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Gallium-Catalyzed Reductive Chlorination of Carboxylic Acids with Copper(II) Chloride
Described herein is the direct chlorination
of carboxylic acids
using copper(II) chloride via a gallium(III)-catalyzed reduction in
the presence of a hydrosiloxane. During this reductive chlorination,
the counteranions of CuCl<sub>2</sub> functioned as a chloride source