Spatially resolved Spectroscopy of Europa's Large-scale Compositional Units at 3–4 μm with Keck NIRSPEC

We present spatially resolved spectroscopic observations of Europa's surface at 3–4 μm obtained with the near-infrared spectrograph and adaptive optics system on the Keck II telescope. These are the highest quality spatially resolved reflectance spectra of Europa's surface at 3–4 μm. The observations spatially resolve Europa's large-scale compositional units at a resolution of several hundred kilometers. The spectra show distinct features and geographic variations associated with known compositional units; in particular, large-scale leading hemisphere chaos shows a characteristic longward shift in peak reflectance near 3.7 μm compared to icy regions. These observations complement previous spectra of large-scale chaos, and can aid efforts to identify the endogenous non-ice species

Endogenic and Exogenic Contributions to Visible-wavelength Spectra of Europa’s Trailing Hemisphere

The composition of Europa's trailing hemisphere reflects the combined influences of endogenous geologic resurfacing and exogenous sulfur radiolysis. Using spatially resolved visible-wavelength spectra of Europa obtained with the Hubble Space Telescope, we map multiple spectral features across the trailing hemisphere and compare their geographies with the distributions of large-scale geology, magnetospheric bombardment, and surface color. Based on such comparisons, we interpret some aspects of our spectra as indicative of purely exogenous sulfur radiolysis products and other aspects as indicative of radiolysis products formed from a mixture of endogenous material and magnetospheric sulfur. The spatial distributions of two of the absorptions seen in our spectra—a widespread downturn toward the near-UV and a distinct feature at 530 nm—appear consistent with sulfur allotropes previously suggested from ground-based spectrophotometry. However, the geographies of two additional features—an absorption feature at 360 nm and the spectral slope at red wavelengths—are more consistent with endogenous material that has been altered by sulfur radiolysis. We suggest irradiated sulfate salts as potential candidates for this material, but we are unable to identify particular species with the available data

Observational constraints on the distribution and temperature dependence of H_2O_2 on the surface of Europa

We use Keck NIRSPEC to investigate the geographic distribution of hydrogen peroxide, a potentially biologically important oxidant, on the surface of Europa. Contrary to expectation, we see the highest abundances at low latitudes, potentially correlated with geologically young chaos terrain. We also use NASA IRTF SpeX spectra of Europa before and after eclipse to investigate the extent to which temperature controls equilibrium hydrogen peroxide concentrations on the surface. During eclipse, Europa's surface temperature falls 10-20 K. If temperature were a significant control on peroxide concentrations, then the hydrogen peroxide band strengths should be different pre- and post-eclipse. Ultimately, these investigations will help further our understanding of the surface, and perhaps subsurface, composition of Europa

Time variability of the Enceladus plumes: Orbital periods, decadal periods, and aperiodic change

The Enceladus plumes vary on a number of timescales. Tidal stresses as Enceladus revolves in its eccentric orbit lead to a periodic diurnal variation in the mass and velocity of solid particles in the plume. Tidal stresses associated with an orbital resonance with Dione lead to a periodic decadal variation. Aperiodic variations occur on time scales of months, and may be due to ice buildup and flow of the walls of the fissures that connect the ocean to the surface. We document these variations using all the relevant data taken by the ISS instrument from 2005 to 2017. Key questions now include how a 5% peak-to-peak variation in orbital eccentricity, which itself is only 0.0045, could lead to a 2-fold decadal variation in plume properties. Another question is how the plumes stay open if ice builds up every month and clogs the vents. Other questions include why the solid particles exit the vents several times slower than the gas, and why the speeds vary inversely with the mass of the plumes. The Cassini data are in, but the modeling has just begun

Time variability of the Enceladus plumes: Orbital periods, decadal periods, and aperiodic change

The Enceladus plumes vary on a number of timescales. Tidal stresses as Enceladus revolves in its eccentric orbit lead to a periodic diurnal variation in the mass and velocity of solid particles in the plume. Tidal stresses associated with an orbital resonance with Dione lead to a periodic decadal variation. Aperiodic variations occur on time scales of months, and may be due to ice buildup and flow of the walls of the fissures that connect the ocean to the surface. We document these variations using all the relevant data taken by the ISS instrument from 2005 to 2017. Key questions now include how a 5% peak-to-peak variation in orbital eccentricity, which itself is only 0.0045, could lead to a 2-fold decadal variation in plume properties. Another question is how the plumes stay open if ice builds up every month and clogs the vents. Other questions include why the solid particles exit the vents several times slower than the gas, and why the speeds vary inversely with the mass of the plumes. The Cassini data are in, but the modeling has just begun

Sodium chloride on the surface of Europa

The potential habitability of Europa’s subsurface ocean depends on its chemical composition, which may be reflected in that of Europa’s geologically young surface. Investigations using Galileo Near-Infrared Mapping Spectrometer data led to the prevailing view that Europa’s endogenous units are rich in sulfate salts. However, recent ground-based infrared observations have suggested that, while regions experiencing sulfur radiolysis may contain sulfate salts, Europa’s more pristine endogenous material may reflect a chloride-dominated composition. Chlorides have no identifying spectral features at infrared wavelengths, but develop distinct visible-wavelength absorptions under irradiation, like that experienced on the surface of Europa. Using spectra obtained with the Hubble Space Telescope, we present the detection of a 450-nm absorption indicative of irradiated sodium chloride on the surface. The feature correlates with geologically disrupted chaos terrain, suggesting an interior source. The presence of endogenous sodium chloride on the surface of Europa has important implications for our understanding of its subsurface chemistry