Peculiarities associated with testing polyetheretherketone (PEEK) in a model rolling contact

Commonly used four-ball testing configuration when used to investigate rolling contact behavior of polyetheretherketone (PEEK) produced some unexpected peculiarities, namely direct contact between ceramic balls. Direct contact between lower three balls is normally not expected to take place when elastic materials (ferrous or ceramics) are tested. However, due to the viscoelastic nature of PEEK surface damage of the ceramic balls were observed leading to the production of wear debris which in turn facilitated premature failure of PEEK components of the assembly. It is postulated that caution is required when using the four-ball testing configuration to assess rolling contact performance of viscoelastic materials, such as engineering polymers.Gdansk University of Technology, Gdansk, Poland(Grant DS-2012)

Criticality in quark-gluon systems far beyond thermal and chemical equilibrium

Experimental evidence and theoretical arguments for the existence of self-organized criticality in systems of gluons and quarks are presented. It is observed that the existing data for high-transverse-momentum jet-production exhibit striking regularities; and it is shown that, together with first-principle considerations, such regularities can be used, not only to probe the possible compositness of quarks, but also to obtain {\em direct evidence} for, or against, the existence of critical temperature and/or critical chemical potential in quark-gluon systems when hadrons are squeezed together.Comment: 13 pages, including 1 figure and 1 tabl

Boron-containing organosilane polymers and ceramic materials thereof

The present invention relates to a polyorgano borosilane ceramic precursor polymer comprising a plurality of repeating units of the formula: (R(sup 1) single bond B)(sub p) being linked together at B by second units of the formula: single bond (R sup 2) single bond (Si single bond R sup 3) single bond (sub q), where R(sup 1) is a lower alkyl, cycloalkyl, phenyl, or (R(sup 2)R(sup 3) single bond Si single bond B single bond)(sub n) and R(sup 2) and R(sup 3) are each independently selected from hydrogen, lower alkyl, vinyl, cycloalkyl, or aryl, n is an integer between 1 and 100; p is an integer between 1 and 100; and q is an integer between 1 and 100. These materials are prepared by combining an organo borohalide of the formula R(sup 4) single bond B single bond (X sup 1) (sub 2) where R(sup 4) is selected from halogen, lower alkyl, cycloalkyl, or aryl, and an organo halosilane of the formula: R(sup 2)(R sup 3)Si(X sup 2)(sub 2) where R(sup 2) and R (sup 3) are each independently selected from lower alkyl, cycloalkyl, or aryl, and X(sup 1) and X(sup 2) are each independently selected from halogen, in an anhydrous aprotic solvent having a boiling point at ambient pressure of not greater than 160 C with in excess of four equivalents of an alkali metal, heating the reaction mixture and recovering the polyorgano borosilane. These silicon boron polymers are useful to generate high-temperature ceramic materials, such as SiC, SiB4, and B4C, upon thermal degradation above 600 C

Preparation of B-trichloroborazine

The present invention relates to a method of preparing B-trichloroborazine. Generally, the method includes the combination of gaseous boron trichloride in an anhydrous aprotic organic solvent followed by addition of excess gaseous ammonia at ambient temperature or below. The reaction mixture is heated to about 100 to 140 C followed by cooling, removal of the solid ammonium chloride at ambient temperature, distillation of the solvent under vacuum if necessary at a temperature of up to about 112 C, and recovery of the B-trichloroborazine. Solvents include toluene, benzene, xylene, chlorinated hydrocarbons, chlorinated aromatic compounds, or mixtures thereof. Toluene is a preferred solvent. The process provides a convenient synthesis of a material which often decomposes on standing. B-trichloroborazine is useful in a number of chemical reactions, and particularly in the formation of high temperature inorganic polymers and polymer precursors