1,567 research outputs found

    Ultralong Copper Phthalocyanine Nanowires with New Crystal Structure and Broad Optical Absorption

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    The development of molecular nanostructures plays a major role in emerging organic electronic applications, as it leads to improved performance and is compatible with our increasing need for miniaturisation. In particular, nanowires have been obtained from solution or vapour phase and have displayed high conductivity, or large interfacial areas in solar cells. In all cases however, the crystal structure remains as in films or bulk, and the exploitation of wires requires extensive post-growth manipulation as their orientations are random. Here we report copper phthalocyanine (CuPc) nanowires with diameters of 10-100 nm, high directionality and unprecedented aspect ratios. We demonstrate that they adopt a new crystal phase, designated eta-CuPc, where the molecules stack along the long axis. The resulting high electronic overlap along the centimetre length stacks achieved in our wires mediates antiferromagnetic couplings and broadens the optical absorption spectrum. The ability to fabricate ultralong, flexible metal phthalocyanine nanowires opens new possibilities for applications of these simple molecules

    Associations of apolipoprotein E exon 4 and lipoprotein lipase S447X polymorphisms with acute ischemic stroke and myocardial infarction

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    Background: Because apolipoprotein E (apoE) and lipopoprotein lipase (LPL) polymorphisms interact with each other and with other factors to affect lipid metabolism, we sought to determine their separate and combined effects in association with ischemic vascular disease. Methods: We performed a case-control study of 816 subjects: 246 acute ischemic stroke patients, 234 acute myocardial infarction patients, and 336 controls. APOE exon 4 and LPL S447X genotypes were determined. Results: APOE ε2 and ε4 homozygotes were increased in stroke (4.5% vs. 1.0%, p = 0.008), while in myocardial infarction the ε4 allele was increased (12.6% vs. 9.5%, p = 0.006) but ε2 was decreased (3.7% vs. 12.1%, p = 0.000006). For subjects with either APOE ε2 or ε4 alleles, LPL X alleles were increased in vascular disease (OR = 2.2, p = 0.01). LPL X alleles displayed opposite tendencies toward association with disease when subjects were divided by sex, smoking, or APOE genotype. Meta-analysis and regression analysis of previous studies supported the sex and smoking dichotomies. Conclusion: This is the first report of an association of vascular disease with an interaction of APOE exon 4 and LPL S447X genotypes. Therefore, APOE genotypes and LPL S447X interactions with apoE, sex, and smoking may affect the risk of myocardial infarction and ischemic stroke. © 2006 by Walter de Gruyter.published_or_final_versio

    First Observation of PP-odd γ\gamma Asymmetry in Polarized Neutron Capture on Hydrogen

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    We report the first observation of the parity-violating 2.2 MeV gamma-ray asymmetry AγnpA^{np}_\gamma in neutron-proton capture using polarized cold neutrons incident on a liquid parahydrogen target at the Spallation Neutron Source at Oak Ridge National Laboratory. AγnpA^{np}_\gamma isolates the ΔI=1\Delta I=1, \mbox{3S13P1^{3}S_{1}\rightarrow {^{3}P_{1}}} component of the weak nucleon-nucleon interaction, which is dominated by pion exchange and can be directly related to a single coupling constant in either the DDH meson exchange model or pionless EFT. We measured Aγnp=[3.0±1.4(stat)±0.2(sys)]×108A^{np}_\gamma = [-3.0 \pm 1.4 (stat) \pm 0.2 (sys)]\times 10^{-8}, which implies a DDH weak πNN\pi NN coupling of hπ1=[2.6±1.2(stat)±0.2(sys)]×107h_{\pi}^{1} = [2.6 \pm 1.2(stat) \pm 0.2(sys)] \times 10^{-7} and a pionless EFT constant of C3S13P1/C0=[7.4±3.5(stat)±0.5(sys)]×1011C^{^{3}S_{1}\rightarrow ^{3}P_{1}}/C_{0}=[-7.4 \pm 3.5 (stat) \pm 0.5 (sys)] \times 10^{-11} MeV1^{-1}. We describe the experiment, data analysis, systematic uncertainties, and the implications of the result.Comment: 6 pages, 5 figure

    Quantifying atmospheric nitrogen deposition through a nationwide monitoring network across China

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    A Nationwide Nitrogen Deposition Monitoring Network (NNDMN) containing 43 monitoring sites was established in China to measure gaseous NH3, NO2, and HNO3 and particulate NH4+ and NO3− in air and/or precipitation from 2010 to 2014. Wet/bulk deposition fluxes of Nr species were collected by precipitation gauge method and measured by continuous-flow analyzer; dry deposition fluxes were estimated using airborne concentration measurements and inferential models. Our observations reveal large spatial variations of atmospheric Nr concentrations and dry and wet/bulk Nr deposition. On a national basis, the annual average concentrations (1.3–47.0 μg N m−3) and dry plus wet/bulk deposition fluxes (2.9–83.3 kg N ha−1 yr−1) of inorganic Nr species are ranked by land use as urban > rural > background sites and by regions as north China > southeast China > southwest China > northeast China > northwest China > Tibetan Plateau, reflecting the impact of anthropogenic Nr emission. Average dry and wet/bulk N deposition fluxes were 20.6 ± 11.2 (mean ± standard deviation) and 19.3 ± 9.2 kg N ha−1 yr−1 across China, with reduced N deposition dominating both dry and wet/bulk deposition. Our results suggest atmospheric dry N deposition is equally important to wet/bulk N deposition at the national scale. Therefore, both deposition forms should be included when considering the impacts of N deposition on environment and ecosystem health

    Study of the P-wave charmonium state \chi_{cJ} in \psi(2S) decays

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    The processes ψ(2S)γπ+π\psi(2S)\to \gamma \pi^+ \pi^-, γK+K\gamma K^+ K^- and γppˉ\gamma p \bar{p} have been studied using a sample of 3.7×1063.7 \times 10^6 produced ψ(2S)\psi(2S) decays. We determine the total width of the χc0\chi_{c0} to be Γχc0tot=14.3±2.0±3.0\Gamma^{tot}_{\chi_{c0}} = 14.3\pm 2.0\pm 3.0 MeV. We present the first measurement of the branching fraction B(χc0ppˉ)=(16.3±4.4±5.4)×105B(\chi_{c0} \to p \bar{p}) = (16.3 \pm 4.4 \pm 5.4)\times 10^{-5}, where the first error is statistical and the second one systematic. Branching fractions of χc0,2π+π\chi_{c0,2} \to \pi^+ \pi^- and K+KK^+ K^- are also reported.Comment: 10 pages, revtex, 3 figures, 2 table

    Measurement of the Total Cross Section for Hadronic Production by e+e- Annihilation at Energies between 2.6-5 Gev

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    Using the upgraded Beijing Spectrometer (BESII), we have measured the total cross section for e+ee^+e^- annihilation into hadronic final states at center-of-mass energies of 2.6, 3.2, 3.4, 3.55, 4.6 and 5.0 GeV. Values of RR, σ(e+ehadrons)/σ(e+eμ+μ)\sigma(e^+e^-\to {hadrons})/\sigma(e^+e^-\to\mu^+\mu^-), are determined.Comment: Submitted to Phys. Rev. Let

    Measurement of ψ(2S)\psi(2S) decays to baryon pairs

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    A sample of 3.95M ψ(2S)\psi(2S) decays registered in the BES detector are used to study final states containing pairs of octet and decuplet baryons. We report branching fractions for ψ(2S)ppˉ\psi(2S)\to p\bar{p}, ΛΛˉ\Lambda\bar{\Lambda}, Σ0Σˉ0\Sigma^0\bar{\Sigma}{}^0, ΞΞˉ+\Xi^-\bar{\Xi}{}^+, Δ++Δˉ\Delta^{++}\bar{\Delta}{}^{--}, Σ+(1385)Σˉ(1385)\Sigma^+(1385)\bar{\Sigma}{}^-(1385), Ξ0(1530)Ξˉ0(1530)\Xi^0(1530)\bar{\Xi}{}^0(1530), and ΩΩˉ+\Omega^-\bar{\Omega}{}^+. These results are compared to expectations based on the SU(3)-flavor symmetry, factorization, and perturbative QCD.Comment: 22 pages, 21 figures, 4 table
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