Time-resolved photoluminescence of the size-controlled ZnO nanorods

Size dependence of the time-resolved photoluminescence (TRPL) has been investigated for the ZnO nanorods fabricated by catalyst-free metalorganic chemical vapor deposition. The nanorods have a diameter of 35 nm and lengths in the range of 150 nm to 1.1 mum. The TRPL decay rate decreases monotonically as the length of the nanorods increases in the range of 150 to 600 nm. Decrease of the radiative decay rate of the exciton-polariton has been invoked to account for the results

Femtosecond-Resolved Excited State Relaxation Dynamics of Copper (II) Tetraphenylporphyrin (CuTPP) After Soret Band Excitation

Excited state relaxation dynamics of Copper (II) tetraphenylporphyrin (CuTPP) after Soret band excitation have been investigated in various solvents by femtosecond broadband transient absorption spectroscopy. Significant role of charge transfer state has been confirmed from fast relaxation of triplet CuTPP in pyridine, giving τ ~ 26.5 ps. In piperidine, the transient measured at 480 nm shows biexponential behavior with distinct time constants of 300 fs and 27.4 ps. The fast component with τ ~ 300 fs is attributed to relaxation of the CuTPP-piperidine adduct populated in the ground state, giving the intrinsic relaxation rate of the CuTPP exciplex for the first time. For CuTPP in O-coordinating solvents of 1,4-dioxane and tetrahydrofuran (THF), a completely new relaxation channel via the 2[dz2, dx2−y2] state is opened. As the exciplex formation is diffusion controlled, triplet CuTPP lifetimes in pure solvents employed here are all measured to be more or less same to give ~30 ps, whereas the 2[dz2, dx2−y2] exciplex formed by the ligation with O-coordinating solvents is found to relax much slowly to the ground state, giving lifetimes of ~360 and ~270 ps in 1,4-dioxane and THF, respectively.11sciescopu

Time resolved photoluminescence of the size controlled ZnO nanorods

Size dependence of the time-resolved photoluminescence (TRPL) has been investigated for the ZnO nanorods fabricated by catalyst-free metalorganic chemical vapor deposition. The nanorods have a diameter of 35 nm and lengths in the range of 150 nm to 1.1 mum. The TRPL decay rate decreases monotonically as the length of the nanorods increases in the range of 150 to 600 nm. Decrease of the radiative decay rate of the exciton-polariton has been invoked to account for the results

Excitation Intensity Dependent Carrier Dynamics of Chalcogen Heteroatoms in Medium-Bandgap Polymer Solar Cells

11Nsciescopu

Ultrafast time-resolved fluorescence at cryogenic temperature

Time resolved fluorescence at low temperature can be a powerful tool for the study of dynamics and spectroscopy. We have developed a time resolved fluorescence apparatus that provides a time resolution of 45 fs at cryogenic temperature, which is comparable to the best time resolution at ambient temperature. A continuous flow cryostat with a customized vacuum shroud and fluorescence upconversion gating by sum frequency generation were employed. A reflective Cassegrain type microscope objective lens was used to collect and to image the fluorescence to achieve high time resolution. It was demonstrated that time-resolved fluorescence spectra can also be measured directly without the spectra reconstruction at the same time resolution by in situ adjustment of the time delay to compensate the group velocity dispersion. Heat dissipation of the sample holder and the actual temperature of the irradiated volume were estimated by measuring the steady-state emission spectra of prodan solution in two different sample thicknesses, which provides a design consideration for the sample cell. The time-resolved fluorescence spectra of prodan, which undergoes charge transfer in the excited state, were measured at low temperature to demonstrate the capability of the apparatus. Published by AIP Publishing.11Nsciescopu

Bond formation dynamics of dicyanoaurate in the first excited singlet state

Time-resolved fluorescence of [Au(CN)2−]3 in water reveals a coherent vibration of 74 cm-1. A massive non-Condon effect, proved unambiguously by time-resolved fluorescence spectra, demonstrates that the wave packet motion arises from the coherent bond formation

Bond formation dynamics of dicyanoaurate in the first excited singlet state

Time-resolved fluorescence of [Au(CN)2−]3 in water reveals a coherent vibration of 74 cm-1. A massive non-Condon effect, proved unambiguously by time-resolved fluorescence spectra, demonstrates that the wave packet motion arises from the coherent bond formation

Excited-State Dynamics of Thioflavin T: Planar Stable Intermediate Revealed by Nuclear Wave Packet Spectroscopies

Time-domain spectroscopies with time resolution shorter than the vibrational periods of interest were employed to reveal the reaction kinetics and molecular dynamics of the intramolecular charge transfer (ICT) reaction of thioflavin T in liquids. Time-resolved fluorescence spectra provided detailed reaction kinetics, and vibrational wave packets observed in the time-resolved fluorescence and transient absorption provided structural information on the reaction intermediate. Upon photoexcitation, the Franck-Condon state undergoes vibrational relaxation and minor conformational change to form a stable planar intermediate followed by the twisting of the central C-C single bond to form the twisted ICT state. The ICT reaction rate is determined by the solvent fluctuation excluding the inertial component in the solvation function. © 2018 American Chemical Society.11sciescopu