8 research outputs found
High Proton Conductivity of Zinc Oxalate Coordination Polymers Mediated by a Hydrogen Bond with Pyridinium
No full textA novel metal–organic framework,
(Hpy)<sub>2</sub>[Zn<sub>2</sub>(ox)<sub>3</sub>]·<i>n</i>H<sub>2</sub>O (<i>n</i> = 0, 1), having a pyridinium cation,
was newly synthesized, and the crystal structures were determined.
The hydrated compound shows a high proton conductivity of 2.2 ×
10<sup>–3</sup> S cm<sup>–1</sup> at 298 K and 98% relative
humidity. Single crystal XRD analysis revealed a rotational displacement
factor for the hydrated pyridinium ring and elongated water site that
is thought to cause the high proton conductivity
High Proton Conductivity of Zinc Oxalate Coordination Polymers Mediated by a Hydrogen Bond with Pyridinium
No full textA novel metal–organic framework,
(Hpy)<sub>2</sub>[Zn<sub>2</sub>(ox)<sub>3</sub>]·<i>n</i>H<sub>2</sub>O (<i>n</i> = 0, 1), having a pyridinium cation,
was newly synthesized, and the crystal structures were determined.
The hydrated compound shows a high proton conductivity of 2.2 ×
10<sup>–3</sup> S cm<sup>–1</sup> at 298 K and 98% relative
humidity. Single crystal XRD analysis revealed a rotational displacement
factor for the hydrated pyridinium ring and elongated water site that
is thought to cause the high proton conductivity
High Proton Conductivity of Zinc Oxalate Coordination Polymers Mediated by a Hydrogen Bond with Pyridinium
No full textA novel metal–organic framework,
(Hpy)<sub>2</sub>[Zn<sub>2</sub>(ox)<sub>3</sub>]·<i>n</i>H<sub>2</sub>O (<i>n</i> = 0, 1), having a pyridinium cation,
was newly synthesized, and the crystal structures were determined.
The hydrated compound shows a high proton conductivity of 2.2 ×
10<sup>–3</sup> S cm<sup>–1</sup> at 298 K and 98% relative
humidity. Single crystal XRD analysis revealed a rotational displacement
factor for the hydrated pyridinium ring and elongated water site that
is thought to cause the high proton conductivity
Synthesis of Azo-Bridged Ferrocene Oligomers and a Polymer and Electrochemical and Optical Analysis of Internuclear Electronic Interactions in Their Mixed-Valence States
No full text
