240 research outputs found
Study of improved resins for advanced supersonic technology composites. Part 1: Heteroaromatic polymers containing ether groups. Part 2: Curing chemistry of aromatic polymers and composite studies
Fourteen ether-containing, aromatic dianhydrides have been synthesized from N-phenyl-3 or 4-nitrophthalimide and various bisphenols. The process involves nucleophilic displacement of activated nitro groups with bisphenolate ions. Ether-containing dianhydrides were indefinitely stable in the presence of atmospheric moisture. One-step, high temperature solution polymerization of the ether-containing dianhydrides with m-phenylene diamine, 4,4'-oxydianiline and 1, 3-bis(4-aminophenoxy)benzene afforded 42 polyetherimides. The polyetherimides were all soluble in m-cresol except two which were found to be crystalline. The glass transition temperatures of the polyetherimides ranged from 178 to 277 C. Soluble polybenzimidazopyrrolones containing ether groups were also prepared from the same ether-containing dianhydrides and aromatic tetraamines by one-step solution polymerization. Using low molecular weight polyetherimides, various thermoset resin systems were developed and tested as matrices for fiber-reinforced composites. The curing chemistry involving reaction of the phthalonitrile group and the o-diaminophenyl group was found to be generally applicable to crosslinking various aromatic polymers other than polyimides
Fictitious Magnetic Resonance by Quasi-Electrostatic Field
We propose a new kind of spin manipulation method using a {\it fictitious}
magnetic field generated by a quasi-electrostatic field. The method can be
applicable to every atom with electron spins and has distinct advantages of
small photon scattering rate and local addressability. By using a
laser as a quasi-electrostatic field, we have experimentally demonstrated the
proposed method by observing the Rabi-oscillation of the ground state hyperfine
spin F=1 of the cold atoms and the Bose-Einstein condensate.Comment: 5 pages, 5 figure
Molecular vibration in cold collision theory
Cold collisions of ground state oxygen molecules with Helium have been
investigated in a wide range of cold collision energies (from 1 K up to 10
K) treating the oxygen molecule first as a rigid rotor and then introducing the
vibrational degree of freedom. The comparison between the two models shows that
at low energies the rigid rotor approximation is very accurate and able to
describe all the dynamical features of the system. The comparison between the
two models has also been extended to cases where the interaction potential He -
O is made artificially stronger. In this case vibration can perturb rate
constants, but fine-tuning the rigid rotor potential can alleviate the
discrepancies between the two models.Comment: 11 pages, 3 figure
Quantum entanglement using trapped atomic spins
We propose an implementation for quantum logic and computing using trapped
atomic spins of two different species, interacting via direct magnetic
spin-spin interaction. In this scheme, the spins (electronic or nuclear) of
distantly spaced trapped neutral atoms serve as the qubit arrays for quantum
information processing and storage, and the controlled interaction between two
spins, as required for universal quantum computing, is implemented in a three
step process that involves state swapping with a movable auxiliary spin.Comment: minor revisions with an updated discussion on adibatic tranportation
of trapped qubit, 5 pages, 3 figs, resubmitted to PR
Photoassociation of cold atoms with chirped laser pulses: time-dependent calculations and analysis of the adiabatic transfer within a two-state model
This theoretical paper presents numerical calculations for photoassociation
of ultracold cesium atoms with a chirped laser pulse and detailed analysis of
the results. In contrast with earlier work, the initial state is represented by
a stationary continuum wavefunction. In the chosen example, it is shown that an
important population transfer is achieved to vibrational levels in
the vicinity of the v=98 bound level in the external well of the
potential. Such levels lie in the energy range swept by
the instantaneous frequency of the pulse, thus defining a ``photoassociation
window''. Levels outside this window may be significantly excited during the
pulse, but no population remains there after the pulse. Finally, the population
transfer to the last vibrational levels of the ground (6s + 6s)
is significant, making stable molecules. The results are interpreted in the
framework of a two state model as an adiabatic inversion mechanism, efficient
only within the photoassociation window. The large value found for the
photoassociation rate suggests promising applications. The present chirp has
been designed in view of creating a vibrational wavepacket in the excited state
which is focussing at the barrier of the double well potential.Comment: 49 pages, 9 figures, submitted to Phys. Rev.
Molecular Dynamics Simulation of Sympathetic Crystallization of Molecular Ions
It is shown that the translational degrees of freedom of a large variety of
molecules, from light diatomic to heavy organic ones, can be cooled
sympathetically and brought to rest (crystallized) in a linear Paul trap. The
method relies on endowing the molecules with an appropriate positive charge,
storage in a linear radiofrequency trap, and sympathetic cooling. Two
well--known atomic coolant species, and
, are sufficient for cooling the molecular mass range
from 2 to 20,000 amu. The large molecular charge required for simultaneous
trapping of heavy molecules and of the coolant ions can easily be produced
using electrospray ionization. Crystallized molecular ions offer vast
opportunities for novel studies.Comment: Accepted for publication in Phys. Rev.
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