CeMnNi4: an impostor half-metal

Recent experiments show CeMnNi$_{4}$ to have a nearly integer magnetic moment and a relatively large transport spin polarization, as probed by Andreev reflection, suggesting that the material is a half metal or close to it. However, the calculations reported here show that it is not a half metal at all, but rather a semimetal of an unusual nature. Phonon properties should also be quite unusual, with rattling low-frequency Mn modes. Nontrivial transport properties, including a large thermolectric figure of merit, $ZT,$ are predicted in the ferromagnetic state of the well ordered stoichiometric CeMnNi$_{4}$Comment: 4 pages, 6 fig

Tools for the identification of variable and potentially variable tandem repeats

BACKGROUND: Tandem repeat arrays showing variation between sequences within a population, between strains or across species may have functional effects. The increasing availability of genomic sequence data makes routine description of observed variation possible, creating a need for tools to describe such variability. RESULTS: We present a set of programs that facilitate the identification of tandem repeats showing variation across multiple sequences or genomes, and the prediction of potentially polymorphic tandem repeats. The VNTRfinder (Variable Number of Tandem Repeats finder) program enables the detection of sequence length variation between arrays of inter-specific or intra-specific tandem repeats. In the absence of comparable sequences to explore observed variation, predictions are provided describing which tandem repeats are more likely to be variable, to help guide and focus further experimental evaluation. CONCLUSION: These tools represent a resource for researchers interested in tandem repeats in nucleotide sequences that are most likely to be of clinical and evolutionary interest. The tools are available at . Downloadable versions for UNIX/LINUX and WINDOWS which permit the consideration of longer and more numerous sequences are also available

The Black Hole Mass - Galaxy Bulge Relationship for QSOs in the SDSS DR3

We investigate the relationship between black hole mass and host galaxy velocity dispersion for QSOs in Data Release 3 of the Sloan Digital Sky Survey. We derive black hole mass from the broad Hbeta line width and continuum luminosity, and the bulge stellar velocity dispersion from the [OIII] narrow line width. At higher redshifts, we use MgII and [OII] in place of Hbeta and [OIII]. For redshifts z < 0.5, our results agree with the black hole mass - bulge velocity dispersion relationship for nearby galaxies. For 0.5 < z < 1.2, this relationship appears to show evolution with redshift in the sense that the bulges are too small for their black holes. However, we find that part of this apparent trend can be attributed to observational biases, including a Malmquist bias involving the QSO luminosity. Accounting for these biases, we find ~0.2 dex evolution in the black hole mass-bulge velocity dispersion relationship between now and redshift z ~ 1.Comment: Accepted by ApJ, 15 pages, 9 figure

The Nature of the UV/X-Ray Absorber in PG 2302+029

We present Chandra X-ray observations of the radio-quiet QSO PG 2302+029. This quasar has a rare system of ultra-high velocity (-56,000 km/s) UV absorption lines that form in an outflow from the active nucleus (Jannuzi et al. 2003). The Chandra data indicate that soft X-ray absorption is also present. We perform a joint UV and X-ray analysis, using photoionization calculations, to detemine the nature of the absorbing gas. The UV and X-ray datasets were not obtained simultaneously. Nonetheless, our analysis suggests that the X-ray absorption occurs at high velocities in the same general region as the UV absorber. There are not enough constraints to rule out multi-zone models. In fact, the distinct broad and narrow UV line profiles clearly indicate that multiple zones are present. Our preferred estimates of the ionization and total column density in the X-ray absorber (log U=1.6, N_H=10^22.4 cm^-2) over predict the O VI 1032, 1038 absorption unless the X-ray absorber is also outflowing at ~56,000 km/s, but they over predict the Ne VIII 770, 780 absorption at all velocities. If we assume that the X-ray absorbing gas is outflowing at the same velocity of the UV-absorbing wind and that the wind is radiatively accelerated, then the outflow must be launched at a radius of < 10^15 cm from the central continuum source. The smallness of this radius casts doubts on the assumption of radiative acceleration.Comment: Accepted for Publication in Ap

The Extraordinary Abundances of QSO Broad Absorption Line Regions: A Matter of Novae?

The broad absorption lines (BALs) of QSOs indicate abundances of heavy elements, relative to hydrogen, that are 1 to 2 orders of magnitude higher than the solar values. In at least one QSO, an especially large enhancement of phosphorus is observed. These abundances resemble those in Galactic novae, and this suggests that novae may produce the BAL gas. The needed rate of nova outbursts may come from single white dwarfs that accrete gas as they pass through a supermassive accretion disk around a central black hole.Comment: 9 pages including 1 Postscript figure. Uses aaspp4.sty and flushrt.sty. Uuencoded, gzipped tarfile. To appear in Astrophys. J. (Letters), 1996 April 1

Ultraviolet and optical properties of Narrow-Line Seyfert 1 galaxies

Narrow Line Seyfert 1 (NLS1) galaxies are remarkable for their extreme continuum and emission line properties which are not well understood. New results bearing on the spectroscopic characteristics of these objects are presented here, with the aim of establishing their typical ultraviolet and optical spectral behavior. We employ HST observations of 22 NLS1s, which represent a substantial improvement over previous work in terms of data quality and sample size. High signal-to-noise NLS1 composite spectra are constructed, allowing accurate measurements of the continuum shape and the strengths, ratios, and widths for lines, including weak features which are barely identifiable in other Active Galactic Nuclei (AGN) composites. We find that the NLS1 sources have redder UV-blue continua than those typically measured in other quasars and Seyferts. Objects with UV line absorption show redder spectra, suggesting that dust is important in modifying the continuum shapes. The data also permit a detailed investigation of the previously proposed link between NLS1s and z >~ 4 quasars. Direct comparison of their composite spectra, as well as a Principal Component Analysis, suggest that high-z QSOs do not show a strong preference toward NLS1 behavior.Comment: 23 pages (incl. 9 figures, 4 tables), to appear in The Publications of the Astronomical Society of the Pacifi

An exploration of occupation in nursing home residents with dementia

Objectives: This study evaluated the sitting room environment of two nursing homes in Ireland, using interactive occupation and social engagement as outcome measures and defining these rooms as occupational spaces. Method: Snapshot observational recordings were made in the main sitting rooms during the periods of time when the rooms were in most active use. Narrative information was also recorded. Results: Residents were more likely to occupy their time in the main sitting room passively, rather than in interactive occupation and social engagement. The nursing home residents with dementia spent approximately 70% of their daily time in the main sitting room areas in states of occupational disengagement. Discussion: Additional insight is provided through pragmatic narrative descriptions of the functioning of the main sitting room environment in terms of interactive occupation and social engagement. Relevance: The research study demonstrates a methodology for evaluating the sitting room areas of a care environment, using interactive occupation and social engagement as outcome measures,which can be used for descriptive and comparative insights into the performance of care environments

Broad Band X-Ray Observations of the Narrow Line X-Ray Galaxy NGC 5506

We present a detailed analysis of broad band X-ray data of the Seyfert 2 galaxy NGC5506. 2-10 keV band are detected during a 1-day ASCA observation, while no significant change in the 2-10 keV continuum shape is found. The ASCA spectrum consists of an absorbed power-law, a 'soft excess' below 2 keV, and an Fe K$\alpha$ emission line at 6.4 keV. The 'soft excess' can be well described by either thermal emission from very low abundance material at a temperature kT$\simeq$0.8 keV, or scattered/leaking flux from the primary power-law plus a small amount of thermal emission. Analysis of ROSAT HRI data reveals that the soft X-ray emission is extended on kpc scales in this object, and the extended component may account for most of the soft X-ray excess observed by the ASCA. The result suggests that in this type 2 AGN, the 'soft excess' at least partly comes from an extended region, imposing serious problem for the model in which the source is partially covered. Fe K$\alpha$ profile is complex and can not be satisfactorily modeled by a single gaussian. Models of either double gaussians, or a narrow gaussian plus a line from a relativistic accretion disk viewed at an inclination of about 40$\pm10^\circ$ provide good fits to the data. However, the inclination of the disk can be substantially larger if there is a small amount of excessive Fe K edge absorption. The intermediate inclinations for NLXGs are consistent with the ideas that the inner accretion disk is aligned with the outer obscuring torus.Comment: 8 pages, 5 postscript figures. to appear in Astrophy. J., 1999, April 2

Water-Mediated Peptide Bond Formation in the Gas Phase: A Model Prebiotic Reaction

The emergence of life on the prebiotic Earth must have involved the formation of polypeptides, yet the polymerization of amino acids is thermodynamically unfavorable under biologically relevant aqueous conditions because amino acids are zwitterions in solution and because of the production of a water molecule through a condensation reaction. Many mechanisms for overcoming this thermodynamic unfavorability have been proposed, but the role of gas phase water clusters has not been investigated. We present the thermodynamics of the water-mediated gas phase dimerization reaction of glycine as a model for the atmospheric polymerization of amino acids prior to the emergence of biological machinery. We hypothesize that atmospheric aerosols may have played a major role in the prebiotic formation of peptide bonds by providing the thermodynamic driving force to facilitate increasingly stable linear oligopeptides. In addition, we hypothesize that small aerosols orient amino acids on their surfaces, thus providing the correct molecular orientations to funnel the reaction pathways of peptides through transition states that lead eventually to polypeptide products. Using density functional theory and a thorough configurational sampling technique, we show that the thermodynamic spontaneity of the linear dimerization of glycine in the gas phase can be driven by the addition of individual water molecules