4,067 research outputs found
The gas phase cyclization of deprotonated N-aryl-2-cyano-2-diazoacetamides
The document attached has been archived with permission from the publisher.1-Aryl-4-cyano-5-hydroxy-1,2,3-triazoles can be obtained in solution by base-catalysed cyclization of N-aryl-2-cyano-2-diazoacetamides. A similar reaction was shown to take place under conditions of negative ion chemical ionization in the ion source of a mass spectrometer. High resolution mass spectrometry, tandem mass spectrometry, charge reversal spectra, synthesis of the ions with known structures and quantum chemical calculations were used to prove the latter statement. The fact of the observed cyclization demonstrates once again the ability of mass spectrometry to study the gas phase chemical reactions that take place in solution.Vladislav V. Lobodin, Yuriy Yu. Morzherin, Tom Blumenthal, Daniel Bilusich, Vladimir V. Ovcharenko, John H. Bowie, and Albert T. Lebede
Single-parameter non-adiabatic quantized charge pumping
Controlled charge pumping in an AlGaAs/GaAs gated nanowire by
single-parameter modulation is studied experimentally and theoretically.
Transfer of integral multiples of the elementary charge per modulation cycle is
clearly demonstrated. A simple theoretical model shows that such a quantized
current can be generated via loading and unloading of a dynamic quasi-bound
state. It demonstrates that non-adiabatic blockade of unwanted tunnel events
can obliterate the requirement of having at least two phase-shifted periodic
signals to realize quantized pumping. The simple configuration without multiple
pumping signals might find wide application in metrological experiments and
quantum electronics.Comment: 4 pages, 4 figure
In vitro and in vivo anticancer efficacy of unconjugated humanised anti-CEA monoclonal antibodies
Inverse Compton Scattering as the Source of Diffuse EUV Emission in the Coma Cluster of Galaxies
We have examined the hypothesis that the majority of the diffuse EUV flux in
the Coma cluster is due to inverse Compton scattering of low energy cosmic ray
electrons (0.16 < epsilon < 0.31 GeV) against the 3K black-body background. We
present data on the two-dimensional spatial distribution of the EUV flux and
show that these data provide strong support for a non-thermal origin for the
EUV flux. However, we show that this emission cannot be produced by an
extrapolation to lower energies of the observed synchrotron radio emitting
electrons and an additional component of low energy cosmic ray electrons is
required.Comment: 11 pages, 5 figure
Multiple electron pumping
The need to pump single electrons with a high degree of accuracy and fidelity has led to the development of a range of different pump and turnstile designs. Previous pumping mechanisms have all demonstrated that pumping more than one electron per cycle degrades the quantisation of the measured current. This unreliable delivery of multiple electrons per cycle has limited the use of on-demand single electron sources in electron quantum optic experiments. We present highly quantised current with multiple electrons pumped per cycle. We experimentally demonstrate that in our pumps an increase in electron throughput per cycle does not lead to an appreciable degradation in the accuracy of the produced current. Our pump is realised in an aluminium gallium arsenide two-dimensional electron gas, where electrons are pumped through a one-dimensional split-gate confinement potential under the influence of an applied source-drain voltage VSD , and where the pump is driven by a trapezoidal arbitrary waveform. This combination of a split-gate potential, VSD bias and trapezoidal wave form has led to the observation of robust quantised plateaus where not just a single electron, but a multiple integer number of electrons are pumped per cycle with a high degree of robustness and without the need of a magnetic field. For seven electrons per cycle, we report an increase of over two orders of magnitude in pumping accuracy from 2.72 × 10 − 2 in devices operating in the conventional pumping regime, to 1.64 × 10 − 4 in pumps operating in what we call the long plateau regime, a regime accessed under a change in a split-gate pumps applied VSD voltage. This pump will find direct use in quantum transport measurements where the metrological accuracy of single electrons pumped per cycle is not required and the low throughput per cycle of electrons is limiting
A depression before a bump in the highest energy cosmic ray spectrum
We re-examine the interaction of ultra high energy nuclei with the microwave
background radiation. We find that the giant dipole resonance leaves a new
signature in the differential energy spectrum of iron sources located around 3
Mpc: A depression before the bump which is followed by the expected cutoff.Comment: revisited version, 5 pages RevTex, 5 figure
Spectroscopy of Po
Prompt, in-beam rays following the reaction Yb + 142 MeV
Si were measured at the ATLAS facility using 10 Compton-suppressed Ge
detectors and the Fragment Mass Analyzer. Transitions in Po were
identified and placed using -ray singles and coincidence data gated on
the mass of the evaporation residues. A level spectrum up to
J10 was established. The structure of Po is more
collective than that observed in the heavier polonium isotopes and indicates
that the structure has started to evolve towards the more collective nature
expected for deformed nuclei.Comment: 8 pages, revtex 3.0, 4 figs. available upon reques
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