13 research outputs found
Naturstoffchemie. 116. Mitt.: Synthese des Daurins und Folidins, 2(1H)-Chinolinon-Alkaloide aus Haplophyllum Spezies
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Community-Associated Methicillin-Resistant Staphylococcus aureus Infective Endocarditis with Panton-Valentine Leukocidin Gene in an Injection Drug User with HIV Infection
No full textInter-Slice Blood Flow and Magnetization Transfer Effects as A New Simultaneous Imaging Strategy
No full textBlocking-cyclization technique for precise synthesis of cyclic polymers with regulated topology
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Iridium-Catalyzed Silylation
No full textIn this chapter, homogeneous iridium-catalyzed silylation reactions are reviewed, focusing primarily on their synthetic utility. Additionally, relevant catalytic cycles are commented, paying especial attention to those that are more representative of each type of process. The chapter is divided into two main types of reactions, namely, hydrosilylation and C–H bond silylation. The former deals with the hydrosilylation of polar unsaturated bonds (ketones and imines) and non-polar unsaturated bonds (alkenes and alkynes). The latter covers the directed and non-directed C–H bond silylation of alkenes, alkynes, arenes, and alkanes – mainly comprising dehydrogenative silylation reactions, which may occur in the presence or absence of a hydrogen acceptor.This work was supported by the “Ramón y Cajal” program (RYC2016-20864) (FSE/Agencia Estatal de Investigación) (M. I.) and the Spanish Ministry of Science, Innovation and Universities (RTI2018-099136-A-I00).Peer reviewe
