158 research outputs found
Formation of Diaplectic Glass in Anorthite by Shock-Loading Experiments(Physics)
Shock-recovery experiments on primitive anorthite have been carried out in which single crystals of anorthite are shocked to peak pressures of 150, 300, and 380 kbar, and the recovered specimen is examined by means of electron microscopy. Diaplectic glass is observed in specimens shocked above 300 kbar, and the specimen shocked to 380 kbar is found to be completely converted to diaplectic glass. In fragments shocked to 300 kbar, the intergrowth textures of diaplectic glass and anorthite crystal are observed under an electron microscope. The diffuseness of b reflections in the electron diffraction pattern of intergrown crystals has no noticeable change in comparison with that of the starting specimen. The results indicate that the original configuration of antiphase domains is retained in the shocked crystal until an abrupt transition of primitive anorthite to diaplectic glass occurs. Diaplectic glass is supposed to be produced secondarily from an unquenchable high-pressure form induced under shock loading
Realistic many-body models for Manganese Monoxide under pressure
In materials like transition metals oxides where electronic Coulomb
correlations impede a description in terms of standard band-theories, the
application of genuine many-body techniques is inevitable. Interfacing the
realism of density-functional based methods with the virtues of Hubbard-like
Hamiltonians, requires the joint ab initio construction of transfer integrals
and interaction matrix elements (like the Hubbard U) in a localized basis set.
In this work, we employ the scheme of maximally localized Wannier functions and
the constrained random phase approximation to create effective low-energy
models for Manganese monoxide, and track their evolution under external
pressure. We find that in the low pressure antiferromagnetic phase, the
compression results in an increase of the bare Coulomb interaction for specific
orbitals. As we rationalized in recent model considerations [Phys. Rev. B 79,
235133 (2009)], this seemingly counter-intuitive behavior is a consequence of
the delocalization of the respective Wannier functions. The change of screening
processes does not alter this tendency, and thus, the screened on-site
component of the interaction - the Hubbard U of the effective low-energy system
- increases with pressure as well. The orbital anisotropy of the effects
originates from the orientation of the orbitals vis-a-vis the deformation of
the unit-cell. Within the high pressure paramagnetic phase, on the other hand,
we find the significant increase of the Hubbard U is insensitive to the orbital
orientation and almost exclusively owing to a substantial weakening of
screening channels upon compression.Comment: 13 pages, 6 figure
Mott Transition of MnO under Pressure: Comparison of Correlated Band Theories
The electronic structure, magnetic moment, and volume collapse of MnO under
pressure are obtained from four different correlated band theory methods; local
density approximation + Hubbard U (LDA+U), pseudopotential self-interaction
correction (pseudo-SIC), the hybrid functional (combined local exchange plus
Hartree-Fock exchange), and the local spin density SIC (SIC-LSD) method. Each
method treats correlation among the five Mn 3d orbitals (per spin), including
their hybridization with three O orbitals in the valence bands and their
changes with pressure. The focus is on comparison of the methods for rocksalt
MnO (neglecting the observed transition to the NiAs structure in the 90-100 GPa
range). Each method predicts a first-order volume collapse, but with variation
in the predicted volume and critical pressure. Accompanying the volume collapse
is a moment collapse, which for all methods is from high-spin to low-spin (5/2
to 1/2), not to nonmagnetic as the simplest scenario would have. The specific
manner in which the transition occurs varies considerably among the methods:
pseudo-SIC and SIC-LSD give insulator-to-metal, while LDA+U gives
insulator-to-insulator and the hybrid method gives an insulator-to-semimetal
transition. Projected densities of states above and below the transition are
presented for each of the methods and used to analyze the character of each
transition. In some cases the rhombohedral symmetry of the
antiferromagnetically ordered phase clearly influences the character of the
transition.Comment: 14 pages, 9 figures. A 7 institute collaboration, Updated versio
NMR Study on La and Tl-based High-T_c Cuprates (High Field Superconductors)
NMR study on three types of high-T_C cuprates TlBa_2CaCu_2O_ (Tl1212), La_Ba_xCuO_4 (LBCO) and (La_Y_y)_Ce_xCuO_4 (LYCCO) is reported. First the Knight shift in the superconducting state was investigated for the Zn-substituted TlBa_2Ca(Cu_Zn_z)_2O_, which belongs to the over-doped region. The temperature dependence of the Knight shift was successfully explained in terms of the partially closed d-wave model proposed by Kitaoka et al. The reduction in T_C by Zn-substitution was also consistent with Miyake\u27s theoretical calculation on the potential scattering of the unitarity limit in the d-wave superconductors. Next, the impurity effect on the anomalous suppression of the superconductivity in La_Ba_xCuO_4 (LBCO) around x≅1/8 was investigated by La-NMR and ultrasonic measurements. The transition temperatures of the magnetic order and of the structural phase transformation in Zn^ and Ce^-doped LBCO have shown that the main and direct force to the suppression in the superconductivity is the magnetic ordering, and that the role of the structural phase transformation is the enhancement of the suppression. Lastly, the new electron doped cuprate free from 4f-spins has been synthesized and studied by NMR. Observed spectra of ^Cu without quadrupolar splitting similar to other conventional electron-doped cuprates indicate that the doped carrier in this system is electron like
Recommended from our members
Transition to a Virtually Incompressible Oxide Phase at a Shock Pressure of 120 GPa (1.2 Mbar): Gd3Ga5O12
Cubic, single-crystal, transparent Gd{sub 3}Ga{sub 5}O{sub 12} has a density of 7.10 g/cm{sup 3}, a Hugoniot elastic limit (HEL) of 30 GPa, and undergoes a continuous phase transition from 65 GPa to a quasi-incompressible (QI) phase at 120 GPa. Only diamond has a larger HEL. The QI phase of Gd{sub 3}Ga{sub 5}O{sub 12} is more incompressible than diamond from 170 to 260 GPa. Electrical conductivity measurements indicate the QI phase has a bandgap of 3.1 eV. Gd{sub 3}Ga{sub 5}O{sub 12} can be used to obtain substantially higher pressures and lower temperatures in metallic fluid hydrogen than was achieved previously by shock reverberation between Al{sub 2}O{sub 3} disks. Dynamic compression achieves pressures, densities, and temperatures that enable investigation of ultracondensed matter at conditions yet to be achieved by any other technique. The prototypical example is observation of minimum metallic conductivity (MMC) of dense fluid hydrogen at 140 GPa, nine-fold compression of liquid density, and {approx}3000 K [1-3]. The high pressure and density and relatively low temperature are achieved by multiple-shock compression [2]. Temperature T is relatively low in the sense that T/TP{sub F} {approx} 0.01, where T{sub F} is the Fermi temperature. The time scale of compression is sufficiently long to achieve thermal equilibrium and sufficiently short so the process is adiabatic. Similar results are obtained for oxygen [4] and nitrogen [5]. Fluid Cs and Rb undergo the same transition at 2000 K near their liquid-vapor critical points [6]. All five elemental fluids have essentially the same value of MMC and the density dependences of their semiconductivities scale with the quantum-mechanical charge-density distributions of the respective atoms [5]. Liquid H{sub 2} is one of the most compressible of all materials. In this paper, we report that the dielectric crystal Gd{sub 3}Ga{sub 5}O{sub 12} (GGG) transitions to a virtually incompressible phase at 120 GPa shock pressure
Thermal conductivity of high- T c superconductors
This paper reviews existing data on the thermal conductivity of high- T c superconductors. Included are discussions of pristine polycrystalline high- T c ceramics, single crystal specimens, and high- T c materials structurally modified by substitution or by radiation damage. The thermal conductivity of high- T c superconductors is compared with that of conventional superconductors, and dramatic differences are found between the two families. Mechanisms of thermal conductivity applicable to high- T c perovskites are discussed and implications for theories of high- T c superconductivity are noted.Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/45121/1/10948_2004_Article_BF00617463.pd
Recommended from our members
Acquisition of shock remanent magnetization for demagnetized samples in a weak magnetic field (7 μT) by shock pressures 5–20 GPa without plasma-induced magnetization
Demagnetized samples of cobalt precipitates in a copper matrix were shocked to 5, 10, and 20 GPa in a weak magnetic field of 7.7 micro-T to elucidate the origins of the natural remanent magnetization of meteorites and the magnetic anomalies of impact craters on the moon and Mars. The samples placed in the target acquired shock remanent magnetization (SRM) whose intensity increased up to 21.3 times compared with the demagnetized state, but SRM intensity and shock intensity were not correlated. The SRM direction was in most cases approximately perpendicular to the shock direction. The samples placed 4.8 mm from the impacted surface did not acquire significant magnetization, suggesting no plasma-induced remanent magnetization (PIRM) up to 20 GPa. When the samples were divided into 8 sub-samples, the SRM intensities of sub-samples increased up to 40 times compared with bulk ones and their directions were scattered. Higher coercive force grains were magnetized perpendicular to the shock direction for shocks of 5 and 10 GPa, but at 20 GPa the directions were less systematically oriented. These results suggest that the proposed plasma-induced magnetization of impactites should be reconsideredThe Meteoritics & Planetary Science archives are made available by the Meteoritical Society and the University of Arizona Libraries. Contact [email protected] for further information.Migrated from OJS platform February 202
STRUCTURAL AND MAGNETIC PROPERTIES OF AMORPHOUS BaO-Fe2O3-B2O3 SYSTEM
Des verres homogènes du type BaO-Fe2O3 (39-63 mol.% Fe2O3) avec B2O3 en petite quantité ont été obtenus par trempe à partir de l'état liquide. L'étude Mössbauer montre que le verre comporte essentiellement des mailles tetraédriques de Fe3+O4 et qu'il existe un ordre antiferromagnétique à courte distance à basse température.Homogeneous glasses of the iron-rich BaO-Fe2O3 system (39-63 mol.% Fe2O3) with a small amount of B2O3 are prepared by splat cooling method. Mössbauer study reveals that the glass mainly consists of tetrahedral network of Fe3+O4 and a short range antiferromagnetic order is formed at low temperatures
- …