327 research outputs found
Adiabatic limits, Theta functions, and geometric quantization
Let be a (non-singular) Lagrangian torus
fibration on a compact, complete base with prequantum line bundle
. For a positive integer and a compatible
almost complex structure on invariant along the fiber of
, let be the associated Spin Dirac operator with coefficients in
. Then, we give an orthogonal family of sections of indexed by the
Bohr-Sommerfeld points , and show that each
converges to a delta-function section supported on the corresponding
Bohr-Sommerfeld fiber and the -norm of converges to by the adiabatic(-type) limit. Moreover, if
is integrable, we also give an orthogonal basis of the space of holomorphic sections of indexed by
, and show that each converges to a delta-function
section supported on the corresponding Bohr-Sommerfeld fiber by
the adiabatic(-type) limit. We also explain the relation of with
Jacobi's theta functions when is .Comment: 41 page
JAPAN ALPS, its Physical Profiles and the Beginnings of People's Mountaineerings under the outward Looks of Worship
Article人文科学論集. 人間情報学科編 41: 171-183(2007)departmental bulletin pape
Land Use System Transformation with the Development of Tourism and some Environmental Problems in Shinshu District, an Inland Area of Central Japan
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Appearance of similar triangles by certain operations on triangles
In this paper, a theorem about similar triangles is proved. It shows that two
small and four large triangles similar to the original triangle can appear if
we choose well among several intersections of the perpendicular bisectors of
the sides with perpendicular lines of sides passing through the vertices of the
triangle
From photoelectron detachment spectra of BrHBr−, BrDBr− and IHI−, IDI− to vibrational bonding of BrMuBr and IMuI
Photoelectron detachment XLX−(0000) + hν → XLX(vib) + e − + KER (X = Br or I,
L = H or D) at sufficiently low temperatures photoionizes linear dihalogen
anions XLX− in the vibrational ground state (v 1 v 2 l v 3 = 0000) and
prepares the neutral radicals XLX(vib) in vibrational states (vib). At the
same time, part of the photon energy (hν) is converted into kinetic energy
release (KER) of the electron [R. B. Metz, S. E. Bradforth, and D. M. Neumark,
Adv. Chem. Phys. 81, 1 (1992)]. The process may be described approximately in
terms of a Franck-Condon type transfer of the vibrational wavefunction
representing XLX−(0000) from the domain close to the minimum of its potential
energy surface (PES) to the domain close to the linear transition state of the
PES of the neutral XLX. As a consequence, prominent peaks of the photoelectron
detachment spectra (pds) correlate with the vibrational energies E XLX,vib of
states XLX(vib) which are centered at linear transition state. The
corresponding vibrational quantum numbers may be labeled vib = (v 1 v 2 l v 3)
= (000 v 3). Accordingly, the related most prominent peaks in the pds are
labeled v 3. We construct a model PES which mimics the “true” PES in the
domain of transition state such that it supports vibrational states with
energies E XLX,pds,000v3 close to the peaks of the pds labeled v 3 = 0, 2, and
4. Subsequently, the same model PES is also used to calculate approximate
values of the energies E XMuX,0000 of the isotopomers XMuX(0000). For the
heavy isotopomers XHX and XDX, it turns out that all energies E XLX,000 v 3
are above the threshold for dissociation, which means that all heavy XLX(000 v
3) with wavefunctions centered at the transition state are unstable resonances
with finite lifetimes. Turning the table, bound states of the heavy XLX are
van der Waals (vdW) bonded. In contrast, the energies E XMuX,0000 of the light
isotopomers XMuX(0000) are below the threshold for dissociation, with
wavefunctions centered at the transition state. This means that XMuX(0000) are
vibrationally bonded. This implies a fundamental change of the nature of
chemical bonding, from vdW bonding of the heavy XHX, XDX to vibrational
bonding of XMuX. For BrMuBr, the present results derived from experimental pds
of BrHBr− and BrDBr− confirm the recent discovery of vibrational bonding based
on quantum chemical ab initio calculations [D. G. Fleming, J. Manz, K. Sato,
and T. Takayanagi, Angew. Chem., Int. Ed. 53, 13706 (2014)]. The extension
from BrLBr to ILI means the discovery of a new example of vibrational bonding.
These empirical results for the vibrational bonding of IMuI, derived from the
photoelectron spectra of IHI− and IDI−, are supported by ab initio simulations
of the spectra and of the wavefunction representing vibrational bonding of
IMuI
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