229 research outputs found
Structural Control of the Horizontal Double Fixation of Oligothiophenes on Gold
Quaterthiophenes bearing one (1) or two (2) alkanethiol chains attached at the internal β-position of the outermost thiophene ring through a sulfide linkage have been synthesized. Cyclic voltammetric analysis of their electrochemical behavior in solution suggests that electrooxidation of the doubly substituted oligomer 2 leads to electrodeposition of a poly(disulfide) on the anode surface. Monolayers of 1 or 2 on gold surfaces have been investigated and characterized by cyclic voltammetry, ellipsometry, contact angle measurement, and X-ray photoelectron spectroscopy. The results of these investigations indicate that introduction of two thiol groups in the structure leads to double fixation of the oligothiophene chain with the main axis of the conjugated system oriented parallel to the surface. The effects of single versus double fixation of the quaterthiophene chain on the electrochemical properties and stability of the corresponding monolayers are discussed
OPTOSAM: Surfaces aux propriétés électroniques réversiblement modifiables par stimulation optique
Date du colloque : 10/2008</p
Surface Functionalization by Monolayers of Immobilized Thiophene-based Linear pi-Conjugated Systems
Date du colloque : 10/2008</p
Self-Assembled Monolayers of π-Conjugated Molecules on Gold for Electric and Photoelectric Studies
Electropolymerized Self-Assembled Monolayers of a 3,4-Ethylenedioxythiophene-Thiophene Hybrid System
Self-assembled monolayers (SAMs) of a conjugated bithiophenic system connected to an alkanethiol chain have been deposited on gold surface. The electroactive bithiophenic system involves a 3,4-ethylenedioxythiophene (EDOT) unit and a thiophene ring on which an alkanethiol is attached at the internal β-position via a sulfide linkage. The analysis of the structure of the SAMs by IR spectroscopy, ellipsometry, contact angle measurement and X-ray photoelectron spectroscopy (XPS) provides consistent results indicating compact monolayers in which the alkyl linkers are arranged in an almost vertical fashion while the bithiophenic-conjugated systems are essentially parallel to the surface. Cyclic voltammetry shows that application of a few potential scans to SAMs immersed in a medium containing only a supporting electrolyte leads to the typical electropolymerization curves while the CV of the electrooxized monolayer exhibits a reversible cyclic voltammogram characteristic of a stable electroactive extended conjugated system. The characterization of the electropolymerized monolayers by IR spectroscopy, ellipsometry, contact angle measurement, and XPS indicates compact monolayers. The analysis of the current voltage characteristics of the monolayers by conducting AFM before and after electrooxidation shows that the enhancement of the effective conjugation resulting from electropolymerization leads to a significant increase of the transport properties
Surface Functionalization by Monolayers of Thiophene-based pi-Conjugated Systems
Date du colloque : 09/2009</p
A Crown-Ether Loop-Derivatized Oligothiophene Doubly Attached on Gold Surface as Cation-Binding Switchable Molecular Junction
Surfaces modifiées par des monocouches d‟oligothiophènes conjugués pour l‟électronique moléculaire
Date du colloque : 07/2009</p
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