594 research outputs found
NaV_2O_5 as an Anisotropic t-J Ladder at Quarter Filling
Based on recent experimental evidences that the electronic charge degrees of
freedom plays an essential role in the spin-Peierls--like phase transition of
NaVO, we first make the mapping of low-energy electronic states of the
model for NaVO to the quarter-filled ladder with
anisotropic parameter values between legs and rungs, and then show that this
anisotropic ladder is in the Mott insulating state, of which
lowest-energy states can be modeled by the one-dimensional Heisenberg
antiferromagnet with the effective exchange interaction whose value
is consistent with experimental estimates. We furthermore examine the coupling
between the ladders as the trellis lattice model and show that the
nearest-neighbor Coulomb repulsion on the zigzag-chain bonds can lead to the
instability in the charge degrees of freedom of the ladders.Comment: 4 pages, 5 gif figures. Fig.3 corrected. Hardcopies of figures (or
the entire manuscript) can be obtained by e-mail request to
[email protected]
Low-Temperature Structure of the Quarter-Filled Ladder Compound alpha'-NaV2O5
The low-temperature (LT) superstructure of -NaVO was
determined by synchrotron radiation x-ray diffraction. Below the phase
transition temperature associated with atomic displacement and charge ordering
at 34K, we observed the Bragg peak splittings, which evidence that the LT
structure is monoclinic. It was determined that the LT structure is
with the space group where and
represent the high temperature orthorhombic unit cell. The valence estimation
of V ions according to the bond valence sum method shows that the V sites are
clearly separated into two groups of V and V with a
charge ordering pattern. This LT structure is consistent with resonant x-ray
and NMR measurements, and strikingly contrasts to the LT structure previously
reported, which includes V sites.Comment: 4 pages, 3 figures, 1 tabl
Zigzag Charge Ordering in alpha'-NaV2O5
23Na NMR spectrum measurements in alpha'-NaV2O5 with a single- crystalline
sample are reported. In the charge-ordered phase, the number of inequivalent Na
sites observed is more than that expected from the low-temperature structures
of space group Fmm2 reported so far. This disagreement indicates that the real
structure including both atomic displacement and charge disproportionation is
of lower symmetry. It is suggested that zigzag ordering is the most probable.
The temperature variation of the NMR spectra near the transition temperature is
incompatible with that of second-order transitions. It is thus concluded that
the charge ordering transition is first-order.Comment: 4 pages, 5 eps figures, submitted to J. Phys. Soc. Jp
Competition between Pauli and orbital effects in a charge-density wave system
We present angular dependent magneto-transport and magnetization measurements
on alpha-(ET)2MHg(SCN)4 compounds at high magnetic fields and low temperatures.
We find that the low temperature ground state undergoes two subsequent
field-induced density-wave type phase transitions above a critical angle of the
magnetic field with respect to the crystallographic axes. This new phase
diagram may be qualitatively described assuming a charge density wave ground
state which undergoes field-induced transitions due to the interplay of Pauli
and orbital effects.Comment: 11 pages, 4 figures, shown at the APS march meeting 2000, appears in
the Ph.D. thesis of J. S. Qualls (Florida State University, 1999), and
submitted to PR
- …