173 research outputs found
A Unifying Variational Framework for Gaussian Process Motion Planning
To control how a robot moves, motion planning algorithms must compute paths
in high-dimensional state spaces while accounting for physical constraints
related to motors and joints, generating smooth and stable motions, avoiding
obstacles, and preventing collisions. A motion planning algorithm must
therefore balance competing demands, and should ideally incorporate uncertainty
to handle noise, model errors, and facilitate deployment in complex
environments. To address these issues, we introduce a framework for robot
motion planning based on variational Gaussian Processes, which unifies and
generalizes various probabilistic-inference-based motion planning algorithms.
Our framework provides a principled and flexible way to incorporate
equality-based, inequality-based, and soft motion-planning constraints during
end-to-end training, is straightforward to implement, and provides both
interval-based and Monte-Carlo-based uncertainty estimates. We conduct
experiments using different environments and robots, comparing against baseline
approaches based on the feasibility of the planned paths, and obstacle
avoidance quality. Results show that our proposed approach yields a good
balance between success rates and path quality
A cocrystal of 3α-hydroxytirucalla-8,24-dien-21-oic acid and 3β-fluorotirucalla-7,24-dien-21-oic acid (0.897:0.103)
The title compound, 0.897C30H48O3.0.103C30H47O2F is a co-crystal of two triterpenes isolated from the resin of Canarium schweinfurthiiand Engl. Both triterpenes consists of four trans-fused rings having chair/half-chair/half-chair and envelope conformations. The molecular conformations are stabilized by intramolecular C—H⋯O hydrogen bonds, forming rings of S(7) graph-set motif. In the crystal, molecules are linked by intermolecular O—H⋯O and C—H⋯O interactions, forming sheets parallel to (001). All atoms. excepting the axially-oriented hydroxyl group in the major component and the equatorially-oriented fluorine atom in the minor component, are overlapping
3α-Hydroxytirucalla-8,24-dien-21-oic acid
The title compound, C30H48O3, a triterpene isolated from the resin of canarium schweinfurthiiand, is an isomer of the previously reported triterpene 3α-hydroxytirucalla-7,24-dien-21-oic acid [Mora et al. (2001 ▶). Acta Cryst. C57, 638–640], which crystallizes in the same trigonal space group. The title molecule consists of four fused rings having chair, half-chair, half-chair and envelope conformations for rings A, B, C and D, respectively (steroid labelling). An intramolecular C—H⋯O hydrogen bond generates an S(7) ring. In the crystal, molecules are linked by O—H⋯O and C—H⋯O interactions, forming (001) sheets
Bis(2-aminothiazolium) succinate succinic acid
In the title compound, 2C3H5N2S+·C4H4O4
2−·C4H6O4, the thiazolium ring is almost planar, with the maximum deviation from planarity being 0.0056 (8) Å for the C atom carrying the amine substituent. The N atom of the 2-aminothiazole molecule is protonated. Both the anion and the acid lie across inversion centres. The crystal packing is consolidated by intermolecular O—H⋯O, N—H⋯O and C—H⋯O hydrogen bonds. Molecules are stacked down the b axis
2-Ethylpiperidinium chloride
In the title molecular salt, C7H16N+·Cl−, the piperidinium ring adopts a chair conformation. In the crystal, the two components are connected by N—H⋯Cl and C—H⋯Cl hydrogen bonds, forming a supramolecular double-chain structure along the c axis
Monoclinic polymorph of poly[aqua(μ4-hydrogen tartrato)sodium]
A monoclinic polymorph of the title compound, [Na(C4H5O6)(H2O)]n, is reported and complements an orthorhombic form [Kubozono, Hirano, Nagasawa, Maeda & Kashino (1993 ▶). Bull. Chem. Soc. Jpn, 66, 2166–2173]. The asymmetric unit contains a hydrogen tartrate anion, an Na+ cation and a water molecule. The Na+ ion is surrounded by seven O atoms derived from one independent and three symmetry-related hydrogen tartrate anions, and a water molecule, forming a distorted pentagonal–bipyramidal geometry. Independent units are linked via a pair of intermolecular bifurcated O—H⋯O acceptor bonds, generating an R
2
1(6) ring motif to form polymeric two-dimensional arrays parallel to the (100) plane. In the crystal packing, the arrays are linked by adjacent ring motifs, together with additional intermolecular O—H⋯O interactions, into a three-dimensional network
2,6-Difluorobenzoic acid
In the title compound, C7H4F2O2, the dihedral angle between the benzene ring and the carboxylate group is 33.70 (14)°. In the crystal structure, inversion dimers linked by pairs of O—H⋯O hydrogren bonds occur, generating R
2
2(8) loops. The dimers are linked into sheets lying parallel to (102) by C—H⋯F hydrogen bonds
N,N′-[4,4′-Methylenebis(4,1-phenylene)]bis(2,6-difluorobenzamide)
The complete molecule of the title compound, C27H18F4N2O2, is generated by crystallographic twofold symmetry, with one C atom lying on the rotation axis. The dihedral angle between fluoro-substituted phenyl ring and the adjacent benzene ring is 10.37 (5)°. In the crystal, molecules are connected by N—H⋯O and C—H⋯F hydrogen bonds, resulting in supramolecular chains propagating along the c direction
Triethylammonium 4-nitrobenzenesulfonate
In the anion of the title molecular salt, C6H16N+·C6H4O5S−, the nitro group is twisted slightly from the benzene ring, making a dihedral angle of 3.16 (10)°. In the crystal structure, the cations and anions are linked into a two-dimensional network parallel to the ab plane by C—H⋯O and N—H⋯O hydrogen bonds
Poly[μ2-aqua-(μ3-2,5-dichlorobenzenesulfonato)sodium]
In the title compound, [Na(C6H3Cl2O3S)(H2O)]n, the NaI ion is pentacoordinated by three dichlorobenzenesulfonate anions and two water molecules, forming a distorted trigonal-bipyramidal geometry. The NaI ions are bridged by the sulfonate groups and the water molecules, leading to a polymeric layer structure parallel to the bc plane in which O—H⋯O hydrogen bonds are observed
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