115 research outputs found
Infrared and Raman spectra of LiV2O5 single crystals
The phonon dynamics of LiV2O5 single crystals is studied using infrared and
Raman spectroscopy techniques. The infrared-active phonon frequencies and
dielectric constants are obtained by oscillator fitting procedure of the
reflectivity data measured at room temperature. The Raman scattering spectra
are measured at room temperature and at T=10 K in all nonequivalent polarized
configurations. The assignment of the phonons is done by comparing the infrared
and Raman spectra of LiV2O5 and NaV2O5. The factor-group-analysis of the LiV2O5
crystal symmetry and of its constituent layers is performed to explain the
symmetry properties of the observed modes. We concluded that layer symmetry
dominates in the vibrational properties of this compound.Comment: 10 pages, 5 figure
Isotropic Conductivity of Two-Dimensional Three-Component Symmetric Composites
The effective dc-conductivity problem of isotropic, two-dimensional (2D),
three-component, symmetric, regular composites is considered. A simple cubic
equation with one free parameter for
is suggested whose solutions automatically have all the exactly known
properties of that function. Numerical calculations on four different
symmetric, isotropic, 2D, three-component, regular structures show a
non-universal behavior of with an
essential dependence on micro-structural details, in contrast with the
analogous two-component problem. The applicability of the cubic equation to
these structures is discussed. An extension of that equation to the description
of other types of 2D three-component structures is suggested, including the
case of random structures.
Pacs: 72.15.Eb, 72.80.Tm, 61.50.AhComment: 8 pages (two columns), 8 figures. J. Phys. A - submitte
Anomalous Lattice Vibrations of Single and Few-Layer MoS2
Molybdenum disulfide (MoS2) of single and few-layer thickness was exfoliated
on SiO2/Si substrate and characterized by Raman spectroscopy. The number of
S-Mo-S layers of the samples was independently determined by contact-mode
atomic-force microscopy. Two Raman modes, E12g and A1g, exhibited sensitive
thickness dependence, with the frequency of the former decreasing and that of
the latter increasing with thickness. The results provide a convenient and
reliable means for determining layer thickness with atomic-level precision. The
opposite direction of the frequency shifts, which cannot be explained solely by
van der Waals interlayer coupling, is attributed to Coulombic interactions and
possible stacking-induced changes of the intralayer bonding. This work
exemplifies the evolution of structural parameters in layered materials in
changing from the 3-dimensional to the 2-dimensional regime.Comment: 14 pages, 4 figure
Mechanical and Electronic Properties of MoS Nanoribbons and Their Defects
We present our study on atomic, electronic, magnetic and phonon properties of
one dimensional honeycomb structure of molybdenum disulfide (MoS) using
first-principles plane wave method. Calculated phonon frequencies of bare
armchair nanoribbon reveal the fourth acoustic branch and indicate the
stability. Force constant and in-plane stiffness calculated in the harmonic
elastic deformation range signify that the MoS nanoribbons are stiff quasi
one dimensional structures, but not as strong as graphene and BN nanoribbons.
Bare MoS armchair nanoribbons are nonmagnetic, direct band gap
semiconductors. Bare zigzag MoS nanoribbons become half-metallic as a
result of the (2x1) reconstruction of edge atoms and are semiconductor for
minority spins, but metallic for the majority spins. Their magnetic moments and
spin-polarizations at the Fermi level are reduced as a result of the
passivation of edge atoms by hydrogen. The functionalization of MoS
nanoribbons by adatom adsorption and vacancy defect creation are also studied.
The nonmagnetic armchair nanoribbons attain net magnetic moment depending on
where the foreign atoms are adsorbed and what kind of vacancy defect is
created. The magnetization of zigzag nanoribbons due to the edge states is
suppressed in the presence of vacancy defects.Comment: 11 pages, 5 figures, first submitted at November 23th, 200
Effective mechanical properties of multilayer nano-heterostructures
Two-dimensional and quasi-two-dimensional materials are important nanostructures because of their exciting electronic, optical, thermal, chemical and mechanical properties. However, a single-layer nanomaterial may not possess a particular property adequately, or multiple desired properties simultaneously. Recently a new trend has emerged to develop nano-heterostructures by assembling multiple monolayers of different nanostructures to achieve various tunable desired properties simultaneously. For example, transition metal dichalcogenides such as MoS2 show promising electronic and piezoelectric properties, but their low mechanical strength is a constraint for practical applications. This barrier can be mitigated by considering graphene-MoS2 heterostructure, as graphene possesses strong mechanical properties. We have developed efficient closed-form expressions for the equivalent elastic properties of such multi-layer hexagonal nano-hetrostructures. Based on these physics-based analytical formulae, mechanical properties are investigated for different heterostructures such as graphene-MoS2, graphene-hBN, graphene-stanene and stanene-MoS2. The proposed formulae will enable efficient characterization of mechanical properties in developing a wide range of application-specific nano-heterostructures
Investigation of Unsteady/Quasi-Steady Scramjet Behavior using High-Speed Visualization Techniques
Experiments are carried out in the HEG (High Enthalpy Shock Tunnel Göttingen) wind-tunnel to obtain detailed measurements on the HyShot II scramjet configuration at equivalence ratios close to the incipient choking point at simulated 28-km altitude flight conditions. Diagnostic techniques include time-resolved pressure measurements and simultaneous high-speed schlieren and OH* chemiluminescence imaging. Similar to previous experiments at higher equivalence ratios, the onset of choking is signaled by the formation of an unsteady shock train that initially propagates up the duct. The shock motion then slows, however, and a quasi-steady topology develops with the shock lodged at a position that depends strongly on the equivalence ratio (the position lying further upstream for higher equivalence ratios). This topology persists until the conclusion of the steady test time. Based on these measurements, a value for the critical choking equivalence ratio, i.e., that at which the shock train first appears, in the range of 0.38-0.39 is determined. High-speed temperature sensitive paint measurements are also carried out on the model intake ramp to provide global information on the boundary-layer transition behavior
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