1,245 research outputs found
-Electron Ferromagnetism in Metal Free Carbon Probed by Soft X-Ray Dichroism
Elemental carbon represents a fundamental building block of matter and the
possibility of ferromagnetic order in carbon attracted widespread attention.
However, the origin of magnetic order in such a light element is only poorly
understood and has puzzled researchers. We present a spectromicroscopy study at
room temperature of proton irradiated metal free carbon using the elemental and
chemical specificity of x-ray magnetic circular dichroism (XMCD). We
demonstrate that the magnetic order in the investigated system originates only
from the carbon -electron system.Comment: 10 pages 3 color figure
The role of hydrogen in room-temperature ferromagnetism at graphite surfaces
We present a x-ray dichroism study of graphite surfaces that addresses the
origin and magnitude of ferromagnetism in metal-free carbon. We find that, in
addition to carbon states, also hydrogen-mediated electronic states
exhibit a net spin polarization with significant magnetic remanence at room
temperature. The observed magnetism is restricted to the top 10 nm of
the irradiated sample where the actual magnetization reaches emu/g
at room temperature. We prove that the ferromagnetism found in metal-free
untreated graphite is intrinsic and has a similar origin as the one found in
proton bombarded graphite.Comment: 10 pages, 5 figures, 1 table, submitted to New Journal of Physic
Magnetic phase diagram of the Hubbard model with next-nearest-neighbour hopping
We calculate the magnetic phase diagram of the Hubbard model for a Bethe
lattice with nearest neighbour (NN) hopping and next nearest neighbour
(NNN) hopping in the limit of infinite coordination. We use the amplitude
of the NNN hopping to tune the density of states (DOS) of the
non-interacting system from a situation with particle-hole symmetry to an
asymmetric one with van-Hove singularities at the lower ()
respectively upper () band edge for large enough . For
this strongly asymmetric situation we find rather extended parameter regions
with ferromagnetic states and regions with antiferromagnetic states.Comment: 13 pages, 7 figure
Ultrafast optical control of magnetization in EuO thin films
All-optical pump-probe detection of magnetization precession has been
performed for ferromagnetic EuO thin films at 10 K. We demonstrate that the
circularly-polarized light can be used to control the magnetization precession
on an ultrafast time scale. This takes place within the 100 fs duration of a
single laser pulse, through combined contribution from two nonthermal
photomagnetic effects, i.e., enhancement of the magnetization and an inverse
Faraday effect. From the magnetic field dependences of the frequency and the
Gilbert damping parameter, the intrinsic Gilbert damping coefficient is
evaluated to be {\alpha} \approx 3\times10^-3.Comment: 5 pages, 3 figures, accepted for publication in Phys. Rev.
The structure of the Au(111)/methylthiolate interface : new insights from near-edge X-ray absorption spectroscopy and X-ray standing waves
The local structure of the Au(111)([square root of]3×[square root of]3)R30°-methylthiolate surface phase has been investigated by S K-edge near-edge s-ray absorption fine structure (NEXAFS) both experimentally and theoretically and by experimental normal-incidence x-ray standing waves (NIXSW) at both the C and S atomic sites. NEXAFS shows not only excitation into the intramolecular sigma* S–C resonance but also into a sigma* S–Au orbital perpendicular to the surface, clearly identifying the local S headgroup site as atop a Au atom. Simulations show that it is not possible, however, to distinguish between the two possible adatom reconstruction models; a single thiolate species atop a hollow-site Au adatom or a dithiolate moiety comprising two thiolate species bonded to a bridge-bonded Au adatom. Within this dithiolate moiety a second sigma* S–Au orbital that lies near parallel to the surface has a higher energy that overlaps that of the sigma* S–C resonance. The new NIXSW data show the S–C bond to be tilted by 61° relative to the surface normal, with a preferred azimuthal orientation in , corresponding to the intermolecular nearest-neighbor directions. This azimuthal orientation is consistent with the thiolate being atop a hollow-site Au adatom, but not consistent with the originally proposed Au-adatom-dithiolate moiety. However, internal conformational changes within this species could, perhaps, render this model also consistent with the experimental data
Fine-tuning the functional properties of carbon nanotubes via the interconversion of encapsulated molecules
Tweaking the properties of carbon nanotubes is a prerequisite for their
practical applications. Here we demonstrate fine-tuning the electronic
properties of single-wall carbon nanotubes via filling with ferrocene
molecules. The evolution of the bonding and charge transfer within the tube is
demonstrated via chemical reaction of the ferrocene filler ending up as
secondary inner tube. The charge transfer nature is interpreted well within
density functional theory. This work gives the first direct observation of a
fine-tuned continuous amphoteric doping of single-wall carbon nanotubes
Magnetic versus crystal field linear dichroism in NiO thin films
We have detected strong dichroism in the Ni x-ray absorption
spectra of monolayer NiO films. The dichroic signal appears to be very similar
to the magnetic linear dichroism observed for thicker antiferromagnetic NiO
films. A detailed experimental and theoretical analysis reveals, however, that
the dichroism is caused by crystal field effects in the monolayer films, which
is a non trivial effect because the high spin Ni ground state is not
split by low symmetry crystal fields. We present a practical experimental
method for identifying the independent magnetic and crystal field contributions
to the linear dichroic signal in spectra of NiO films with arbitrary
thicknesses and lattice strains. Our findings are also directly relevant for
high spin and systems such as LaFeO, FeO,
VO, LaCrO, CrO, and Mn manganate thin films
Are the renormalized band widths in TTF-TCNQ of structural or electronic origin? - An angular dependent NEXAFS study
We have performed angle-dependent near-edge x-ray absorption fine structure
measurements in the Auger electron yield mode on the correlated
quasi-one-dimensional organic conductor TTF-TCNQ in order to determine the
orientation of the molecules in the topmost surface layer. We find that the
tilt angles of the molecules with respect to the one-dimensional axis are
essentially the same as in the bulk. Thus we can rule out surface relaxation as
the origin of the renormalized band widths which were inferred from the
analysis of photoemission data within the one-dimensional Hubbard model.
Thereby recent theoretical results are corroborated which invoke long-range
Coulomb repulsion as alternative explanation to understand the spectral
dispersions of TTF-TCNQ quantitatively within an extended Hubbard model.Comment: 6 pages, 5 figure
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