165 research outputs found
Magnetotransport Properties of Quasi-Free Standing Epitaxial Graphene Bilayer on SiC: Evidence for Bernal Stacking
We investigate the magnetotransport properties of quasi-free standing
epitaxial graphene bilayer on SiC, grown by atmospheric pressure graphitization
in Ar, followed by H intercalation. At the charge neutrality point the
longitudinal resistance shows an insulating behavior, which follows a
temperature dependence consistent with variable range hopping transport in a
gapped state. In a perpendicular magnetic field, we observe quantum Hall states
(QHSs) both at filling factors () multiple of four (), as
well as broken valley symmetry QHSs at and . These results
unambiguously show that the quasi-free standing graphene bilayer grown on the
Si-face of SiC exhibits Bernal stacking.Comment: 12 pages, 5 figure
Photo-physics and electronic structure of lateral graphene/MoS2 and metal/MoS2 junctions
Integration of semiconducting transition metal dichalcogenides (TMDs) into
functional optoelectronic circuitries requires an understanding of the charge
transfer across the interface between the TMD and the contacting material.
Here, we use spatially resolved photocurrent microscopy to demonstrate
electronic uniformity at the epitaxial graphene/molybdenum disulfide (EG/MoS2)
interface. A 10x larger photocurrent is extracted at the EG/MoS2 interface when
compared to metal (Ti/Au) /MoS2 interface. This is supported by semi-local
density-functional theory (DFT), which predicts the Schottky barrier at the
EG/MoS2 interface to be ~2x lower than Ti/MoS2. We provide a direct
visualization of a 2D material Schottky barrier through combination of angle
resolved photoemission spectroscopy with spatial resolution selected to be ~300
nm (nano-ARPES) and DFT calculations. A bending of ~500 meV over a length scale
of ~2-3 micrometer in the valence band maximum of MoS2 is observed via
nano-ARPES. We explicate a correlation between experimental demonstration and
theoretical predictions of barriers at graphene/TMD interfaces. Spatially
resolved photocurrent mapping allows for directly visualizing the uniformity of
built-in electric fields at heterostructure interfaces, providing a guide for
microscopic engineering of charge transport across heterointerfaces. This
simple probe-based technique also speaks directly to the 2D synthesis community
to elucidate electronic uniformity at domain boundaries alongside morphological
uniformity over large areas
Carotenoid Distribution in Living Cells of Haematococcus pluvialis (Chlorophyceae)
Haematococcus pluvialis is a freshwater unicellular green microalga belonging to the class Chlorophyceae and is of commercial interest for its ability to accumulate massive amounts of the red ketocarotenoid astaxanthin (3,3′-dihydroxy-β,β-carotene-4,4′-dione). Using confocal Raman microscopy and multivariate analysis, we demonstrate the ability to spectrally resolve resonance–enhanced Raman signatures associated with astaxanthin and β-carotene along with chlorophyll fluorescence. By mathematically isolating these spectral signatures, in turn, it is possible to locate these species independent of each other in living cells of H. pluvialis in various stages of the life cycle. Chlorophyll emission was found only in the chloroplast whereas astaxanthin was identified within globular and punctate regions of the cytoplasmic space. Moreover, we found evidence for β-carotene to be co-located with both the chloroplast and astaxanthin in the cytosol. These observations imply that β-carotene is a precursor for astaxanthin and the synthesis of astaxanthin occurs outside the chloroplast. Our work demonstrates the broad utility of confocal Raman microscopy to resolve spectral signatures of highly similar chromophores in living cells
SITE‐TO‐SITE DIFFUSION IN PROTEINS AS OBSERVED BY ENERGY TRANSFER AND FREQUENCY‐DOMAIN FLUOROMETRY *
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