5,383 research outputs found
Manipulating the torsion of molecules by strong laser pulses
A proof-of-principle experiment is reported, where torsional motion of a
molecule, consisting of a pair of phenyl rings, is induced by strong laser
pulses. A nanosecond laser pulse spatially aligns the carbon-carbon bond axis,
connecting the two phenyl rings, allowing a perpendicularly polarized, intense
femtosecond pulse to initiate torsional motion accompanied by an overall
rotation about the fixed axis. The induced motion is monitored by femtosecond
time-resolved Coulomb explosion imaging. Our theoretical analysis accounts for
and generalizes the experimental findings.Comment: 4 pages, 4 figures, submitted to PRL; Major revision of the
presentation of the material; Correction of ion labels in Fig. 2(a
Solving the m-mixing problem for the three-dimensional time-dependent Schr\"{o}dinger equation by rotations: application to strong-field ionization of H2+
We present a very efficient technique for solving the three-dimensional
time-dependent Schrodinger equation. Our method is applicable to a wide range
of problems where a fullly three-dimensional solution is required, i.e., to
cases where no symmetries exist that reduce the dimensionally of the problem.
Examples include arbitrarily oriented molecules in external fields and atoms
interacting with elliptically polarized light. We demonstrate that even in such
cases, the three-dimensional problem can be decomposed exactly into two
two-dimensional problems at the cost of introducing a trivial rotation
transformation. We supplement the theoretical framework with numerical results
on strong-field ionization of arbitrarily oriented H2+ molecules.Comment: 5 pages, 4 figure
Exposure to Dust and Endotoxin of Employees in Cucumber and Tomato Nurseries
Exposure to bioaerosols in occupational settings is associated with a range of adverse health effects. The aim of this study was to investigate the exposure levels to dust and endotoxin of people working in two cucumber nurseries and two tomato nurseries. Exposure was measured for greenhouse workers (n = 70) mainly working on harvesting cucumbers and tomatoes and clearing the plants after the harvest season. The people were exposed to between 0.2 and 15 mg inhalable dust m−3 (median = 1.6 mg m−3) and between 0.5 and 400 ng inhalable endotoxin m−3 (median = 32 ng m−3). The exposure to ‘total dust’ and endotoxin measured by stationary samplers (n = 30) in the greenhouses was low. Endotoxin was present in relatively high concentrations on cucumber leaves compared with leaves on pot plants. The Danish occupational exposure limit (OEL) for total organic dust is 3 mg m−3 and 36% and 17% of the cucumber and tomato workers, respectively, were exposed to >3.0 mg inhalable dust m−3. There is no OEL for endotoxin, but ‘no effect levels’ at ∼15 ng m−3 have been found. The majority of subjects (65%) were exposed to >15 ng m−3. Significantly higher exposure was found for employees in cucumber nurseries than for employees in tomato nurseries. Clearing tomato plants after the harvest season caused a higher exposure to endotoxin than tomato harvesting. In conclusion, people working in cucumber and tomato nurseries were often exposed to high levels of inhalable dust and endotoxin. Cucumber harvest workers were exposed to significantly more dust and endotoxin than tomato harvest workers. The dust and endotoxin aerosolized during the working processes were only transported to other areas in the greenhouses to a very low degree. Cucumber and tomato leaves were identified as endotoxin reservoirs
Orientation-dependent ionization yields from strong-field ionization of fixed-in-space linear and asymmetric top molecules
The yield of strong-field ionization, by a linearly polarized probe pulse, is
studied experimentally and theoretically, as a function of the relative
orientation between the laser field and the molecule. Experimentally, carbonyl
sulfide, benzonitrile and naphthalene molecules are aligned in one or three
dimensions before being singly ionized by a 30 fs laser pulse centered at 800
nm. Theoretically, we address the behaviour of these three molecules. We
consider the degree of alignment and orientation and model the angular
dependence of the total ionization yield by molecular tunneling theory
accounting for the Stark shift of the energy level of the ionizing orbital. For
naphthalene and benzonitrile the orientational dependence of the ionization
yield agrees well with the calculated results, in particular the observation
that ionization is maximized when the probe laser is polarized along the most
polarizable axis. For OCS the observation of maximum ionization yield when the
probe is perpendicular to the internuclear axis contrasts the theoretical
results.Comment: 14 pages, 4 figure
Influence of molecular symmetry on strong-field ionization: Studies on ethylene, benzene, fluorobenzene, and chlorofluorobenzene
Using the molecular strong-field approximation we consider the effects of
molecular symmetry on the ionization of molecules by a strong, linearly
polarized laser pulse. Electron angular distributions and total ionization
yields are calculated as a function of the relative orientation between the
molecule and the laser polarization. Our studies focus on ethylene
(CH), benzene (CH), fluorobenzene (CHF), and ortho
chlorofluorobenzene (1,2 CHClF), the molecules representing four
different point groups. The results are compared with experiments, when
available, and with the molecular tunneling theory appropriately extended to
non-linear polyatomic molecules. Our investigations show that the orientational
dependence of ionization yields is primarily determined by the nodal surface
structure of the molecular orbitals.Comment: 13 pages, 10 figures. Submitted to Physical Review
Differential atom interferometry beyond the standard quantum limit
We analyze methods to go beyond the standard quantum limit for a class of
atomic interferometers, where the quantity of interest is the difference of
phase shifts obtained by two independent atomic ensembles. An example is given
by an atomic Sagnac interferometer, where for two ensembles propagating in
opposite directions in the interferometer this phase difference encodes the
angular velocity of the experimental setup. We discuss methods of squeezing
separately or jointly observables of the two atomic ensembles, and compare in
detail advantages and drawbacks of such schemes. In particular we show that the
method of joint squeezing may improve the variance by up to a factor of 2. We
take into account fluctuations of the number of atoms in both the preparation
and the measurement stage, and obtain bounds on the difference of the numbers
of atoms in the two ensembles, as well as on the detection efficiency, which
have to be fulfilled in order to surpass the standard quantum limit. Under
realistic conditions, the performance of both schemes can be improved
significantly by reading out the phase difference via a quantum non-demolition
(QND) measurement. Finally, we discuss a scheme using macroscopically entangled
ensembles.Comment: 10 pages, 5 figures; eq. (3) corrected and other minor change
Effects of Air Contact on Growth, Inorganic Carbon Sources, and Nitrogen Uptake by an Amphibious Freshwater Macrophyte
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