1,567 research outputs found
Ultralong Copper Phthalocyanine Nanowires with New Crystal Structure and Broad Optical Absorption
The development of molecular nanostructures plays a major role in emerging
organic electronic applications, as it leads to improved performance and is
compatible with our increasing need for miniaturisation. In particular,
nanowires have been obtained from solution or vapour phase and have displayed
high conductivity, or large interfacial areas in solar cells. In all cases
however, the crystal structure remains as in films or bulk, and the
exploitation of wires requires extensive post-growth manipulation as their
orientations are random. Here we report copper phthalocyanine (CuPc) nanowires
with diameters of 10-100 nm, high directionality and unprecedented aspect
ratios. We demonstrate that they adopt a new crystal phase, designated
eta-CuPc, where the molecules stack along the long axis. The resulting high
electronic overlap along the centimetre length stacks achieved in our wires
mediates antiferromagnetic couplings and broadens the optical absorption
spectrum. The ability to fabricate ultralong, flexible metal phthalocyanine
nanowires opens new possibilities for applications of these simple molecules
Associations of apolipoprotein E exon 4 and lipoprotein lipase S447X polymorphisms with acute ischemic stroke and myocardial infarction
Background: Because apolipoprotein E (apoE) and lipopoprotein lipase (LPL) polymorphisms interact with each other and with other factors to affect lipid metabolism, we sought to determine their separate and combined effects in association with ischemic vascular disease. Methods: We performed a case-control study of 816 subjects: 246 acute ischemic stroke patients, 234 acute myocardial infarction patients, and 336 controls. APOE exon 4 and LPL S447X genotypes were determined. Results: APOE ε2 and ε4 homozygotes were increased in stroke (4.5% vs. 1.0%, p = 0.008), while in myocardial infarction the ε4 allele was increased (12.6% vs. 9.5%, p = 0.006) but ε2 was decreased (3.7% vs. 12.1%, p = 0.000006). For subjects with either APOE ε2 or ε4 alleles, LPL X alleles were increased in vascular disease (OR = 2.2, p = 0.01). LPL X alleles displayed opposite tendencies toward association with disease when subjects were divided by sex, smoking, or APOE genotype. Meta-analysis and regression analysis of previous studies supported the sex and smoking dichotomies. Conclusion: This is the first report of an association of vascular disease with an interaction of APOE exon 4 and LPL S447X genotypes. Therefore, APOE genotypes and LPL S447X interactions with apoE, sex, and smoking may affect the risk of myocardial infarction and ischemic stroke. © 2006 by Walter de Gruyter.published_or_final_versio
First Observation of -odd Asymmetry in Polarized Neutron Capture on Hydrogen
We report the first observation of the parity-violating 2.2 MeV gamma-ray
asymmetry in neutron-proton capture using polarized cold
neutrons incident on a liquid parahydrogen target at the Spallation Neutron
Source at Oak Ridge National Laboratory. isolates the , \mbox{} component of the weak
nucleon-nucleon interaction, which is dominated by pion exchange and can be
directly related to a single coupling constant in either the DDH meson exchange
model or pionless EFT. We measured , which implies a DDH weak coupling of
and a pionless
EFT constant of MeV. We describe the experiment, data
analysis, systematic uncertainties, and the implications of the result.Comment: 6 pages, 5 figure
726.7-Gb/s 1.5-µm single-mode VCSEL discrete multi-tone transmission over 2.5-km multicore fiber
Experimental demonstration of 503.61-Gbit/s DMT over 10-km 7-Core fiber with 1.5-µm SM-VCSEL for optical interconnects
Quantifying atmospheric nitrogen deposition through a nationwide monitoring network across China
A Nationwide Nitrogen Deposition Monitoring Network (NNDMN) containing 43 monitoring sites was established in China to measure gaseous NH3, NO2, and HNO3 and particulate NH4+ and NO3− in air and/or precipitation from 2010 to 2014. Wet/bulk deposition fluxes of Nr species were collected by precipitation gauge method and measured by continuous-flow analyzer; dry deposition fluxes were estimated using airborne concentration measurements and inferential models. Our observations reveal large spatial variations of atmospheric Nr concentrations and dry and wet/bulk Nr deposition. On a national basis, the annual average concentrations (1.3–47.0 μg N m−3) and dry plus wet/bulk deposition fluxes (2.9–83.3 kg N ha−1 yr−1) of inorganic Nr species are ranked by land use as urban > rural > background sites and by regions as north China > southeast China > southwest China > northeast China > northwest China > Tibetan Plateau, reflecting the impact of anthropogenic Nr emission. Average dry and wet/bulk N deposition fluxes were 20.6 ± 11.2 (mean ± standard deviation) and 19.3 ± 9.2 kg N ha−1 yr−1 across China, with reduced N deposition dominating both dry and wet/bulk deposition. Our results suggest atmospheric dry N deposition is equally important to wet/bulk N deposition at the national scale. Therefore, both deposition forms should be included when considering the impacts of N deposition on environment and ecosystem health
Study of the P-wave charmonium state \chi_{cJ} in \psi(2S) decays
The processes , and have been studied using a sample of produced
decays. We determine the total width of the to be
MeV. We present the first
measurement of the branching fraction , where the first error is statistical and the
second one systematic. Branching fractions of and
are also reported.Comment: 10 pages, revtex, 3 figures, 2 table
Measurement of the Total Cross Section for Hadronic Production by e+e- Annihilation at Energies between 2.6-5 Gev
Using the upgraded Beijing Spectrometer (BESII), we have measured the total
cross section for annihilation into hadronic final states at
center-of-mass energies of 2.6, 3.2, 3.4, 3.55, 4.6 and 5.0 GeV. Values of ,
, are determined.Comment: Submitted to Phys. Rev. Let
Measurement of decays to baryon pairs
A sample of 3.95M decays registered in the BES detector are used
to study final states containing pairs of octet and decuplet baryons. We report
branching fractions for , ,
, ,
, ,
, and . These results
are compared to expectations based on the SU(3)-flavor symmetry, factorization,
and perturbative QCD.Comment: 22 pages, 21 figures, 4 table
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