13 research outputs found
Local electronic structure of Fe impurities in MgO thin films: Temperature-dependent soft x-ray absorption spectroscopy study
We report on the local electronic structure of Fe impurities in MgO thin
films. Using soft x-ray absorption spectroscopy (XAS) we verified that the Fe
impurities are all in the 2+ valence state. The fine details in the line shape
of the Fe edges provide direct evidence for the presence of a
dynamical Jahn-Teller distortion. We are able to determine the magnitude of the
effective crystal field energies. We also observed a strong
temperature dependence in the spectra which we can attribute to the thermal
population of low-lying excited states that are present due to the spin-orbit
coupling in the Fe 3d. Using this Fe impurity system as an example, we
show that an accurate measurement of the orbital moment in FeO will
provide a direct estimate for the effective local low-symmetry crystal fields
on the Fe sites, important for the theoretical modeling of the formation
of orbital ordering
Epitaxial and layer-by-layer growth of EuO thin films on yttria-stabilized cubic zirconia (001) using MBE distillation
We have succeeded in growing epitaxial and highly stoichiometric films of EuO
on yttria-stabilized cubic zirconia (YSZ) (001). The use of the Eu-distillation
process during the molecular beam epitaxy assisted growth enables the
consistent achievement of stoichiometry. We have also succeeded in growing the
films in a layer-by-layer fashion by fine tuning the Eu vs. oxygen deposition
rates. The initial stages of growth involve the limited supply of oxygen from
the YSZ substrate, but the EuO stoichiometry can still be well maintained. The
films grown were sufficiently smooth so that the capping with a thin layer of
aluminum was leak tight and enabled ex situ experiments free from trivalent Eu
species. The findings were used to obtain recipes for better epitaxial growth
of EuO on MgO (001).Comment: 10 pages, 15 figure
Epitaxy, stoichiometry, and magnetic properties of Gd-doped EuO films on YSZ (001)
We have succeeded in preparing high-quality Gd-doped single-crystalline EuO
films. Using Eu-distillation-assisted molecular beam epitaxy and a systematic
variation in the Gd and oxygen deposition rates, we have been able to observe
sustained layer-by-layer epitaxial growth on yttria-stabilized cubic zirconia
(001). The presence of Gd helps to stabilize the layer-by-layer growth mode. We
used soft x-ray absorption spectroscopy at the Eu and Gd M4,5 edges to confirm
the absence of Eu3+ contaminants and to determine the actual Gd concentration.
The distillation process ensures the absence of oxygen vacancies in the films.
From magnetization measurements we found the Curie temperature to increase
smoothly as a function of doping from 70 K up to a maximum of 125 K. A
threshold behavior was not observed for concentrations as low as 0.2%.Comment: 8 pages, 9 figure
Electronic structure of SrPt_4Ge_{12}: a combined photoelectron spectroscopy and band structure study
We present a combined study of the electronic structure of the
superconducting skutterudite derivative SrPt4Ge12 by means of X-ray
photoelectron spectroscopy and full potential band structure calculations
including an analysis of the chemical bonding. We establish that the states at
the Fermi level originate predominantly from the Ge 4p electrons and that the
Pt 5d shell is effectively full. We find excellent agreement between the
measured and the calculated valence band spectra, thereby validating that band
structure calculations in combination with photoelectron spectroscopy can
provide a solid basis for the modeling of superconductivity in the compounds
MPt4Ge12 (M = Sr, Ba, La, Pr) series
Optimizing polarization dependent hard X-ray photoemission experiments for solids
Polarization dependent hard X-ray photoemission (HAXPES) experiments are a very powerful tool to identify the nature of the orbitals contributing to the valence band. To optimize this type of experiments we have set up a photoelectron spectroscopy system consisting of two electron energy analyzers mounted such that one detects the photoelectrons propagating parallel to the polarization vector (E) of the light and the other perpendicular. This method has the advantage over using phase retarders (to rotate the E-vector of the light) that the full intensity and full polarization of the light is available for the experiments. Using NiO as an example, we are able to identify reliably the Ni 3d spectral weight of the valence band and at the same time demonstrate the importance of the Ni 4s for the chemical stability of the compound. We have also discovered the limitations of this type of polarization dependent experiments: the polarization dependence is less than expected on the basis of calculations for free atoms and we can ascribe this incompleteness of the polarization dependence to the presence of appreciable side-scattering effects of the outgoing electrons, even at these high kinetic energies in the 6–8 keV range. © Springer International Publishing Switzerland 2016
Challenges from experiment: electronic structure of NiO
We report on a detailed experimental and theoretical study of the electronic structure of NiO. The charge-transfer nature of the band gap as well as the intricate interplay between local electronic correlations and band formation makes NiO to be a challenging case for a quantitative ab-initio modeling of its electronic structure. To reproduce the compensated-spin character of the first ionization state and the state created by hole doping requires a reliable determination of the charge transfer energy Δ relative to the Hubbard U. Furthermore, the presence of non-local screening processes makes it necessary to go beyond single-site many body approaches to explain the valence band spectrum
Epitaxial and layer-by-layer growth of EuO thin films on yttria-stabilized cubic zirconia (001) using MBE distillation
We have succeeded in growing epitaxial and highly stoichiometric films of EuO on yttria-stabilized cubic zirconia (YSZ) (001). The use of the Eu-distillation process during the molecular beam epitaxy assisted growth enables the consistent achievement of stoichiometry. We have also succeeded in growing the films in a layer-by-layer fashion by fine tuning the Eu vs oxygen deposition rates. The initial stages of growth involve the limited supply of oxygen from the YSZ substrate, but the EuO stoichiometry can still be well maintained. The films grown were sufficiently smooth so that the capping with a thin layer of aluminum was leak tight and enabled ex situ experiments free from trivalent Eu species. The findings were used to obtain recipes for better epitaxial growth of EuO on MgO (001)
Epitaxy, stoichiometry, and magnetic properties of Gd-doped EuO films on YSZ (001)
We have succeeded in preparing high-quality Gd-doped single-crystalline EuO films. Using Eu-distillation-assisted molecular beam epitaxy and a systematic variation in the Gd and oxygen deposition rates, we have been able to observe sustained layer-by-layer epitaxial growth on yttria-stabilized cubic zirconia (001). The presence of Gd helps to stabilize the layer-by-layer growth mode. We used soft x-ray absorption spectroscopy at the Eu and Gd M4,5 edges to confirm the absence of Eu3+ contaminants and to determine the actual Gd concentration. The distillation process ensures the absence of oxygen vacancies in the films. From magnetization measurements we found the Curie temperature to increase smoothly as a function of doping from 70 K up to a maximum of 125 K. A threshold behavior was not observed for concentrations as low as 0.2%