Preparation and Characterization of Stimuli-Responsive Magnetic Nanoparticles

In this work, the main attention was focused on the synthesis of stimuli-responsive magnetic nanoparticles (SR-MNPs) and the influence of glutathione concentration on its cleavage efficiency. Magnetic nanoparticles (MNPs) were first modified with activated pyridyldithio. Then, MNPs modified with activated pyridyldithio (MNPs-PDT) were conjugated with 2, 4-diamino-6-mercaptopyrimidine (DMP) to form SR-MNPs via stimuli-responsive disulfide linkage. Fourier transform infrared spectra (FTIR), transmission electron microscopy (TEM), and X-ray photoelectron spectroscopy (XPS) were used to characterize MNPs-PDT. The disulfide linkage can be cleaved by reduced glutathione (GHS). The concentration of glutathione plays an important role in controlling the cleaved efficiency. The optimum concentration of GHS to release DMP is in the millimolar range. These results had provided an important insight into the design of new MNPs for biomedicine applications, such as drug delivery and bio-separation

GmFT2a, a Soybean Homolog of FLOWERING LOCUS T, Is Involved in Flowering Transition and Maintenance

BACKGROUND: Flowering reversion can be induced in soybean (Glycine max L. Merr.), a typical short-day (SD) dicot, by switching from SD to long-day (LD) photoperiods. This process may involve florigen, putatively encoded by FLOWERING LOCUS T (FT) in Arabidopsis thaliana. However, little is known about the potential function of soybean FT homologs in flowering reversion. METHODS: A photoperiod-responsive FT homologue GmFT (renamed as GmFT2a hereafter) was cloned from the photoperiod-sensitive cultivar Zigongdongdou. GmFT2a gene expression under different photoperiods was analyzed by real-time quantitative PCR. In situ hybridization showed direct evidence for its expression during flowering-related processes. GmFT2a was shown to promote flowering using transgenic studies in Arabidopsis and soybean. The effects of photoperiod and temperature on GmFT2a expression were also analyzed in two cultivars with different photoperiod-sensitivities. RESULTS: GmFT2a expression is regulated by photoperiod. Analyses of GmFT2a transcripts revealed a strong correlation between GmFT2a expression and flowering maintenance. GmFT2a transcripts were observed continuously within the vascular tissue up to the shoot apex during flowering. By contrast, transcripts decreased to undetectable levels during flowering reversion. In grafting experiments, the early-flowering, photoperiod-insensitive stock Heihe27 promotes the appearance of GmFT2a transcripts in the shoot apex of scion Zigongdongdou under noninductive LD conditions. The photothermal effects of GmFT2a expression diversity in cultivars with different photoperiod-sensitivities and a hypothesis is proposed. CONCLUSION: GmFT2a expression is associated with flowering induction and maintenance. Therefore, GmFT2a is a potential target gene for soybean breeding, with the aim of increasing geographic adaptation of this crop

Ionospheric Pc1 waves during a storm recovery phase observed by the China Seismo-Electromagnetic Satellite

Abstract During the storm recovery phase on 27 August 2018, the China Seismo-Electromagnetic Satellite (CSES) detected Pc1 wave activities in both the Northern Hemisphere and Southern Hemisphere in the high-latitude, post-midnight ionosphere with a central frequency of about 2 Hz. Meanwhile, the typical Pc1 waves were simultaneously observed for several hours by the Sodankylä Geophysical Observatory (SGO) stations on the ground. In this paper, we study the propagation characteristics and possible source regions of those waves. Firstly, we find that the Pc1 waves observed by the satellites exhibited mixed polarisation, and the wave normal is almost parallel with the background magnetic field. The field-aligned Poynting fluxes point downwards in both hemispheres, implying that the satellites are close to the wave injection regions in the ionosphere at about L=3. Furthermore, we also find that the estimated position of the plasmapause calculated by models is almost at L=3. Therefore, we suggest that the possible sources of waves are near the plasmapause, which is consistent with previous studies in that the outward expansion of the plasmasphere into the ring current during the recovery phase of geomagnetic storms may generate electromagnetic ion cyclotron (EMIC) waves, and these EMIC waves propagate northwards and southwards along the background magnetic field to the ionosphere at about L=3. Additionally, the ground station data show that Pc1 wave power attenuates with increasing distance from L=3, supporting the idea that the CSES observes the wave activities near the injection region. The observations are unique in that the Pc1 waves are observed in the ionosphere in nearly conjugate regions where transverse Alfvén waves propagate down into the ionosphere

Optical and surface properties of 3C–SiC thin epitaxial films grown at different temperatures on 4H–SiC substrates

A series of 3C–SiC films were grown on 4H–SiC substrates with different growth conditions using high-temperature chemical vapor deposition (HT-CVD). The influences of growth temperature (Tg) on the morphology, optical and material properties of films were assessed by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and Raman scattering spectroscopy (RSS). Significant effects of Tg on the film crystalline quality were observed from analyzing XRD and RSS results. XPS characterized the surface states of Si, C, O elements, and variations with Tg. The 3C–SiC Raman TO mode was found to shift to lower frequency with the increase of Tg in 1530–1580 °C. Temperature dependent Raman studies indicated the anharmonic coupling and variation of phonon lifetimes. The optimized Tg is obtained