Evaluation Of Carbonation Resistance Of Paint Coated Concrete For Buildings

When evaluating the carbonation resistance of paint coated concrete, the effects of both the strength grade and the curing conditions (standard curing and accelerated curing) of concrete substrate on carbonation resistance of paint coated concrete were investigated. The concept of the carbonation suppression ratio of paint was presented for evaluation of the anti-carbonation performance of the two types of paints (exterior and interior paints) when applied to a reference concrete substrate. The test results showed a good linear relationship between the carbonation depths of the paint coated concrete and the square root of exposure times. Concrete with higher strength grade exhibited greater carbonation resistance. The carbonation depth of the C35 standard cured concrete was reduced by 56% in comparison with that of the C25 standard cured concrete. It was found that concrete substrate prepared by accelerated curing method displayed lower carbonation resistance than standard cured concrete. Compared with the standard cured specimen, the carbonation depth of the accelerated cured specimen increased by 61% for the control C25 concrete and by 56% for the control C35 concrete. This phenomenon was attributed to the formation of a higher volume of capillary pores in concrete prepared by accelerated curing. Additionally, the exterior paint had a higher carbonation suppression ratio than the interior paint. The suppression ratios of the exterior and interior paint coatings applied on C25 standard cured concrete were 71% and 56%, respectively. The exterior paint coated concrete had a better carbonation resistance with longer effective blockage time and smaller carbonation rate

Crystal Structure Manipulation of the Exchange Bias in an Antiferromagnetic Film

Exchange bias is one of the most extensively studied phenomena in magnetism, since it exerts a unidirectional anisotropy to a ferromagnet (FM) when coupled to an antiferromagnet (AFM) and the control of the exchange bias is therefore very important for technological applications, such as magnetic random access memory and giant magnetoresistance sensors. In this letter, we report the crystal structure manipulation of the exchange bias in epitaxial hcp Cr2O3 films. By epitaxially growing twined (10-10) oriented Cr2O3 thin films, of which the c axis and spins of the Cr atoms lie in the film plane, we demonstrate that the exchange bias between Cr2O3 and an adjacent permalloy layer is tuned to in-plane from out-of-plane that has been observed in (0001) oriented Cr2O3 films. This is owing to the collinear exchange coupling between the spins of the Cr atoms and the adjacent FM layer. Such a highly anisotropic exchange bias phenomenon is not possible in polycrystalline films.Comment: To be published in Scientific Reports, 12 pages, 6 figure