl)thiochromones

Facile Condensation of Aromatic Aldehydes with Chroman-4-ones and 1-Thiochroman-4-ones Catalysed by Amberlyst-15 under Microwave Irradiation Condition

Different aromatic aldehydes and cinnamaldehyde undergo cross-aldol condensation with chroman-4-ones and1-thiochroman-4-ones in the presence of amberlyst-15 under microwave irradiation in solvent free condition to afford rapidly the corresponding E-3-arylidene and E-3-cinnamylidene derivatives, respectively, in high yield. This process is simple, efficient and environmentally benign

Schmidt Reaction of E-3-Benzylidenechromanones and E-3-Benzylidenethiochromanones

On treatment with NaN3/c. H2SO4-HOAc or NaN3/TFA, E-3-benzylidenechromanones are mostly converted to E-β-aminobenzylidenechromanones while E-3-benzylidenethiochromanones are converted to 3-benzoylthiochromones. A structurally new type of product has been isolated for the reaction of E-3-benzylidene-4′-methoxychromanone with NaN3/TFA. Mechanistic paths have been suggested for formation of the products

Erythrocytic oxidative stress indices, biochemical and trace mineral milieu in yaks with persistent haemorrhagic diarrhoea associated with enterovirulent Escherichia coli

The present study was designed to enumerate the antioxidant status and trace mineral profile of yaks with haemorrhagic diarrhoea associated with enterovirulent E. coli. The study was conducted in 15 yaks with haemorrhagic diarrhoea and with PCR based evidence for enteropathogenic E. coli (EPEC) and enterotoxigenic E. coli (ETEC) infection. A significant rise of ALT activity, marginally significant increase of BUN and serum creatinine level, marginally significant fall of blood glucose level, and no significant changes in AST activity and serum protein were recorded in affected yaks. Persistent haemorrhagic diarrhoea resulted into significant increase in MDA, protein carbonylation and reactive nitrogen species level, but decreased SOD and catalase activity. Iron, copper and zinc concentrations in plasma were reduced, whereas cobalt and mnganese concentrations remain unaltered in the affected population.</p