1,025 research outputs found
Synthesis and Properties of Polysilsesquioxanes Having Ethoxysulfonyl Group as a Side Chain
Polysilsesquioxane having an ethoxysulfonyl group as a side chain was synthesized to prepare a proton-conductive film composed of a main chain of siloxane. At first, sodium 4-(2-methylallyloxy)benzenesulfonate was chlorinated with thionyl chloride. Next, hydrosilylation with trichlorosilane was carried out in the presence of platinum catalyst followed by treatment with ethanol. Finally, the hydrolytic polycondensation was carried out to provide poly(3-(4-ethoxysulfonylphenoxy)-2-methylpropyl)silsesquioxane. This polysilsesquioxane was heated to form a free-standing film that was brittle and brown in color
Novel Extrapolation Method in the Monte Carlo Shell Model
We propose an extrapolation method utilizing energy variance in the Monte
Carlo shell model in order to estimate the energy eigenvalue and observables
accurately. We derive a formula for the energy variance with deformed Slater
determinants, which enables us to calculate the energy variance efficiently.
The feasibility of the method is demonstrated for the full -shell
calculation of Ni, and the applicability of the method to a system
beyond current limit of exact diagonalization is shown for the
+-shell calculation of Ge.Comment: 4 pages, 4figure
Void-induced cross slip of screw dislocations in fcc copper
Pinning interaction between a screw dislocation and a void in fcc copper is
investigated by means of molecular dynamics simulation. A screw dislocation
bows out to undergo depinning on the original glide plane at low temperatures,
where the behavior of the depinning stress is consistent with that obtained by
a continuum model. If the temperature is higher than 300 K, the motion of a
screw dislocation is no longer restricted to a single glide plane due to cross
slip on the void surface. Several depinning mechanisms that involve multiple
glide planes are found. In particular, a depinning mechanism that produces an
intrinsic prismatic loop is found. We show that these complex depinning
mechanisms significantly increase the depinning stress
エネルギ解放率破壊規準によるき裂干渉問題に関する研究
取得学位:博士(工学),学位授与番号:博甲第497号,学位授与年月日:平成14年3月22日,学位授与年:200
Development of the Japanese version of the health‐related quality of life questionnaire for bladder cancer patients using the Bladder Cancer Index: A pilot study
Peer Reviewedhttps://deepblue.lib.umich.edu/bitstream/2027.42/151958/1/iju14073.pdfhttps://deepblue.lib.umich.edu/bitstream/2027.42/151958/2/iju14073_am.pdfhttps://deepblue.lib.umich.edu/bitstream/2027.42/151958/3/iju14073-sup-0003-app2.pd
Immunohistochemical Analysis of Oral Dysplasia: Diagnostic Assessment by Fascin and Podoplanin Expression
The aim of this study was to investigate fascin and podoplanin expression in oral dysplasia and carcinoma in situ (CIS) immunohistochemically, and to evaluate their relationship to histopathological diagnosis based on architectural and cytological features. Fascin and podoplanin expression patterns were analyzed immunohistologically in 26 specimens of oral lesions, including benign disease (hyperplasia, papilloma, and others), intraepithelial neoplasia/borderline disease (dysplasia), and malignant disease (CIS, invasive squamous cell carcinoma). Fascin expression was scored into four original categories, and podoplanin expression was scored into five previously established categories. The relationship between the immunohistochemically determined scores of fascin and podoplanin expression and the architectural and cytological features in the hematoxylin-eosin-stained slides was analyzed statistically. The immunostaining scores for fascin and podoplanin were significantly higher in dysplasia and CIS than in benign disease (p=0.0011, p=0.00036), and they were significantly higher in dysplasia than in benign disease (p=0.0087, p=0.0032). In all cases of invasive SCC, fascin was expressed mainly in the cytoplasm of the tumor cells and fascin expression extended from the destruction of the basal layer of the epithelium to the upper layer of the epithelium and podoplanin was expressed in the cytoplasm and membrane of the tumor cells. This was the first report of up-regulation of fascin in oral dysplasia. Our results suggest that it would be helpful for improving the diagnostic accuracy of oral dysplasia and CIS to assess the expression of fascin and podoplanin immunohistochemically
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