A zero dimensional model of lithium-sulfur batteries during charge and discharge

Lithium-sulfur cells present an attractive alternative to Li-ion batteries due to their large energy density, safety, and possible low cost. Their successful commercialisation is dependent on improving their performance, but also on acquiring sufficient understanding of the underlying mechanisms to allow for the development of predictive models for operational cells. To address the latter, we present a zero dimensional model that predicts many observed features in the behaviour of a lithium-sulfur cell during charge and discharge. The model accounts for two electrochemical reactions via the Nernst formulation, power limitations through Butler-Volmer kinetics, and precipitation/dissolution of one species, including nucleation. It is shown that the precipitation/dissolution causes the flat shape of the low voltage plateau, typical of the lithium-sulfur cell discharge. During charge, it is predicted that the dissolution can act as a bottleneck, as for large enough currents smaller amounts dissolve. This results in reduced charge capacity and an earlier onset of the high plateau reaction, such that the two plateaus merge. By including these effects, the model improves on the existing zero dimensional models, while requiring considerably fewer input parameters and computational resources. The model also predicts that, due to precipitation, the customary way of experimentally measuring the open circuit voltage from a low rate discharge might not be suitable for lithium-sulfur. This model can provide the basis for mechanistic studies, identification of dominant effects in a real cell, predictions of operational behaviour under realistic loads, and control algorithms for applications

Characterizing Some Gaia Alerts with LAMOST and SDSS

Gaia is regularly producing Alerts on objects where photometric variability has been detected. The physical nature of these objects has often to be determined with the complementary observations from ground-based facilities. We have compared the list of Gaia Alerts (until 20181101) with archival LAMOST and SDSS spectroscopic data. The date of the ground-based observation rarely corresponds to the date of the Alert, but this allows at least the identification of the source if it is persistent, or the host galaxy if the object was only transient like a supernova. A list of Gaia Nuclear Transients from Kostrzewa-Rutkowska et al. (2018) has been included in this search also. We found 26 Gaia Alerts with spectra in LAMOST+SDSS labelled as stars (12 with multi-epoch spectra). A majority of them are CVs. Similarly 206 Gaia Alerts have associated spectra labelled as galaxies (49 with multi-epoch spectra). Those spectra were generally obtained on a date different from the Alert date, are mostly emission-line galaxies, leading to the suspicion that most of the Alerts were due to a SN. As for the GNT list, we found 55 associated spectra labelled as galaxies (13 with multi-epoch spectra). In two galaxies, Gaia17aal and GNTJ170213+2543, was the date of the spectroscopic observation close enough to the Alert date: we find a trace of the SN itself in their LAMOST spectrum, both classified here as a type Ia SN. The GNT sample has a higher proportion of AGNs, suggesting that some of the detected variations are also due to the AGN itself. Similar for Quasars, we found 30 Gaia Alerts but 68 GNT cases have single epoch quasar spectra, while 12 plus 23 have multi-epoch spectra. For ten out of these 35, their multi-epoch spectra show appearance or disappearance of the broad Balmer lines and also variations in the continuum, qualifying them as "Changing Look Quasars".Comment: Accepted for publication in APSS, 14 pages, 8 figures, 2 table