Nanoparticle transport in saturated porous medium using magnetic resonance imaging

Transport study of nanoparticle (NP) through matrix flow dominated aquifer sand and soils have significant influence in natural systems. To quantify the transport behaviour, magnetic resonance imaging (MRI) was used to image the iron oxide based nanoparticle, Molday ION (carboxyl terminated) through saturated sandstone rock core. T2-weighted images were acquired and the changes in image intensity were calibrated to get a quantitative concentration profiles at various time intervals. These profiles were evaluated through CXTFIT transport model to estimate the transport parameters. These parameters are estimated at various points along the length of the column while classical breakthrough curve analysis cannot provide these details. NP–surface interactions were investigated using DLVO (Derjaguin–Landau–Verwey–Overbeek) theory. The dispersion coefficients (2.55–1.21 × 10−7 m2/s) were found to be decrease with distance, deposition rate constant k (6.70–9.13 × 10−4 (1/s)) and fast deposition rate constant kfast (4.32–8.79 × 10−2 (1/s)) were found to be increase with distance. These parameter variations over length will have a scaling up impact in developing transport models for environmental remediation and risk assessment schemes

Metagenomic sequencing unravels gene fragments with phylogenetic signatures of O2-tolerant NiFe membrane-bound hydrogenases in lacustrine sediment

Many promising hydrogen technologies utilising hydrogenase enzymes have been slowed by the fact that most hydrogenases are extremely sensitive to O2. Within the group 1 membrane-bound NiFe hydrogenase, naturally occurring tolerant enzymes do exist, and O2 tolerance has been largely attributed to changes in iron–sulphur clusters coordinated by different numbers of cysteine residues in the enzyme’s small subunit. Indeed, previous work has provided a robust phylogenetic signature of O2 tolerance [1], which when combined with new sequencing technologies makes bio prospecting in nature a far more viable endeavour. However, making sense of such a vast diversity is still challenging and could be simplified if known species with O2-tolerant enzymes were annotated with information on metabolism and natural environments. Here, we utilised a bioinformatics approach to compare O2-tolerant and sensitive membrane-bound NiFe hydrogenases from 177 bacterial species with fully sequenced genomes for differences in their taxonomy, O2 requirements, and natural environment. Following this, we interrogated a metagenome from lacustrine surface sediment for novel hydrogenases via high-throughput shotgun DNA sequencing using the Illumina™ MiSeq platform. We found 44 new NiFe group 1 membrane-bound hydrogenase sequence fragments, five of which segregated with the tolerant group on the phylogenetic tree of the enzyme’s small subunit, and four with the large subunit, indicating de novo O2-tolerant protein sequences that could help engineer more efficient hydrogenases

The Internal Spin Angular Momentum of an Asymptotically Flat Spacetime

In this paper we investigate the manner in which the internal spin angular momentum of a spinor field is encoded in the gravitational field at asymptotic infinity. The inclusion of internal spin requires us to re-analyze our notion of asymptotic flatness. In particular, the Poincar\'{e} symmetry at asymptotic infinity must replaced by a spin-enlarged Poincar\'{e} symmetry. Likewise, the generators of the asymptotic symmetry group must be supplemented to account for the internal spin. In the Hamiltonian framework of first order Einstein-Cartan gravity, the extra generator comes from the boundary term of the Gauss constraint in the asymptotically flat context. With the additional term, we establish the relations among the Noether charges of a Dirac field, the Komar integral, and the asymptotic ADM-like geometric integral. We show that by imposing mild restraints on the generating functionals of gauge transformations at asymptotic infinity, the phase space is rendered explicitly finite. We construct the energy-momentum and the new total (spin+orbital) angular momentum boundary integrals that satisfy the appropriate algebra to be the generators of the spin-enlarged Poincar\'{e} symmetry. This demonstrates that the internal spin is encoded in the tetrad at asymptotic infinity. In addition, we find that a new conserved and (spin-enlarged) Poincar\'{e} invariant charge emerges that is associated with the global structure of a gauge transformation.Comment: V2: No major changes, journal reference adde

Drought- Conditioning of Quaking Aspen (Populus tremuloides Michx.) Seedlings During Nursery Production Modifies Seedling Anatomy and Physiology

In the western US, quaking aspen (Populus tremuloides Michx.) regenerates primarily by root suckers after disturbances such as low to moderate severity fires. Planting aspen seedlings grown from seed may provide a mechanism to improve restoration success and genetic diversity on severely disturbed sites. However, few studies have examined the use of container-grown aspen seedlings for restoration purposes from both the outplanting and nursery production perspective. Thus, the purpose of this novel study was to examine how alterations in irrigation levels during nursery production across three seed sources would impact seedling performance attributes on harsh, dry outplanting sites. Irrigation treatments were based on three irrigation levels, determined gravimetrically: High = 90%, Medium = 80%, and Low = 70% of container capacity. The three seed sources represented a latitudinal gradient across the aspen range (New Mexico, Utah, and Alberta). Carbon isotope analysis indicated irrigation treatments were effective in creating higher levels of water stress for both the Low and Medium irrigation levels compared to seedlings under the High irrigation level. Seedlings subject to the Low irrigation level were found to induce greater height, higher photosynthetic rates, larger percentages of hydraulically active xylem, and faster xylem flow velocities compared to the High irrigation level. The lack of an interaction between irrigation treatments and seed source for nearly all response variables suggests that nursery conditioning via irrigation limitations may be effective for a range of aspen seed sources

Spectroscopy of Hadrons with b Quarks from Lattice NRQCD

Preliminary results from an extensive lattice calculation of the B, B_c, and \Upsilon spectrum at quenched \beta = 6.0 are presented. The study includes radially and orbitally excited mesons, and baryons containing b quarks. The b quarks are formulated using NRQCD; for light and c quarks, a tadpole-improved clover action is used.Comment: talk given at LATTICE98(heavyqk), 3 pages LaTeX, 2 Postscript figure

B Meson Decay Constants From NRQCD

We present quenched results for B meson decay constants using NRQCD b quarks and O(a) tadpole improved clover light quarks. For the first time, one-loop matching factors between lattice and continuum currents are incorporated through O(\alpha/M) taking operator mixing fully into account. This includes an important O(\alpha a) discretization correction to the heavy-light axial vector current. We find f_B = 0.147(11)(^{+8}_{-12})(9)(6) MeV and f_{B_s}/f_B = 1.20(4)(^{+4}_{-0}). PACS numbers: 12.38.Gc, 12.39.Hg, 13.20.He, 14.40.NdComment: LaTeX file, 14 pages, typos corrected, to be published in Phys. Lett.

Simulation of Cosmic Ray neutrinos Interactions in Water

The program CORSIKA, usually used to simulate extensive cosmic ray air showers, has been adapted to a water medium in order to study the acoustic detection of ultra high energy neutrinos. Showers in water from incident protons and from neutrinos have been generated and their properties are described. The results obtained from CORSIKA are compared to those from other available simulation programs such as Geant4.Comment: Talk presented on behalf of the ACoRNE Collaboration at the ARENA Workshop 200