73 research outputs found
Ultrastructural alteration of the cell surface of Staphylococcus aureus cultured in a different salt condition
Staphylococcus aureus growing in a normal NaGI medium
has a specific NaGI tolerance property to grow in the medium contain. ing NaGl in as high a concentration as over 10%. In our comparative study of the cells proliferating in the normal NaGI medium and 10% NaGl medium, we have observed the following differences aside from the changes of lipid composition in the cytoplasmic membrane previously reported. 1. S. aureus grown in high NaGl medium undergoes changes as to increase its size and reduce its surface area. 2. The thickness and weight of cell wall are increased to about 1. 7 times and 1. 32 times, respectively. 3. The protoplast prepared from S. aureus growing in the high NaGI medium shows a weaker resistance to hypotonic condition than that from normal cell.</p
STM observation of the quantum interference effect in finite-sized graphite
Superperiodic patterns were observed by STM on two kinds of finite-sized
graphene sheets. One is nanographene sheets inclined from a highly oriented
pyrolitic graphite (HOPG) substrate and the other is several-layer-thick
graphene sheets with dislocation-network structures against a HOPG substrate.
As for the former, the in-plane periodicity increased gradually in the
direction of inclination, and it is easily changed by attachment of a
nanographite flake on the nanographene sheets. The oscillation pattern can be
explained by the interference of electron waves confined in the inclined
nanographene sheets. As for the latter, patterns and their corrugation
amplitudes depended on the bias voltage and on the terrace height from the HOPG
substrate. The interference effect by the perturbed and unperturbed waves in
the overlayer is responsible for the patterns whose local density of states
varies in space.Comment: 11 pages; 2 figures; accepted for publication in J. Phys. Chem.
Solids; ISIC1
A Novel Method for Constructing β-D-Mannosidic, 2-Acetamido-2-deoxy-β-D-mannosidic, and 2-Deoxy-D-arabino-hexopyranosidic Units from the Bis(triflate) Derivative of β-D-Galactoside
An efficient construction of the β-D-mannosidic, 2-Acetamido-2-deoxy-β-D-mannosidic, 2-deoxy-2-fluoro-β-D-mannosidic, and 2-deoxy-β-D-arabino-hexopyranosidic units from the same intermediate, 2-4-bis(O-trifluoromethylsulfonyl) derivative of β-D-galactoside, was achieved in good yields in a stepwise inversion at C-4 and C-2 by using cesium acetate, n-Bu4NN3, n-Bu4NF, and n-Bu4NBH4. A convenient and practical protection of β-D-mannoside to the straightforward synthesis of antennary oligosaccharides was also achieved by using cesium trifluoroacetate
Kohn anomalies in graphene nanoribbons
The quantum corrections to the energies of the point optical phonon
modes (Kohn anomalies) in graphene nanoribbons are investigated. We show
theoretically that the longitudinal optical modes undergo a Kohn anomaly
effect, while the transverse optical modes do not. In relation to Raman
spectroscopy, we show that the longitudinal modes are not Raman active near the
zigzag edge, while the transverse optical modes are not Raman active near the
armchair edge. These results are useful for identifying the orientation of the
edge of graphene nanoribbons by G band Raman spectroscopy, as is demonstrated
experimentally. The differences in the Kohn anomalies for nanoribbons and for
metallic single wall nanotubes are pointed out, and our results are explained
in terms of pseudospin effects.Comment: 11 pages, 6 figure
マリアナ弧北端部の熱水活動域(日光海山)より単離した新規Epsilon-Proteobacteriaの諸性質
BE09-P99ポスター要旨 / ブルーアース2009(2009年3月12日~13日, 立教大学池袋キャンパス)http://www.godac.jamstec.go.jp/darwin/cruise/natsushima/nt05-18/
MOLECULAR DYNAMICS SIMULATION OF LI-ION COORDINATION STRUCTURE AND TRANSPORT PROPERTIES IN LIB ELECTROLYTES: INFLUENCE OF MOLECULAR SIZE
Lithium-ion batteries (LIBs) are currently attracting much attention because electric vehicles and large storage batteries are becoming widespread. For lightweight and efficient usability, LIB performance for safety, capacity, charge/discharge cycle characteristics, and electric current must be improved. Development of high performance LIB relies mostly on progress of materials used for electrolytes and electrodes. In particular, electrolytes are an important factor because they play a role in carrying charged substances, i.e. ions, between separated electrodes. The ion-carrying performance depends on the choice of electrolyte, and thus, in this study, we discuss the relationship between the geometric shape of molecules used as electrolytes and their physical properties, using molecular dynamics (MD) simulations. We showed that, as the smaller solvent is used, ionic conductivity of the system is further enhanced. MD simulations showed that there are two main reasons for this behavior. First, a smaller radius allows the solvent molecule to diffuse easily. Consequently, when solvent molecules frequently surround a lithium ion, and the diffusion coefficient of the lithium ion becomes larger. Second, because small solvent molecules naturally come close to ions, salt (composed of cations and anions) is forced to be dissociated because of the solvent molecules, and the degree of salt dissociation increases
Three Severe Cases of Viral Infections with Post-Kidney Transplantation Successfully Confirmed by Polymerase Chain Reaction and Flow Cytometry
Viral infections in patients with post-kidney transplantation are often difficult to diagnose as well as treat. We herein report three cases with severe viral infections after kidney transplantation. All their causative pathogens could be detected promptly by polymerase chain reaction and flow cytometry during the early stages of infection. These examinations would also be of great use to monitor therapeutic responses and disease activity. It is indeed true that no specific treatment is available for most of the viral infections, but we should be aware that some infections, such as Epstein-Barr virus infection, can be treatable with prompt and specific treatment, such as rituximab
N-アセチルラクトサミン・キトビオースのアノマー位活性化および部分保護
糖鎖合成における従来法より効果的な新規ブロック合成法の確立のため、近年酵素合成可能となった二糖(N-アセチルラクトサミン、キトビオース)を用いて、アノマー位の活性化および部分保護について検討を行った結果、グリコシド化反応においてビリジニウム-p-トルエンスルホナート(PPTS)が2-アミノ糖で一般に用いられる酸触媒よりも効果的であることが判明した。講演番号:3 A1 1
STM observation of electronic wave interference effect in finite-sized graphite with dislocation-network structures
Superperiodic patterns near a step edge were observed by STM on
several-layer-thick graphite sheets on a highly oriented pyrolitic graphite
substrate, where a dislocation network is generated at the interface between
the graphite overlayer and the substrate. Triangular- and rhombic-shaped
periodic patterns whose periodicities are around 100 nm were observed on the
upper terrace near the step edge. In contrast, only outlines of the patterns
similar to those on the upper terrace were observed on the lower terrace. On
the upper terrace, their geometrical patterns gradually disappeared and became
similar to those on the lower terrace without any changes of their periodicity
in increasing a bias voltage. By assuming a periodic scattering potential at
the interface due to dislocations, the varying corrugation amplitudes of the
patterns can be understood as changes in LDOS as a result of the beat of
perturbed and unperturbed waves, i.e. the interference in an overlayer. The
observed changes in the image depending on an overlayer height and a bias
voltage can be explained by the electronic wave interference in the ultra-thin
overlayer distorted under the influence of dislocation-network structures.Comment: 8 pages; 6 figures; Paper which a part of cond-mat/0311068 is
disscussed in detai
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