84 research outputs found
Indoor particulate matter (PM) from cooking in UK students' studio flats and associated intervention strategies: evaluation of cooking methods, PM concentrations and personal exposures using low-cost sensors
Study on factors influencing social network service addiction among junior college students based on problem behavior theory
Objective·To construct a structural equation model based on problem behavior theory to conduct a study on social network addiction among junior college students.Methods·A cross-sectional questionnaire survey was conducted in a college in Shanghai. Logistic regression analysis was used to analyze the effects of gender, grade, study pressure, self-esteem, loneliness, depression, entrapment, defeat, interpersonal needs, perceived social support, smoking, alcohol, exercise, and academic achievement on social network service addiction. Based on the problem behavior theory, the structural equation model was used to construct a theoretical framework model of social network service addiction of junior college students.Results·60.31% of the total 980 participants had social network service addiction. The univariate Logistic regression results showed that depression, self-esteem, loneliness, frustration, drowsiness, social support, interpersonal needs, exercise, and academic performance had a significant impact on social network addiction. The structural equation model fitted well [S-Bχ2/df=8.03, goodness-of-fit index (GFI)=0.924, comparative fit index (CFI)=0.909, Tucker-Lewis index (TLI)=0.872, root mean square error of approximation (RMSEA)=0.096, standardized root mean square residual (SRMR)=0.070], suggesting the mutual influence between the personality system and the perceived environment system, between the personality system and the behavioral system, and between the perceived environment system and the behavior system interact (β=1.018, P=0.000; β=0.218, P=0.003; β=0.268, P=0.000). The influence of personality system and behavior system on social network service addiction was not statistically significant, while the perceived environment system had a significant positive impact on social network service addiction (β=0.481, P=0.001).Conclusion·Personality system and behavior system indirectly affect social network service addiction by influencing perceived environment system, and perceived environment system directly affects social network service addiction. For the problem of social network addiction among lower grade college students, it is necessary to fully respect the characteristics of college students, and work together from three levels of the system to reduce the risk of social network addiction among college students
Antibiotics in the offshore waters of the Bohai Sea and the Yellow Sea in China: Occurrence, distribution and ecological risks
The ocean is an important sink of land-based pollutants. Previous studies showed that serious antibiotic pollution occurred in the coastal waters, but limited studies focused on their presence in offshore waters. In this study, eleven antibiotics in three different categories were investigated in offshore waters of the Bohai Sea and the Yellow Sea in China. The results indicated that three antibiotics dehydration erythromycin, sulfamethoxazole and trimethoprim occurred throughout the offshore waters at concentrations of 0.10-16.6 ng L-1 and they decreased exponentially from the rivers to the coastal and offshore waters. The other antibiotics all presented very low detection rates (<10%) and concentrations (<0.51 ng L-1). Although the concentrations were very low, risk assessment based on the calculated risk quotients (RQs) showed that sulfamethoxazole, dehydration erythromycin and clarithromycin at most of sampling sites posed medium or low ecological risks (0.01 < RQ < 1) to some sensitive aquatic organisms, including Synechococcus leopoliensis and Pseudokirchneriella subcapitata. (C) 2012 Elsevier Ltd. All rights reserved.The ocean is an important sink of land-based pollutants. Previous studies showed that serious antibiotic pollution occurred in the coastal waters, but limited studies focused on their presence in offshore waters. In this study, eleven antibiotics in three different categories were investigated in offshore waters of the Bohai Sea and the Yellow Sea in China. The results indicated that three antibiotics dehydration erythromycin, sulfamethoxazole and trimethoprim occurred throughout the offshore waters at concentrations of 0.10-16.6 ng L-1 and they decreased exponentially from the rivers to the coastal and offshore waters. The other antibiotics all presented very low detection rates (<10%) and concentrations (<0.51 ng L-1). Although the concentrations were very low, risk assessment based on the calculated risk quotients (RQs) showed that sulfamethoxazole, dehydration erythromycin and clarithromycin at most of sampling sites posed medium or low ecological risks (0.01 < RQ < 1) to some sensitive aquatic organisms, including Synechococcus leopoliensis and Pseudokirchneriella subcapitata. (C) 2012 Elsevier Ltd. All rights reserved
15.34% efficiency all-small-molecule organic solar cells with an improved fill factor enabled by a fullerene additive
Solution processed organic solar cells (OSCs) composed of all small molecules (ASM) are promising for production on an industrial scale owing to the properties of small molecules, such as well-defined chemical structures, high purity of materials, and outstanding repeatability from batch to batch synthesis. Remarkably, ASM OSCs with power conversion efficiency (PCE) beyond 13% were achieved by structure improvement of the electron donor and choosingY6as the electron acceptor. However, the fill factor (FF) is an obstacle that limits the further improvement of the PCE for these ASM OSCs. Herein, we focus on the FF improvement of recently reported ASM OSCs withBTR-Cl:Y6as the active layer by miscibility-induced active layer morphology optimization. The incorporation of fullerene derivatives, which have good miscibility with bothBTR-ClandY6, results in reduced bimolecular recombination and thus improved FF. In particular, whenca.5 wt% ofPC(71)BMwas added in the active layer, a FF of 77.11% was achieved without sacrificing the open circuit voltage (V-OC) and the short circuit current density (J(SC)), leading to a record PCE of 15.34% (certified at 14.7%) for ASM OSCs. We found that the optimized device showed comparable charge extraction, longer charge carrier lifetime, and slower bimolecular recombination rate compared with those of the control devices (w/o fullerene). Our results demonstrate that the miscibility driven regulation of active layer morphology by incorporation of a fullerene derivative delicately optimizes the active layer microstructures and improves the device performance, which brings vibrancy to OSC research
Real-time monitoring of airborne molecular contamination on antireflection silica coatings using surface acoustic wave technology
Real time monitoring of contamination on antireflection (AR) silica coatings in high peak power laser systems (HPLs) is critically needed in order to avoid reductions of transmission and laser damage to optical surfaces. Herein we proposed to apply a surface acoustic wave (SAW) sensor to real-time monitor trace amounts of airborne molecular contaminants (AMCs) adsorbed on the AR silica coatings. The silica coating is found to be susceptible to AMCs because of its mesoporous structure, huge surface area and polar nature. The adsorbed AMCs caused the increased mass on the silica coating of the SAW sensor, which resulted in a significant increase of its frequency shift. The fabricated sensor showed a high sensitivity of ∼-490 mm2 ng−1Hz and an excellent linearity vs. the areal density of adsorbed AMCs since the frequency shift of the sensor is linearly related to the change of mass of the silica coating
Elastic loading enhanced NH3 sensing for surface acoustic wave sensor with highly porous nitrogen doped diamond like carbon film
We proposed a surface acoustic wave (SAW) NH3 gas sensor based on nitrogen doped diamond like carbon (N-DLC) film. The N-DLC film, prepared using a microwave electron cyclotron resonance plasma chemical vapor deposition (ECR-PECVD) method, is highly porous and physically and chemically stable, and have active polar groups on its surface, which can selectively absorb polar NH3 gas molecules. These features of the film lead to the high sensitivity, low noise and excellent stability of the sensor. The sensor can achieve capabilities of in-situ monitoring NH3 in a concentration range from 100 ppb to 100 ppm with fast response (∼5 s) and recovery (∼29 s) at room temperature. The NH3 sensing mechanism is attributed to the decreased porosity of the N-DLC film caused by adsorbed NH3 molecules on its polar groups, which leads an increase of the elastic modulus of the film
H2S gas sensing performance and mechanisms using CuO-Al2O3 composite films based on both surface acoustic wave and chemiresistor techniques
Surface acoustic wave and chemiresistor based gas sensors integrated with a sensing layer of sol-gel CuO-Al2O3 composite film were fabricated and their performance and mechanisms for H2S sensing were characterized and compared. In the composite film, CuO nanoparticles provide active sites for adsorption and reaction of H2S molecules while Al2O3 nanoparticles help to form a uniform and mesoporous film structure, both of which enhance the sensitivity of the sensors by providing numerous active CuO surfaces. Through the comparative studies, the SAW based H2S sensor operated at room temperature showed a lower detection limit, higher sensitivity, better linearity and good selectivity to H2S gas with its concentration ranging from 5 ppb to 100 ppm, compared with those of the chemiresistor sensor, which are mainly attributed to the effective mass sensing properties of the SAW sensor, because a minor change in the mass of the film caused by adsorbed H2S molecules would lead to a significant and monotonous change of the resonant frequency of the SAW devices
Characteristics and generation mechanisms of anticyclonic eddies, cyclonic eddies and dipole eddies in the Mozambique Channel
The discovery of cyclonic and dipole eddies in the Mozambique Channel (MC) indicates that the understanding of the mesoscale eddy characteristics in the MC is incomplete. The distributions of anticyclonic, cyclonic, and dipole eddies along the MC were elucidated in this study using satellite observations. It was observed that these eddies exhibit a preference for emergence and movement in the western MC. The occurrence frequencies of anticyclonic and cyclonic eddies are four and three times per year, respectively, in the narrowest section of the MC. In contrast, the frequency of mesoscale eddies reaches its peak at nine times per year in the central region of the MC. The occurrence of dipole eddies also reaches its peak twice per year in the middle MC. Dipole eddies are more prevalent in the MC and exhibit larger dimensions and shorter lifespans compared to anticyclonic and cyclonic eddies. Mesoscale eddies, which traverse the narrowest section of the MC and propagate southward, are predominantly generated within the western Comoros Basin due to barotropic instability. The southward branch of the Northeast Madagascar Current (NEMC) plays a crucial role in transporting these eddies to the middle MC. The eastern middle MC is also a generation site for mesoscale eddies in addition to the Comoros Basin, where cyclonic eddies are generated twice per year. These cyclonic eddies are also generated due to barotropic instability
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