A Raman spectroscopic study of arsenite and thioarsenite species in aqueous solution at 25°C

The Raman spectra of thioarsenite and arsenite species in aqueous solution were obtained at room temperature. Solutions at constant ΣAs + ΣS of 0.1 and 0.5 mol kg(-1 )were prepared with various ΣS/ΣAs ratios (0.1–9.0) and pH values (~7–13.2). Our data suggest that the speciation of As under the conditions investigated is more complicated than previously thought. The Raman measurements offer evidence for at least six separate S-bearing As species whose principal bands are centered near 365, 385, 390, 400, 415 and 420 cm(-1). The data suggest that at least two different species may give rise to bands at 385 cm(-1), bringing the probable minimum number of species to seven. Several additional species are possible but could not be resolved definitively. In general, the relative proportions of these species are dependent on total As concentration, ΣS/ΣAs ratio and pH. At very low ΣS/ΣAs ratios we also observe Raman bands attributable to the dissociation products of H(3)AsO(3)(aq). Although we were unable to assign precise stoichiometries for the various thioarsenite species, we were able to map out general pH and ΣS/ΣAs conditions under which the various thioarsenite and arsenite species are predominant. This study provides a basis for more detailed Raman spectroscopic and other types of investigations of the nature of thioarsenite species

Shrinking body size as an ecological response to climate change

10.1038/nclimate1259Nature Climate Change18401-40

OPTICAL REDSHIFT AND RICHNESS ESTIMATES FOR GALAXY CLUSTERS SELECTED WITH THE SUNYAEV-ZEL'DOVICH EFFECT FROM 2008 SOUTH POLE TELESCOPE OBSERVATIONS

We present redshifts and optical richness properties of 21 galaxy clusters uniformly selected by their Sunyaev-Zel'dovich signature. These clusters, plus an additional, unconfirmed candidate, were detected in a 178 square-degree area surveyed by the South Pole Telescope in 2008. Using griz imaging from the Blanco Cosmology Survey and from pointed Magellan telescope observations, as well as spectroscopy using Magellan facilities, we confirm the existence of clustered red-sequence galaxies, report red-sequence photometric redshifts, present spectroscopic redshifts for a subsample, and derive R_200 radii and M_200 masses from optical richness. The clusters span redshifts from 0.15 to greater than 1, with a median redshift of 0.74; three clusters are estimated to be at z > 1. Redshifts inferred from mean red-sequence colors exhibit 2% RMS scatter in sigma_z/(1+z) with respect to the spectroscopic subsample for z < 1. We show that M_200 cluster masses derived from optical richness correlate with masses derived from South Pole Telescope data and agree with previously derived scaling relations to within the uncertainties. Optical and infrared imaging is an efficient means of cluster identification and redshift estimation in large Sunyaev-Zel'dovich surveys, and exploiting the same data for richness measurements, as we have done, will be useful for constraining cluster masses and radii for large samples in cosmological analysis