A novel cfd code based on method of lines for reacting flows: Verification on methane/air diffusion flame

A novel parallel computational fluid dynamic (CFD) code based on method of lines (MOL) approach was developed for the numerical simulation of multi-component reacting flows using detailed transport and thermodynamic models. The code was applied to the prediction of a confined axi-symmetric laminar co-flowing methane-air diffusion flame for which experimental data were available in the literature. 1-, 5- and 10-step reduced finite-rate reaction mechanisms were employed for methane-air combustion sub-model. Steady-state velocity, temperature and species profiles obtained by all the mechanisms were validated against experimental data and were found to be in reasonably good agreement with measurements. The code was found to be a useful tool for the prediction and understanding of transient combustion systems

Transient simulation of reacting radiating flows

Laminar methane-air diffusion flame was simulated by coupling a method of lines based parallel direct numerical simulation code with a radiation code based on method of lines solution of discrete ordinates method. The predictions of the code are validated against experimental data as well as numerical results of the same code without radiation model. Comparisons show that incorporation of radiation code to the computational fluid dynamics code results in a significant improvement in the predicted temperatures. Transient results exhibit the physically expected trends. The coupled code is a promising tool for the simulation of transient reacting radiating flows. (c) 2006 Elsevier SAS. All rights reserved

International Comparison EURO.QM-S5 / 1166: Carbon Dioxide Mixtures in Nitrogen Final report

This supplementary comparison is designed to test the capabilities of the participants to measure and certify carbon dioxide in nitrogen, and to provide supporting evidence for the CMCs of institutes for carbon dioxide. Indeed this comparison aims to demonstrate the capabilities of IPQ in the production of primary gas mixtures of carbon dioxide in nitrogen and for the participant laboratories to demonstrate their capabilities on certifying primary gas mixtures of percent levels of carbon dioxide in nitrogen

CCQM-K120 (Carbon dioxide at background and urban level)

CCQM-K120.a comparison involves preparing standards of carbon dioxide in air which are fit for purpose for the atmospheric monitoring community, with stringent requirements on matrix composition and measurement uncertainty of the CO2 mole fraction. This represents an analytical challenge and is therefore considered as a Track C comparison. The comparison will underpin CMC claims for CO2 in air for standards and calibrations services for the atmospheric monitoring community, matrix matched to real air, over the mole fraction range of 250 μmol/mol to 520 μmol/mol. CCQM-K120.b comparison tests core skills and competencies required in gravimetric preparation, analytical certification and purity analysis. It is considered as a Track A comparison. It will underpin CO2 in air and nitrogen claims in a mole fraction range starting at the smallest participant's reported expanded uncertainty and ending at 500 mmol/mol. Participants successful in this comparison may use their result in the flexible scheme and underpin claims for all core mixtures This study has involved a comparison at the BIPM of a suite of 44 gas standards prepared by each of the participating laboratories. Fourteen laboratories took part in both comparisons (CCQM-K120.a, CCQM-K120.b) and just one solely in the CCQM-K120.b comparison. The standards were sent to the BIPM where the comparison measurements were performed. Two measurement methods were used to compare the standards, to ensure no measurement method dependant bias: GC-FID and FTIR spectroscopic analysis corrected for isotopic variation in the CO2 gases, measured at the BIPM using absorption laser spectroscopy. Following the advice of the CCQM Gas Analysis Working Group, results from the FTIR method were used to calculate the key comparison reference values