Synthesis of cubic diamond in the graphite-magnesium carbonate and graphite-K2Mg(CO3)(2) systems at high pressure of 9-10 GPa region

Cubic diamond was synthesized with two systems, (1) graphite with pure magnesium carbonate (magnesite) and (2) graphite with mixed potassium and magnesium carbonate at pressures and temperatures above 9.5 GPa, 1600 degrees C and 9 GPa, 1650 degrees C, respectively. At these conditions (1) the pure magnesite is solid, whereas (2) the mixed carbonate exists as a melt. In this pressure range, graphite seems to be partially transformed into hexagonal diamond. Measured carbon isotope delta(13)C values for all the materials suggest that the origin of the carbon source to form cubic diamond was the initial graphite powder, and not the carbonates

Contactless electromagnetic measuring system using conventional calibration algorithms to determine scattering parameters

In this paper, a contactless measuring system for the determination of the S-parameters of planar circuits is presented. With a contactless measuring system it is possible to characterise a device-under-test (DUT) embedded in a planar circuit environment without cutting the planar transmission lines connecting the DUT. The technique utilizes four identical capacitive probes in conjunction with a vector network analyser (VNA). For the usage of electromagnetic probes compared to other coupling techniques like the electro-optic probing, there is no need for expensive and complex equipment in addition to the typical equipment of a common microwave laboratory. The S-parameters are determined accurately using conventional calibration methods. A simple analytical model for the representation of the basic characteristics is developed. Furthermore, the influences on the S-parameters as a result of a variation in the coupling are presented. With the knowledge of the system characteristics, an accurate contactless measurement system is set up. The comparison between conventional and contactless measurements in a frequency range of 1-20 GHz shows a very good agreement with a phase error smaller than 1°

Random local strain effects in homovalent-substituted relaxor ferroelectrics: a first-principles study of BaTi0.74Zr0.26O3

We present first-principles supercell calculations on BaTi0.74Zr0.26O3, a prototype material for relaxors with a homovalent substitution. From a statistical analysis of relaxed structures, we give evidence for four types of Ti-atom polar displacements: along the , , or directions of the cubic unit cell, or almost cancelled. The type of a Ti displacement is entirely determined by the Ti/Zr distribution in the adjacent unit cells. The underlying mechanism involves local strain effects that ensue from the difference in size between the Ti4+ and Zr4+ cations. These results shed light on the structural mechanisms that lead to disordered Ti displacements in BaTi(1-x)Zr(x)O3 relaxors, and probably in other BaTiO3-based relaxors with homovalent substitution.Comment: 5 pages, 4 figure

Enhancement of piezoelectricity in a mixed ferroelectric

We use first-principles density-functional total energy and polarization calculations to calculate the piezoelectric tensor at zero temperature for both cubic and simple tetragonal ordered supercells of Pb_3GeTe_4. The largest piezoelectric coefficient for the tetragonal configuration is enhanced by a factor of about three with respect to that of the cubic configuration. This can be attributed to both the larger strain-induced motion of cations relative to anions and higher Born effective charges in the tetragonal case. A normal mode decomposition shows that both cation ordering and local relaxation weaken the ferroelectric instability, enhancing piezoelectricity.Comment: 5 pages, revtex, 2 eps figure

Fcc breathing instability in BaBiO_3 from first principles

We present first-principles density-functional calculations using the local density approximation to investigate the structural instability of cubic perovskite BaBiO_3. This material might exhibit charge disproportionation and some evidence thereof has been linked to the appearance of an additional, fourth peak in the experimental IR spectrum. However, our results suggest that the origin of this additional peak can be understood within the picture of a simple structural instability. While the true instability consists of an oxygen-octahedra breathing distortion and a small octahedra rotation, we find that the breathing alone in a fcc-type cell doubling is sufficient to explain the fourth peak in the IR spectrum. Our results show that the oscillator strength of this particular mode is of the same order of magnitude as the other three modes, in agreement with experiment.Comment: submitted to PRB, completely revised version after referee repor

The ferroelectric transition in YMnO3_3 from first principles

We have studied the structural phase transition of multiferroic YMnO$_3$ from first principles. Using group-theoretical analysis and first-principles density functional calculations of the total energy and phonons, we perform a systematic study of the energy surface around the prototypic phase. We find a single instability at the zone-boundary which couples strongly to the polarization. This coupling is the mechanism that allows multiferroicity in this class of materials. Our results imply that YMnO$_3$ is an improper ferroelectric. We suggest further experiments to clarify this point.Comment: published version, PRB (rapid comm), slight change in presentatio

Alternatives to NIMBY gridlock: voluntary approaches to radioactive waste facility siting in Canada and the United States

Neither Canada nor the United States has sited a new radioactive waste management facility in more than two decades, despite the continuous generation of new waste and the paucity of reliable disposal capacity. Both nations have stirred up considerable political controversy in attempting to site such facilities, with aggressive local collective action consistently blocking proposals. Building on provincial experience in gaining public support for hazardous waste facility siting tlirough a voluntary, comprehensive process, both Ontario and Nebraska Show signs of devi˜ting from the classic Not-in-My-Back-Yard (NIMBY) response for low-level radioactive waste. Through a variation of the process used successfully in Alberta and Manitoba for hazardous waste, Ontario and Nebraska have demonstrated the potential applicability of these alternative siting principles for radioactive waste. Sommaire : Ni le Canada, ni les États-Unis n'ont construit de nouvelles installations de gestion des dÉchets radioactifs depuis plus de deux dÉcennies, malgrÉ la production continuelie de dÉchets supplÉmentaires et malgrÉ la faible capacitÉ d'Élimination fiable. Les deux nations ont dÉclenchÉ des controverses politiques considÉrables en essayant de mettre en place de telles installations, et leurs propositions ont ÉtÉ bloquÉes systÉmatiquement et agressivement par les collectivitÉs locales. Forts de certaines expÉriences provinciales pour gagner le soutien du public ewers l'emplacement d'une installation de dÉchets dangereux grÂce À un processus volontaire et extensif, l'Ontario et le Nebraska semblent dÉvier de la rÉaction classique “ pas dans ma cour ” en ce qui concerne les dÉchets faiblement radioactifs. Par l'entremise d'une variante du processus utilisÉ avec succÈs pour les dÉchets dnngereux en Alberta et au Manitoba, l'Ontario et le Nebraska ont dÉmontrÉ qu'on pourrait Éventuellement appliqucr ces principes de rechanpe pour l'emplacement des installations traitant les dÉchets radioactifs.Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/73397/1/j.1754-7121.1994.tb00885.x.pd

Cardiovascular correlates of motor vehicle accident related posttraumatic stress disorder and its successful treatment

Springer Open Choice ArticlePersons with posttraumatic stress disorder (PTSD) have been shown to display elevated baseline cardiovascular activity and a heightened physiological reactivity to trauma-related stimuli. Study 1 examined differences in baseline heart rate (HR) and HR reactivity in 68 survivors of motor vehicle accidents (MVAs) and healthy controls without MVA. MVA survivors with PTSD (n=26), subsyndromal PTSD (n=22), traumatized controls without PTSD (non-PTSD with MVA, n=20) and healthy controls without MVA (HC, n=27) underwent measurement of HR during baseline and exposure to a neutral, positive, negative, and trauma-related picture. PTSD patients showed elevated baseline HR and increased HR reactivity only during exposure to the trauma-related picture. Study 2 investigated whether the elevated physiological responses observed in Study 1 normalized after cognitive behavioral therapy (CBT). We conducted a randomized, controlled treatment trial comparing CBT (n=17) to a Wait-list condition (WLC, n=18). Results showed a greater decrease in HR reactivity for CBT than for WLC. The change in HR reactivity was associated with clinical improvement.This study was supported by the Deutsche Forschungsgemeinschaft (KA 1476/3